GB2007686A - Multi-Arm Star Copolymers - Google Patents
Multi-Arm Star CopolymersInfo
- Publication number
- GB2007686A GB2007686A GB7839327A GB7839327A GB2007686A GB 2007686 A GB2007686 A GB 2007686A GB 7839327 A GB7839327 A GB 7839327A GB 7839327 A GB7839327 A GB 7839327A GB 2007686 A GB2007686 A GB 2007686A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl pyridine
- copolymerisation
- copolymer
- copolymers
- units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001577 copolymer Polymers 0.000 title abstract 7
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- -1 butadiene Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/023—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Multi-arm star copolymers have good physical properties due to copolymerized vinyl pyridine. The copolymers are prepared by subjecting to anionic polymerisation or copolymerisation in a solvent a 1,3- conjugated diene e.g. butadiene, alone or in admixture with a monoalkenyl aromatic monomer, e.g. styrene, using a monolithio organometallic initiator. The copolymerisation may be random or block copolymerisation. At least three moles of divinyl benzene per active polymeric anion are then added to form a nucleus to which at least four radial arms containing the diene units are linked, thus forming a multi- arm star polymer or copolymer. A vinyl pyridine or mixture of monomers one of which is a vinyl pyridine is thereafter added to provide the star copolymer with at least one additional arm containing units of polymerized or copolymerized vinyl pyridine which latter units constitute from 0.5 to 50% by weight of the resulting copolymer. The addition of a proton donor to the polymerization mixture decomposes the active chain ends and enables the resulting copolymer to be recovered in conventional manner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7839327A GB2007686B (en) | 1977-07-05 | 1978-10-04 | Multi-arm star copolymers |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2817277 | 1977-07-05 | ||
| GB7839327A GB2007686B (en) | 1977-07-05 | 1978-10-04 | Multi-arm star copolymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2007686A true GB2007686A (en) | 1979-05-23 |
| GB2007686B GB2007686B (en) | 1982-03-24 |
Family
ID=26259238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7839327A Expired GB2007686B (en) | 1977-07-05 | 1978-10-04 | Multi-arm star copolymers |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2007686B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0029622A3 (en) * | 1979-11-16 | 1981-06-17 | Shell Internationale Research Maatschappij B.V. | Modified hydrogenated star-shaped polymer, its preparation and a lubricating oil composition containing the polymer |
| FR2550207A1 (en) * | 1983-08-04 | 1985-02-08 | Shell Int Research | PROCESS FOR THE PREPARATION OF OIL-SOLUBLE HYDROGEN MODIFIED STAR POLYMERS |
| DE3428402A1 (en) * | 1983-08-04 | 1985-02-21 | Shell Internationale Research Maatschappij B.V., Den Haag | METHOD FOR PRODUCING AN OIL-SOLUBLE STAR-STRUCTURED HYDRATED MODIFIED POLYMER AND ITS USE AS AN OIL ADDITIVE |
| US5397841A (en) * | 1993-12-08 | 1995-03-14 | Shell Oil Company | Grafted polymers having reactive groups at the base |
| EP0684267A1 (en) * | 1994-05-27 | 1995-11-29 | Shell Internationale Researchmaatschappij B.V. | A method for producing asymmetric radial polymers |
| CN111630078A (en) * | 2018-01-26 | 2020-09-04 | 株式会社Lg化学 | Block copolymers containing photoactive moieties |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4427834A (en) | 1981-12-21 | 1984-01-24 | Shell Oil Company | Dispersant-VI improver product |
-
1978
- 1978-10-04 GB GB7839327A patent/GB2007686B/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0029622A3 (en) * | 1979-11-16 | 1981-06-17 | Shell Internationale Research Maatschappij B.V. | Modified hydrogenated star-shaped polymer, its preparation and a lubricating oil composition containing the polymer |
| FR2550207A1 (en) * | 1983-08-04 | 1985-02-08 | Shell Int Research | PROCESS FOR THE PREPARATION OF OIL-SOLUBLE HYDROGEN MODIFIED STAR POLYMERS |
| DE3428402A1 (en) * | 1983-08-04 | 1985-02-21 | Shell Internationale Research Maatschappij B.V., Den Haag | METHOD FOR PRODUCING AN OIL-SOLUBLE STAR-STRUCTURED HYDRATED MODIFIED POLYMER AND ITS USE AS AN OIL ADDITIVE |
| DE3428400A1 (en) * | 1983-08-04 | 1985-02-21 | Shell Internationale Research Maatschappij B.V., Den Haag | METHOD FOR PRODUCING AN OIL-SOLUBLE, STAR-SHAPED, STRUCTURED, HYDRATED, MODIFIED POLYMER, AND ITS USE AS AN OIL ADDITIVE |
| US5397841A (en) * | 1993-12-08 | 1995-03-14 | Shell Oil Company | Grafted polymers having reactive groups at the base |
| EP0684267A1 (en) * | 1994-05-27 | 1995-11-29 | Shell Internationale Researchmaatschappij B.V. | A method for producing asymmetric radial polymers |
| CN111630078A (en) * | 2018-01-26 | 2020-09-04 | 株式会社Lg化学 | Block copolymers containing photoactive moieties |
| EP3736302A4 (en) * | 2018-01-26 | 2021-05-05 | Lg Chem, Ltd. | BLOCK COPOLYMER INCLUDING A PHOTOSENSITIVE GROUP |
| JP2021512182A (en) * | 2018-01-26 | 2021-05-13 | エルジー・ケム・リミテッド | Block copolymer containing photosensitive groups |
| US11384191B2 (en) | 2018-01-26 | 2022-07-12 | Lg Chem, Ltd. | Block copolymer containing photo-sensitive moiety |
| CN111630078B (en) * | 2018-01-26 | 2023-04-07 | 株式会社Lg化学 | Block copolymers comprising photoactive moieties |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2007686B (en) | 1982-03-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |