GB2085463A - Grout preparations - Google Patents
Grout preparations Download PDFInfo
- Publication number
- GB2085463A GB2085463A GB8128903A GB8128903A GB2085463A GB 2085463 A GB2085463 A GB 2085463A GB 8128903 A GB8128903 A GB 8128903A GB 8128903 A GB8128903 A GB 8128903A GB 2085463 A GB2085463 A GB 2085463A
- Authority
- GB
- United Kingdom
- Prior art keywords
- preparation
- grout
- substance
- pigment
- odoriferous substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 44
- 239000011440 grout Substances 0.000 title claims abstract description 34
- 239000000126 substance Substances 0.000 claims abstract description 25
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- 239000002304 perfume Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 7
- 239000004576 sand Substances 0.000 claims abstract description 6
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 4
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 4
- 229920001059 synthetic polymer Polymers 0.000 claims abstract description 3
- 229920002545 silicone oil Polymers 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002270 dispersing agent Substances 0.000 claims description 4
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical group COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 claims description 4
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000000417 fungicide Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 229920003086 cellulose ether Polymers 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 229940102398 methyl anthranilate Drugs 0.000 claims description 2
- 229940081310 piperonal Drugs 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920001229 Starlite Polymers 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000004533 oil dispersion Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- JZFICWYCTCCINF-UHFFFAOYSA-N Thiadiazin Chemical compound S=C1SC(C)NC(C)N1CCN1C(=S)SC(C)NC1C JZFICWYCTCCINF-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- GBPOWOIWSYUZMH-UHFFFAOYSA-N sodium;trihydroxy(methyl)silane Chemical compound [Na+].C[Si](O)(O)O GBPOWOIWSYUZMH-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A grout preparation for use in setting ceramic tiles or for renovating existing grout lines has incorporated therein an odoriferous substance, such as a perfume. The grout may be of ready-mixed type based on an emulsion of a synthetic polymer, e.g. polyvinyl acetate, or of a type to be mixed with water before use, e.g. a grout based on cement and sand. The preparation may be either a paste or of paint- like consistency for coating.
Description
SPECIFICATION
Grout preparations
DESCRIPTION
This invention concerns grout preparations, for use in setting ceramic tiles or for renovating existing grout lines, either as ready mixed compositions or as compositions to be mixed with water prior to use.
Tiles are often fixed to walls of rooms in which an easily cleaned surface is desired for the purpose of hygiene. Such rooms include kitchens and bathrooms where a pleasantly smelling atmosphere is also often desired.
The object of this invention is to provide a grout preparation capable of imparting a pleasant odour to a room in which it has been used.
Accordingly this invention provides a grout preparation having incorporated therein an odoriferous substance.
The odoriferous substance may be a perfume, for example, for imparting an odour like that of pine, rose, cologne, or may even be a blend of perfume oils. Clearly, the odoriferous substance will be chosen according to the desired odour.
Particularly suitable as odoriferous substances are certain aromatic compounds, such as esters and aldehydes. Examples of these are methyl anthranilate
and piperonal
Suitable specific examples of perfumes are those known as Cologne A105257 and Starlite A105258.
The odoriferous substance may be incorporated in the grout preparations in any suitable way and may be a liquid (oil) or solid (powder) which is readily dispersed in the grout preparation. Alternatively, the odoriferous substance may be in the form of microencapsulated particles which are dispersed in the grout preparation, thus ensuring gradual release of the odoriferous substance to atmosphere.
Microencapsulated particles are prepared by a three phase component system consisting of perfume, carrier solution and additive material (a gel type for example) which coagulates on changes of pH allowing the particles to be formed by spray or freeze drying.
The amount of odoriferous substance incorporated in the grout preparations will be fairly small usually up to about 2% by weight.
For a ready mixed grout or grout renovator preparation according to the invention, the essential ingredients apart from the odoriferous substance, will be an aqueous emulsion of a synthetic polymer and a filler.
These ready mixed preparations may also include a silicone oil, a pigment and other minor additives customary in grout preparations, for example thickeners, fungicides and dispersing agents.
The reason for including a silicone oil is to provide a grout preparation which when applied over a glazed tile surface can readily be removed therefrom after drying merely by rubbing with a dry cloth.
The silicone oil will usually be incorporated in the polymer emulsion prior to compounding with the odoriferous substance, fillers, pigment and other additives. The silicone oil may be emulsified by the addition of various surfactant systems and these emulsions are freely miscible with polymer emulsions providing the surfactant systems of the polymer emulsion and the silicone oil emulsion are not incompatible. In some cases a silicone oil can be dispersed directly into the polymer emulsion.
In the polymer-silicone oil dispersions proportions of silicone oils of between 10% and 40% by weight of the polymer solids have proved satisfactory. Suitable silicone oils are dimethyl silicone or dimethyl polysiloxane.
The polymer emulsions particularly suitable for the ready mixed grout preparations are emulsions of vinyl and acrylic polymers or copolymers.
Grout renovators containing an odoriferous substance are particularly advantageous, in that when the original grout no longer imparts a pleasant odour, this can be restored by renovating the grout lines.
The ready mixed preparations in accordance with the present invention can, as stated, be used either as a coating composition for application to existing grout lines to repair and/or improve the appearance of the latter or as a ready-mixed grouting composition. The difference between the preparations will largely be one of consistency, coating compositions being of a paint-like consistency and the grouting compositions being of a thick-paste consistency. This will reflect a lower polymer content and higher filler content of the grouting composition in relation to a coating composition.
For a grout preparation which is to be mixed with water before use, the essential ingredients, apart from the odoriferous substance, will be cement, filler, such as sand, substances to improve adhesion, such as polyvinyl alcohol and polyvinyl acetate, and a substance to improve workability and limit water absorption by the tiles and substrate, such as cellulose ether. Optional ingredients include pigments.
The percentage ratio of cement to sand may be from 70:30 but will usually be about 50:50.
The grout preparations of this invention, as has already been stated, may include pigment. The pigment may an inorganic oxide or an organic pigment and may be included at the manufacturing stage or may be added later by the user of the preparation. The amount of pigment to be added in either case will usually be from 0.1 to 7.5% by weight of the preparation.
In the main, grout preparations according to the invention whether ready mixed or otherwise are prepared by mixing of the ingredients except as stated above for silicone oils.
This invention will be further described by means of the following Examples:
Example 1
A ready-mixed grout was prepared by mixing the following ingredients in the amounts stated:
% by
weight
Pigment dispersant solution
(Vinamul 6975, vinyl acetate
copolymer emulsion) 9.94
DC 772 Water repellant (sodium
methyl siliconate) 1.42
Ethylene glycol 3.55
Ground China Clay 1.42
Polymer (VINAMUL 8120 polyvinyl
acetate emulsion) silicone oil
dispersion 14.22
Filler and pigment (Dolomite and
titanium dioxide) 67.49
Perfume (Cologne A105257) 1.96
Example 2
A ready-mixed grout renovator was prepared by mixing the following ingredients in the amounts stated: :
% by
weight
Water 26.99
Pigment dispersant solution
(VINAPOL 1640, potassium
polymethacrylate) 2.95
Ground limestone 31.90
Titanium dioxide 5.89
Polymer (VINAMUL 8120) silicone 29.46
oil dispersion Hydroxymethyl cellulose 0.30
Fungicide (THION 60, thiadiazine) 0.05
DC 772 water repellant 0.99
Perfume (STARLITE Awl 05258) 1.47
Example 3
A cement based grout was prepared by mixing the following ingredients in the amounts stated:
% by
weight
White cement 42.84
Sand 54.53
Cellulose 0.19' Perfume (COLOGNE A105257) 2.44
It will be appreciated that similar grouts and renovators to those of Examples 1 to 3 may be prepared wherein the perfume is in a microencapsulated form.
Claims (21)
1. A grout preparation having incorporated therein an odoriferous substance.
2. A preparation as claimed in claim 1 wherein the odoriferous substance is a perfume or a blend of perfumes.
3. A preparation as claimed in claim 1 or 2 wherein the odoriferous substance is incorporated in the form of a liquid (oil) or solid (powder) or in microencapsulated form.
4. A preparation as claimed in claim 1, 2 or 3 wherein the odoriferous substance is an aromatic compound;
5. A preparation as claimed in claim 4 wherein the aromatic compound is an ester or an aldehyde.
6. A preparation as claimed in any one of claims 1 ro 5 wherein the odoriferous substance is methyl anthranilate or piperonal.
7. A preparation as claimed in any one of claims 1 ro 6 wherein the amount of odoriferous substance incorporated is upto 2% by weight.
8. A ready mixed grout or grout renovator preparation as claimed in any one of claims 1 to 7 comprising an aqueous emulsion of a synthetic polymer and a filler - - - -
9. A preparation as claimed in claim 8 further comprising a silicone oil, a pigment and optionally one or more of thickners, fungicides and dispersing agents.
1 0. A preparation as claimed in claim 9 wherein pigment is present in an amount of from 0.1 to 7.5% by weight.
11. A preparation as claimed in claim 9 or 10 wherein the silicone oil is emulsified by the addition of a surfactant system.
1 2. A preparation as claimed in claim 9, 10 or 11 wherein the silicone oil is present in an amount of between 10 and 40% by weight of the polymer solids.
1 3. A preparation as claimed in any one of claims 9 to 1 2 in which the silicone oil is dimethyl silicone or dimethyl polysiloxane.
14. A preparation as claimed in any one of claims 8 to 1 3 wherein the aqueous polymer emulsion is of vinyl or acrylic polymers or copolymers.
1 5. A grout preparation as claimed in any one of claims 1 to 7 which is to mixed with water before use comprising cement, filler, substances to improve adhesion, a substance to improve workability and limit water absorption by tiles and substrate, and optionally pigment.
16. A preparation as claimed in claim 1 5 wherein the filler is sand.
1 7. A preparation as claimed in claim 1 5 or 1 6 wherein the substances to improve adhesion are polyvinyl alcohol and polyvinyl acetate.
1 8. A preparation as claimed in claim 15, 1 6 or 1 7 wherein the pigment is present in an amount of from 0.1 to 7.5% by weight.
1 9. A preparation as claimed in any one of claims 1 5 to 1 8 wherein the substance to improve workability and limit water absorption is cellulose ether.
20. A preparation as claimed in any one of claims 1 6 to 1 9 wherein the percentage ratio of cement to sand is from 70:30 to 30:70.
21. A grout preparation substantially as hereinbefore described with reference to any one of the Examples.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8128903A GB2085463B (en) | 1980-10-01 | 1981-09-24 | Grout preparations |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8031618 | 1980-10-01 | ||
| GB8128903A GB2085463B (en) | 1980-10-01 | 1981-09-24 | Grout preparations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2085463A true GB2085463A (en) | 1982-04-28 |
| GB2085463B GB2085463B (en) | 1984-09-05 |
Family
ID=26277054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8128903A Expired GB2085463B (en) | 1980-10-01 | 1981-09-24 | Grout preparations |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2085463B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2141726A (en) * | 1981-02-28 | 1985-01-03 | Building Adhesives Ltd | Adhesive compositions |
| EP0122041A3 (en) * | 1983-03-10 | 1985-03-06 | The Procter & Gamble Company | Method and composition for imparting fragrant odor to product container |
| GB2155944A (en) * | 1984-03-16 | 1985-10-02 | Building Adhesives Ltd | Powder compositions for producing tile adhesives and grouts |
| US4900062A (en) * | 1987-09-17 | 1990-02-13 | Ugo Mursia Editore S.P.A. | Process for perfuming books, device for carrying out said process, so-obtained perfumed book |
| US5558708A (en) * | 1995-05-11 | 1996-09-24 | C-Cure Corporation | System and method for dispersing pigment in cement based compositions |
| US5846315A (en) * | 1995-05-11 | 1998-12-08 | C-Cure Corporation | Method for preparing a pigmented dispersing pigment cement composition |
| FR2839971A1 (en) * | 2002-05-27 | 2003-11-28 | Audresset Creations | Solid material useful for household decoration comprises sand or gravel, a resin and a perfume |
| US6692565B2 (en) | 2000-11-20 | 2004-02-17 | C-Cure Corp. | Colored cement |
-
1981
- 1981-09-24 GB GB8128903A patent/GB2085463B/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2141726A (en) * | 1981-02-28 | 1985-01-03 | Building Adhesives Ltd | Adhesive compositions |
| EP0122041A3 (en) * | 1983-03-10 | 1985-03-06 | The Procter & Gamble Company | Method and composition for imparting fragrant odor to product container |
| US4540721A (en) * | 1983-03-10 | 1985-09-10 | The Procter & Gamble Company | Method of providing odor to product container |
| GB2155944A (en) * | 1984-03-16 | 1985-10-02 | Building Adhesives Ltd | Powder compositions for producing tile adhesives and grouts |
| US4900062A (en) * | 1987-09-17 | 1990-02-13 | Ugo Mursia Editore S.P.A. | Process for perfuming books, device for carrying out said process, so-obtained perfumed book |
| US5558708A (en) * | 1995-05-11 | 1996-09-24 | C-Cure Corporation | System and method for dispersing pigment in cement based compositions |
| US5846315A (en) * | 1995-05-11 | 1998-12-08 | C-Cure Corporation | Method for preparing a pigmented dispersing pigment cement composition |
| US5855665A (en) * | 1995-05-11 | 1999-01-05 | C-Cure Corporation | System and method for producing a pigmented cement composition |
| US5951752A (en) * | 1995-05-11 | 1999-09-14 | C-Cure Corporation | Method of using a coloring composition in a concrete based composition |
| US6692565B2 (en) | 2000-11-20 | 2004-02-17 | C-Cure Corp. | Colored cement |
| FR2839971A1 (en) * | 2002-05-27 | 2003-11-28 | Audresset Creations | Solid material useful for household decoration comprises sand or gravel, a resin and a perfume |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2085463B (en) | 1984-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0919526B1 (en) | Construction materials comprising hydrophobing powders containing organosilicon compounds | |
| DE60121164T2 (en) | Water-repellent organosilicone composition | |
| TW399086B (en) | Water repellent composition | |
| JP2851583B2 (en) | Coating paints and coatings containing water-redispersible powders having water-soluble polymers and organosilicon compounds | |
| JP2002536463A (en) | Aqueous cream of organosilicon compound | |
| CA2065231A1 (en) | Clay-free, asbestos-free and glass microbubble-free joint compounds | |
| GB2155944A (en) | Powder compositions for producing tile adhesives and grouts | |
| GB2085463A (en) | Grout preparations | |
| US6838492B2 (en) | Scented paints, paint scenting additive mixtures and processes for producing scented paints | |
| JPH06100348A (en) | System for increasing viscosity of water based blend of construction material | |
| WO2005023935A1 (en) | Silicone oil-in-water (o/w) emulsions or compositions useful for water repellent applications | |
| JP2003503173A (en) | Hydrolyzable silane emulsion and its preparation | |
| GB2093856A (en) | Adhesive compositions | |
| KR100496241B1 (en) | A compound or manufacturing method of ceramic coating | |
| WO1997042269A1 (en) | Biostatic coating composition | |
| WO2022208376A1 (en) | Multifunctional adhesive composition and a process for its preparation | |
| US4218258A (en) | Hydraulic cement adhesive compositions | |
| GB2061990A (en) | Ceramic tile adhesive | |
| GB2131788A (en) | Grout preparations | |
| RU2281263C2 (en) | Spackling compound | |
| JP2012503050A (en) | Paint material containing basic additives | |
| GB2141726A (en) | Adhesive compositions | |
| GB1572906A (en) | Grout preparations | |
| US20130122209A1 (en) | Organosilicon Hydrophobing Agents | |
| GB2134913A (en) | Adhesive compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |