GB2005269A - Preparation of 3-phenoxybenzyl 3(2,2-dihalovinyl)-2,2- dimethylcyclopropanecarboxylate - Google Patents
Preparation of 3-phenoxybenzyl 3(2,2-dihalovinyl)-2,2- dimethylcyclopropanecarboxylateInfo
- Publication number
- GB2005269A GB2005269A GB7838708A GB7838708A GB2005269A GB 2005269 A GB2005269 A GB 2005269A GB 7838708 A GB7838708 A GB 7838708A GB 7838708 A GB7838708 A GB 7838708A GB 2005269 A GB2005269 A GB 2005269A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dihalovinyl
- dimethylcyclopropanecarboxylate
- phenoxybenzyl
- preparation
- lower alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 3-phenoxybenzyl Chemical group 0.000 title abstract 3
- KGANAERDZBAECK-UHFFFAOYSA-N (3-phenoxyphenyl)methanol Chemical compound OCC1=CC=CC(OC=2C=CC=CC=2)=C1 KGANAERDZBAECK-UHFFFAOYSA-N 0.000 abstract 1
- 238000006136 alcoholysis reaction Methods 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/743—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a three-membered ring and with unsaturation outside the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The insecticide, 3-phenoxybenzyl 3-(2,2-dihalovinyl)-2,2- dimethylcyclopropanecarboxylate, is produced in high yield by the alcoholysis of a lower alkyl 3-(2,2- dihalovinyl)-2,2- dimethylcyclopropanecarboxylate with 3-phenoxybenzyl alcohol in the presence of a catalytic quantity of lower alkyl titanium alkoxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83905177A | 1977-10-03 | 1977-10-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2005269A true GB2005269A (en) | 1979-04-19 |
| GB2005269B GB2005269B (en) | 1982-03-10 |
Family
ID=25278739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7838708A Expired GB2005269B (en) | 1977-10-03 | 1978-09-29 | Process to 3-phenoxybenzyl 3-(2,2-dihalovinyl)-2,2-dimethylcyclopropanecarboxylate |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5459265A (en) |
| BR (1) | BR7806542A (en) |
| CA (1) | CA1123855A (en) |
| GB (1) | GB2005269B (en) |
| GT (1) | GT197854452A (en) |
| MX (1) | MX5105E (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5154841A (en) * | 1988-12-21 | 1992-10-13 | The Procter & Gamble Company | Process for preparing substituted imidazoline fabric conditioning compounds |
| EP1061065A3 (en) * | 1999-06-16 | 2001-11-28 | Sumitomo Chemical Company, Limited | Methods for producing cyclopropane carboxylates |
| US6531626B1 (en) * | 1998-10-08 | 2003-03-11 | Sumitomo Chemical Company, Limited | Method for producing cyclopropanecarboxylates |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE112006000237T5 (en) | 2005-01-28 | 2008-07-03 | Sumitomo Chemical Co., Ltd. | A transition metal complex, a process for producing the transition metal complex, a substituent-containing fluorene compound, a process for producing the substituent-containing fluorene compound, a catalyst component for olefin polymerization, a catalyst for olefin polymerization, and a process for producing an olefin polymer |
-
1978
- 1978-09-06 CA CA310,777A patent/CA1123855A/en not_active Expired
- 1978-09-29 GB GB7838708A patent/GB2005269B/en not_active Expired
- 1978-09-29 JP JP11941178A patent/JPS5459265A/en active Granted
- 1978-10-02 MX MX787438U patent/MX5105E/en unknown
- 1978-10-02 GT GT197854452A patent/GT197854452A/en unknown
- 1978-10-02 BR BR7806542A patent/BR7806542A/en unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5154841A (en) * | 1988-12-21 | 1992-10-13 | The Procter & Gamble Company | Process for preparing substituted imidazoline fabric conditioning compounds |
| US6531626B1 (en) * | 1998-10-08 | 2003-03-11 | Sumitomo Chemical Company, Limited | Method for producing cyclopropanecarboxylates |
| EP1061065A3 (en) * | 1999-06-16 | 2001-11-28 | Sumitomo Chemical Company, Limited | Methods for producing cyclopropane carboxylates |
| US6441220B1 (en) * | 1999-06-16 | 2002-08-27 | Sumitomo Chemical Company, Limited | Methods for producing cyclopropane carboxylates |
| KR100679902B1 (en) * | 1999-06-16 | 2007-02-07 | 스미또모 가가꾸 가부시끼가이샤 | Method for preparing cyclopropane carboxylate |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5459265A (en) | 1979-05-12 |
| CA1123855A (en) | 1982-05-18 |
| JPS5549065B2 (en) | 1980-12-10 |
| BR7806542A (en) | 1979-05-02 |
| MX5105E (en) | 1983-03-16 |
| GT197854452A (en) | 1980-03-25 |
| GB2005269B (en) | 1982-03-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PE20 | Patent expired after termination of 20 years |
Effective date: 19980928 |