GB2005280A - Random copolymers of dicyclopentadiene and unsaturated monocyclic compounds - Google Patents
Random copolymers of dicyclopentadiene and unsaturated monocyclic compoundsInfo
- Publication number
- GB2005280A GB2005280A GB7833140A GB7833140A GB2005280A GB 2005280 A GB2005280 A GB 2005280A GB 7833140 A GB7833140 A GB 7833140A GB 7833140 A GB7833140 A GB 7833140A GB 2005280 A GB2005280 A GB 2005280A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dicyclopentadiene
- random copolymers
- unsaturated monocyclic
- monocyclic compounds
- alkylether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 title abstract 2
- 229920005604 random copolymer Polymers 0.000 title abstract 2
- 125000002950 monocyclic group Chemical group 0.000 title 1
- -1 aralkyl radicals Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 abstract 2
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 abstract 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- ZOLLIQAKMYWTBR-RYMQXAEESA-N cyclododecatriene Chemical compound C/1C\C=C\CC\C=C/CC\C=C\1 ZOLLIQAKMYWTBR-RYMQXAEESA-N 0.000 abstract 1
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 abstract 1
- 239000004913 cyclooctene Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
There is disclosed a method for the preparation of random copolymers of dicyclopentadiene and a compound selected from cyclopentene, cyclooctene, 1,5-cyclooctadiene and 1,5,9- cyclododecatriene by the use of a catalyst system comprising (A) tungsten hexachloride, (B) an organosilicon compound of the general formula: R4-nSi(Y)n in which the R substituents are selected from alkyl, cycloalkyl, aryl and aralkyl radicals, and Y represents either a hydroxy group or a vinyl radical and wherein n is 1 or 2; (C) a di-n-alkylether or a phenyl-n-alkylether and (D), an organotin compound represented by the general formula: <IMAGE> in which R<a>, R<b>, R<c>, and R<d> are selected from n-alkyl, phenyl and vinyl radicals.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83385077A | 1977-09-16 | 1977-09-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2005280A true GB2005280A (en) | 1979-04-19 |
| GB2005280B GB2005280B (en) | 1982-03-17 |
Family
ID=25265436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7833140A Expired GB2005280B (en) | 1977-09-16 | 1978-08-11 | Random copolymers of dicyclopentadiene and unsaturated monocyclic compounds |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5454200A (en) |
| BE (1) | BE869987A (en) |
| BR (1) | BR7805927A (en) |
| CA (1) | CA1108797A (en) |
| DE (1) | DE2838304A1 (en) |
| FR (1) | FR2403352A1 (en) |
| GB (1) | GB2005280B (en) |
| IT (1) | IT1107698B (en) |
| MX (1) | MX147648A (en) |
| NL (1) | NL7808808A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4994426A (en) * | 1988-09-29 | 1991-02-19 | Shell Oil Company | Catalyst and process for polymerization of norbornene derivatives |
| US5109073A (en) * | 1988-11-23 | 1992-04-28 | Shell Oil Company | Process for the preparation of polymer blends |
| US5248745A (en) * | 1988-11-22 | 1993-09-28 | Shell Oil Company | Copolymerization of dicyclopentadiene with norbornene derivatives |
| US5344804A (en) * | 1991-08-16 | 1994-09-06 | Shell Research Limited | Polymerization of cycloolefins and catalytic system suitable for use therein |
| US7833443B2 (en) | 2002-08-16 | 2010-11-16 | Johnson & Johnson Vision Care, Inc. | Molds for producing contact lenses |
| WO2021188332A1 (en) * | 2020-03-19 | 2021-09-23 | The Board Of Trustees Of The University Of Illinois | Elastomer with tunable properties and method of rapidly forming the elastomer |
| US11724250B2 (en) | 2018-09-20 | 2023-08-15 | Exxonmobil Chemical Patents Inc. | Metathesis catalyst system for polymerizing cycloolefins |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400340A (en) * | 1982-01-25 | 1983-08-23 | Hercules Incorporated | Method for making a dicyclopentadiene thermoset polymer |
| US4701510A (en) * | 1985-12-16 | 1987-10-20 | The B.F. Goodrich Company | Polycycloolefins resistant to solvents |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1029897A (en) * | 1973-11-05 | 1978-04-18 | Robert J. Minchak | Cyclopentene-dicyclopentadiene copolymers and method of making same in presence of nonconjugated acyclic olefin |
| CA1053850A (en) * | 1975-01-02 | 1979-05-01 | Anthony J. Bell | Process for preparing cyclorene elastomers |
| CA1074949A (en) * | 1975-04-03 | 1980-04-01 | B.F. Goodrich Company (The) | Cyclopentene-dicyclopentadiene copolymers and method of making same |
| FR2333816A1 (en) * | 1975-12-05 | 1977-07-01 | Goodyear Tire & Rubber | Catalyst for polyalkenamer prepn - consisting of mixture of organo-silicon compound, organo-tungsten halide, and organo-aluminium compound |
-
1978
- 1978-07-31 CA CA308,454A patent/CA1108797A/en not_active Expired
- 1978-08-11 GB GB7833140A patent/GB2005280B/en not_active Expired
- 1978-08-23 FR FR7824472A patent/FR2403352A1/en active Granted
- 1978-08-25 NL NL7808808A patent/NL7808808A/en not_active Application Discontinuation
- 1978-08-25 BE BE190083A patent/BE869987A/en not_active IP Right Cessation
- 1978-09-01 DE DE19782838304 patent/DE2838304A1/en not_active Withdrawn
- 1978-09-08 MX MX174818A patent/MX147648A/en unknown
- 1978-09-11 IT IT51038/78A patent/IT1107698B/en active
- 1978-09-12 BR BR7805927A patent/BR7805927A/en unknown
- 1978-09-14 JP JP11351278A patent/JPS5454200A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4994426A (en) * | 1988-09-29 | 1991-02-19 | Shell Oil Company | Catalyst and process for polymerization of norbornene derivatives |
| US5248745A (en) * | 1988-11-22 | 1993-09-28 | Shell Oil Company | Copolymerization of dicyclopentadiene with norbornene derivatives |
| US5109073A (en) * | 1988-11-23 | 1992-04-28 | Shell Oil Company | Process for the preparation of polymer blends |
| US5344804A (en) * | 1991-08-16 | 1994-09-06 | Shell Research Limited | Polymerization of cycloolefins and catalytic system suitable for use therein |
| US7833443B2 (en) | 2002-08-16 | 2010-11-16 | Johnson & Johnson Vision Care, Inc. | Molds for producing contact lenses |
| US8292256B2 (en) * | 2002-08-16 | 2012-10-23 | Johnson & Johnson Vision Care, Inc. | Molds for producing contact lenses |
| US11724250B2 (en) | 2018-09-20 | 2023-08-15 | Exxonmobil Chemical Patents Inc. | Metathesis catalyst system for polymerizing cycloolefins |
| WO2021188332A1 (en) * | 2020-03-19 | 2021-09-23 | The Board Of Trustees Of The University Of Illinois | Elastomer with tunable properties and method of rapidly forming the elastomer |
| EP4121134A1 (en) | 2020-03-19 | 2023-01-25 | The Board of Trustees of the University of Illinois | Elastomer with tunable properties and method of rapidly forming the elastomer |
| US20230096431A1 (en) * | 2020-03-19 | 2023-03-30 | The Board Of Trustees Of The University Of Illinois | Elastomer with tunable properties and method of rapidly forming the elastomer |
| EP4121134A4 (en) * | 2020-03-19 | 2024-04-17 | The Board of Trustees of the University of Illinois | Elastomer with tunable properties and method of rapidly forming the elastomer |
| US12533441B2 (en) * | 2020-03-19 | 2026-01-27 | The Board Of Trustees Of The University Of Illinois | Elastomer with tunable properties and method of rapidly forming the elastomer |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1108797A (en) | 1981-09-08 |
| MX147648A (en) | 1982-12-30 |
| JPS5454200A (en) | 1979-04-28 |
| FR2403352B1 (en) | 1980-07-18 |
| BR7805927A (en) | 1979-05-02 |
| BE869987A (en) | 1978-12-18 |
| GB2005280B (en) | 1982-03-17 |
| IT1107698B (en) | 1985-11-25 |
| DE2838304A1 (en) | 1979-03-29 |
| FR2403352A1 (en) | 1979-04-13 |
| IT7851038A0 (en) | 1978-09-11 |
| NL7808808A (en) | 1979-03-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |