GB2092123A - A Method of Applying a Resistant Protective Enamel Coat to Ductile Cast Iron Objects - Google Patents
A Method of Applying a Resistant Protective Enamel Coat to Ductile Cast Iron Objects Download PDFInfo
- Publication number
- GB2092123A GB2092123A GB8136178A GB8136178A GB2092123A GB 2092123 A GB2092123 A GB 2092123A GB 8136178 A GB8136178 A GB 8136178A GB 8136178 A GB8136178 A GB 8136178A GB 2092123 A GB2092123 A GB 2092123A
- Authority
- GB
- United Kingdom
- Prior art keywords
- enamel
- cast iron
- coat
- applying
- ductile cast
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 12
- 229910001141 Ductile iron Inorganic materials 0.000 title claims abstract description 11
- 230000001681 protective effect Effects 0.000 title claims abstract description 7
- 229910001018 Cast iron Inorganic materials 0.000 claims abstract description 16
- 239000011159 matrix material Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 230000006698 induction Effects 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 3
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 2
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D5/00—Coating with enamels or vitreous layers
- C23D5/04—Coating with enamels or vitreous layers by dry methods
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/06—Frit compositions, i.e. in a powdered or comminuted form containing halogen
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D5/00—Coating with enamels or vitreous layers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D7/00—Treating the coatings, e.g. drying before burning
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D9/00—Ovens specially adapted for firing enamels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Protection Of Pipes Against Damage, Friction, And Corrosion (AREA)
Abstract
The invention relates to a method of applying a protective enamel coat which is resistant to aggressive media, to ductile cast iron objects, in particular cast iron pipes, comprising applying an enamel to the cast iron, object surface which does not comprise a ground enamel coat and has been pre-treated in well-known manner, which enamel has the following enamel composition matrix: <IMAGE> In this manner it is surprisingly possible to apply the enamel directly-i.e. without previous application of a ground enamel.
Description
SPECIFICATION
A Method of Applying A Resistant Protective
Enamel Coat to Ductile Cast Iron Objects
The invention relates to a method of applying a protective enamel coat which is resistant to aggressive media, to ductile cast iron objects, in particular cast iron pipes.
As described in literature ("Silikat-Technik" 1 955, page 480) one was of the opinion from the first that ductile iron ("Sphdrogup"-nodular iron) could not be enamelled. At about the same time it became known (Petzold "Emaille" 1950, Stuckert "Die Emailfabrikation" 1941 and Marker "Emailliertechnik" 1956) that it is necessary to first of all apply and burn-in a ground enamel before resistant enamel powders are laid on. Accordingly this implies a two-stage proceeding. Such a proceeding entails a high amount of electrical energy and great expense owing to the ground enamel coat which has to be applied and burnedin at first.
The invention is based on the object of further developing the conventional method so that also ductile cast iron objects can be provided with a resistant enamel coat by one-stage enamelling operation.
The method according to the present invention by which this object is achieved, is substantially characterized in that an enamel is applied to the cast iron object surface which does not comprise a ground enamel coat and which has been pretreated in a well-known manner, which enamel has the following enamel composition matrix::
% in weight
SiO2 30-50 B203 2-10 Na20 15-20 Bi203 1-10 Li2O 1-5
TiO2 5-15 CaO 1-5
BaO 1 Awl203 1-3
ZrO2 1-3
CeO2 0-3 SrO 0--1 ZnO 1-5
MnO O3 NiO 0.5-2 CoO 0.5-1 F2 0.5-2 The teaching of the present invention therefore is based on the surprising perception that-unlike the aforementioned prevailing belief-it is possible to apply to ductile cast iron objects, in particular cast iron pipes, and by means of a direct-acting method i.e. without previous application of a ground enamel, an enamel coat resistant to organic acids and to any kind of water, so that for burying such cast iron pipes in the ground one need not provide a special envelope or previously arrange an additional
protective layer to protect them against aggressive media. Apart from the possibility to save energy as the costly application of a ground enamel coat which must be burned-in a special step can be done without, the use of spheroidal graphite or nodular cast iron pipes provided with a protective enamel coat means substantial simplification and thus causes great reduction in labour and time.
The enamel is applied preferably in perpendicular position of the cast iron pipes or of like rotational-cast objects, viz. in particular in the form of a slip by means of dipping, spraying or rinsing. For drying the applied slip most conveniently an induction coil can be used. The enamelling proper, i.e. the firing of the enamel, is carried out while the cast iron objects take the vertical position, preferably also by means of an induction coil at preset temperature and speed.
The pipe is passed through the induction coil from top to bottom, or vice versa.
With the method according to the present invention it proved most practical to apply the enamel in the form of powder directly to the cast iron object while the latter is still in the heated state. Such a proceeding is most advantageous in that time may be saved. Besides, as the enamel used according to the invention has a relatively low meltdown temperature so as to fulfil the condition that first of all the cast iron object to be enamelled can be heated to the temperature at which the enamel will adhere and then can be enamelled while the still existing inherent heat of the cast iron object is being used, a separate heating and firing operation may practically be omitted and additonally a high amount of energy can be saved.
With the afore-mentioned low meltdown temperature there is connected a low softening interval of 500 to 5200C, by means of which the enamel may be melted smooth at a temperature range of from 700 to 8000C. By reducing the burn-in time, e.g. to 1 to 3 minutes, one may proceed also in the upper temperature range of up to 9500 C.
The enamel used in the method according to the subject invention is characterized by its low surface tension of 200 to 210 dyn/cm. This allows quick wetting and flat-flowing of the enamel in the thin-layer range of less than 400 microns. In the thin-layer range of less than 500 microns the enamel is impact resistant and wear resistant up to 5 kp. Owing to the dry technology a non-adulterate enamel glass powder is melted, so that compact and smooth surface enamel coats are obtained which by no means tend to incrustation. Due to the intimate bond of the bonded material-enamel and ductile cast ironcorrosion or rust formation beneath the surface will not occur. The enamel glass powder material is neutral with respect two all metals and metal compounds. It should also be noted that the enamel is harmless in terms of physiology and toxicity, on the one hand, and resistant in the pH range of from 1 to 10 to all organic acids and waste waters as well as raw water, service water and drink water, on-the other hand.
Claims (4)
1. A method of applying a protective enamel coat which is resistant to aggressive media, to ductile cast iron objects, in particular cast iron pipes, characterized in that an enamel is applied to the cast iron object surface, which does not comprise a ground enamel coat, which enamel has the following enamel composition matrix:
% in weight
SiO2 30-50 8203 2-10 Na2O 15-20 Bi203 1-10 Li2O 1-5
TiO2 5-15 CaO 1-5
BaO 1-5
Al2O3 1-3
ZrO2 1-3
CeO2 0-3
SrO 0-1
ZnO 1-5
MnO 0-3 NiO 0.5-
2 CoO 0.5-1 F2 0.5-2 2. A method according to claim 1, characterized in that the enamel is applied, in the form of powder, directly to the cast iron object which is still in the heated state.
3. A method according to claim 1, characterized by the use of an induction coil for drying the enamel slip applied to said cast iron object and/or for firing the protective enamel coat.
4. A cast iron object enameled according to the method of one of the preceding claixns.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19803045249 DE3045249A1 (en) | 1980-12-01 | 1980-12-01 | METHOD FOR APPLYING A RESISTANT PROTECTIVE ENAMEL COVER TO DUCTILE MOLDED BODY |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2092123A true GB2092123A (en) | 1982-08-11 |
| GB2092123B GB2092123B (en) | 1984-04-18 |
Family
ID=6118034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8136178A Expired GB2092123B (en) | 1980-12-01 | 1981-12-01 | A method of applying a resistant protective enamel coat to ductile cast iron objects |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS57149844A (en) |
| DE (1) | DE3045249A1 (en) |
| FR (1) | FR2495190B1 (en) |
| GB (1) | GB2092123B (en) |
| SE (1) | SE445038B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0262565A1 (en) * | 1986-10-02 | 1988-04-06 | Mobay Corporation | Enamel composition and substrates coated therewith |
| EP0267154A1 (en) * | 1986-11-03 | 1988-05-11 | Ciba-Geigy Ag | Lead-free glass frit compositions |
| US4970178A (en) * | 1986-11-03 | 1990-11-13 | Ciba-Geigy Corporation | Lead-free glass frit compositions |
| EP0725254A3 (en) * | 1995-02-04 | 1997-05-14 | Ego Elektro Blanc & Fischer | Cooking plate with a cast piece and method for its production |
| US6498117B1 (en) | 1999-07-08 | 2002-12-24 | Saint-Gobain Vitrage | Process for manufacturing a recyclable zinc-containing black enamel composition |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2786245B2 (en) * | 1988-05-26 | 1998-08-13 | 池袋琺瑯工業株式会社 | Frit composition for direct hanging enamel |
| GB9108257D0 (en) * | 1991-04-17 | 1991-06-05 | Cookson Group Plc | Glaze compositions |
| DE4115173C1 (en) * | 1991-05-09 | 1992-04-16 | Fissler Gmbh, 6580 Idar-Oberstein, De | |
| EP0518610B1 (en) * | 1991-06-14 | 1995-10-18 | COOKSON GROUP plc | Glass compositions |
| DE4124801C2 (en) * | 1991-07-26 | 1995-03-30 | Bayer Ag | Enamel frit for direct enameling on unpainted steel sheet and its use |
| DE4216282C1 (en) * | 1992-05-16 | 1993-06-09 | Hans Josef 5860 Iserlohn De May | |
| DE10351902A1 (en) * | 2003-11-06 | 2005-06-16 | Damixa A/S | Water-conducting body |
| DE102016107944A1 (en) * | 2016-04-28 | 2017-11-02 | Duktus (Production) Gmbh | Method for producing a component of ductile cast iron and ductile cast iron component |
| CN112876080B (en) * | 2021-02-04 | 2022-02-15 | 中国科学院合肥物质科学研究院 | Glass ceramic coating for lead-based reactor pump impeller and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2492523A (en) * | 1948-01-20 | 1949-12-27 | Metal & Thermit Corp | Acid resistant enamel frit and ferrous metal coated with enamel made from same |
| DE1285120B (en) * | 1961-11-18 | 1968-12-12 | Inouye Seiichi | Process for the production of an enamel coating on iron |
| NL288521A (en) * | 1963-01-30 | |||
| US3481757A (en) * | 1964-07-15 | 1969-12-02 | Eagle Picher Co | Dry process porcelain enameling frit and method |
| FR2046633A5 (en) * | 1970-05-13 | 1971-03-05 | Kh | Vitreous metal coating enamel compsn |
| FR2297817A1 (en) * | 1975-01-16 | 1976-08-13 | Pont A Mousson | Cast metal tube with glass liner mfr. - by injecting glass powder into the hot freshly cast metal surface |
-
1980
- 1980-12-01 DE DE19803045249 patent/DE3045249A1/en not_active Withdrawn
-
1981
- 1981-12-01 FR FR8122960A patent/FR2495190B1/en not_active Expired
- 1981-12-01 GB GB8136178A patent/GB2092123B/en not_active Expired
- 1981-12-01 SE SE8107160A patent/SE445038B/en not_active IP Right Cessation
- 1981-12-01 JP JP19360981A patent/JPS57149844A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0262565A1 (en) * | 1986-10-02 | 1988-04-06 | Mobay Corporation | Enamel composition and substrates coated therewith |
| EP0267154A1 (en) * | 1986-11-03 | 1988-05-11 | Ciba-Geigy Ag | Lead-free glass frit compositions |
| US4970178A (en) * | 1986-11-03 | 1990-11-13 | Ciba-Geigy Corporation | Lead-free glass frit compositions |
| EP0725254A3 (en) * | 1995-02-04 | 1997-05-14 | Ego Elektro Blanc & Fischer | Cooking plate with a cast piece and method for its production |
| US6498117B1 (en) | 1999-07-08 | 2002-12-24 | Saint-Gobain Vitrage | Process for manufacturing a recyclable zinc-containing black enamel composition |
| US6849301B2 (en) | 1999-07-08 | 2005-02-01 | Saint-Gobain Glass France | Enamel composition, manufacturing process and resulting enamelled products |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2495190A1 (en) | 1982-06-04 |
| DE3045249A1 (en) | 1982-07-01 |
| SE445038B (en) | 1986-05-26 |
| FR2495190B1 (en) | 1986-04-25 |
| SE8107160L (en) | 1982-06-02 |
| GB2092123B (en) | 1984-04-18 |
| JPS57149844A (en) | 1982-09-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |