GB2079315A - Ferritic spheroidal-graphite iron for casting thick sections without segregation - Google Patents
Ferritic spheroidal-graphite iron for casting thick sections without segregation Download PDFInfo
- Publication number
- GB2079315A GB2079315A GB8119841A GB8119841A GB2079315A GB 2079315 A GB2079315 A GB 2079315A GB 8119841 A GB8119841 A GB 8119841A GB 8119841 A GB8119841 A GB 8119841A GB 2079315 A GB2079315 A GB 2079315A
- Authority
- GB
- United Kingdom
- Prior art keywords
- less
- casting
- mpa
- iron
- spheroidal graphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000005266 casting Methods 0.000 title claims abstract description 53
- 238000005204 segregation Methods 0.000 title description 3
- 229910001141 Ductile iron Inorganic materials 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 26
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 8
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 8
- 239000011777 magnesium Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005864 Sulphur Substances 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 3
- 239000011651 chromium Substances 0.000 claims abstract description 3
- 229910052802 copper Inorganic materials 0.000 claims abstract description 3
- 239000010949 copper Substances 0.000 claims abstract description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 3
- 239000011733 molybdenum Substances 0.000 claims abstract description 3
- 239000010936 titanium Substances 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 34
- 229910002804 graphite Inorganic materials 0.000 claims description 18
- 239000010439 graphite Substances 0.000 claims description 18
- 229910052742 iron Inorganic materials 0.000 claims description 17
- 238000012360 testing method Methods 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 8
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000331231 Amorphocerini gen. n. 1 DAD-2008 Species 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- -1 iron carbides Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/04—Cast-iron alloys containing spheroidal graphite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Abstract
The casting contains, by weight: 3.40 to 3.70% total carbon, 4.10 to 4.40% equivalent carbon, 2.0 to 2.22% silicon, 0.20 to 0.30% nickel, 0.10 to 0.20% manganese, 0.05 to 0.07% magnesium, up to 0.04% copper, up to 0.05% chromium, less than 0.08% molybdenum, less than 0.10% vanadium, less than 0.002% lead, antimony and bismuth together, less than 0.015% titanium, less than 0.010% cerium, less than 0.010% sulphur, and less than 0.040% phosphorus, and has, as rough cast, a minimum dimension of from 100 to 230 mm together with the following characteristics, as tested on the material in the core of the metal mass, a proportion of ferrite of at least 90%, a tensile strength of at least 360 MPa, an elastic limit of at least 250 MPa, an elongation of at least 14%, and a Charpy impact strength (standardised to KCU) of at least 23 J/cm<2>.
Description
SPECIFICATION
Cast iron castings containing spheroidal graphite
The present invention relates to massive and thick cast iron castings containing spheroidal graphite and which have a ferritic structure and are roughcast.
Iron castings containing spheroidal graphite are generally obtained by incorporating a small amount of magnesium into a suitable grade of base iron; they have much better mechanical characteristics than iron castings containing lamellargraphite. Iron castings containing lamellar graphite are generally used with a perlitic matrix produced directly from castings and hence without structural heat treatment.
Cast iron containing spheroidal graphite can have a perlitic, ferritic or mixed perlitic/ferritic structure, which gives it a wide range of possible mechanical properties. Of these iron structures, ferritic iron containing spheroidal graphite has the highest values of elongation under tension and of impact strength.
This type of cast iron can be obtained either directly from casting, without heat treatment, or after a structural heat treatment. The latter converts the ferrite to ferrite and is carried out at a holding temperature of 950 or 750 C, depending on whether or not the iron, in the crude state, contains iron carbides which, if present, detract from the elongation at break under tension and the impact strength. The required holding time at these temperatures depends on the thickness of the casting, the thicker the casting, the longer the holding time. In bulky castings, the high temperatures and long holding times required are likely to lead to deformation of the casting, even with very carefully adjusted furnace settings.
Because of their slow cooling rate after casting, very thick iron castings containing spheroidal graphite also tend to exhibit segregations in the core of the casting. Such segregations reduce the mechanical characteristics of the casting and can lead to fractures during service.
We have now found that by using a particular composition of iron for casting, it is possible to obtain massive castings which have a ferritic structure without the need for any heat treatment for this purpose and which have a homogeneous structure, even in the core ofthethick parts. Furtherthe castings obtained have an advantageous combination of improved characteristics as regards elastic limit, tensile strength, elongation and impact strength.
According to the present invention, there is provided an iron casting which contains spheroidal graphite and has a ferritic structure and which contains by weight:
3.40 to 3.70% total carbon,
4.10 to 4.40% equivalent carbon,
2.0 to 2.22% silicon,
0.20 to 0.30% nickel, 0.10 to 0.20% manganese, 0.05 to 0.07% magnesium,
up to 0.04% copper,
up to 0.05% chromium,
less than 0.08% molybdenum, less than 0.10% vanadium,
less than 0.002% lead, antimony and
bismuth together, less than 0.015% titanium, less than 0.010% cerium,
less than 0.010% sulphur, and
less than 0.040% phosphorus, the metal mass of the casting, as rough cast, having a minimum dimension of from 100 to 230 mm and the casting having the following characteristics, as tested on the material in the core of the metal mass, a proportion of ferrite of at least 90%, a tensile strength of at least 360 MPa, an elastic limit of at least 250 MPa, an elongation of at least 14%, and a
Charpy impact strength (standardised to KCU) of at least 23 J/cm2.
It is to be understood that the minimum dimension referred to is not necessarily that of the casting itself, since the latter may be hollow, but refers to the minimum dimension of the metallic mass making up any part of the casting.
It is preferred that spheroidal graphite should constitute at least 80% of the total graphite present. The casting is preferably free of carbides or contains not more than a very small amount of carbides.
The castings according to the invention can be processed by known methods, but it is preferred to use a combination of preferred conditions and precautions, as follows: use of a large capacity low-frequency electric induction furnace which enables the chemical composition of the iron, the superheating of the iron melt and the casting temperature, which is preferably from 1300 and 1 330 C, to be precisely controlled; careful choice and control of the starting materials used to make the melt: the raw materiais are selected according to their appearance, their analysis and their purity level; careful choice and control of the nature and the order of introduction of the constituents of the charge; the melting rate; and the nature and the amount of final constituents added to the liquid iron before it leaves the furnace; through desulphurisation of the metal by mixing until the sulphur content is less than 0.010%; the addition of the magnesium content in the form of a ferro-silico-magnesium alloy containing about 15% of magnesium; and inoculation with a ferro-silicon containing about 75% of silicon, at the end of the magnesium treatment, while mixing the metal.
Afterthe inoculation treatment, the iron containing spheroidal graphite thus obtained is run into a mould in the form of the desired casting and is allowed to solidify.
The casting is not subsequently subjected to any high temperature structural heat treatment which, on bulky castings, may tend to cause deformations.
On the other hand, in certain cases, the casting can be subjected to a low temperature stress-relieving heat treatment, for example at about 550 .
The chemical analysis of the massive casting obtained conforms to the above-mentioned analysis range according to the invention. Preferably, the casting is free of carbide or contains only a very small amount of carbides and the proportion of spheroidal graphite is at least 80% of the total graphite.
As will be understood, the essentiai advantages of the massive castings according to the invention con sistofthe remarkable mechanical properties which have been mentioned above, these properties being evidenced even in the core of the thick parts, because the casting has a very homogeneous structure.
The avoidance of a high temperature structural heat treatment brings about several substantial advantages: no deformation likely to jeopardise the dimensions of the finished casting; no oxidation, which would necessitate cleaning of the castings by shot-blasting or sand-blasting; and no requirement for a heating furnace of large dimensions.
In order that the invention may be more fully understood, a particular casting according to the invention will now be described by way of example only and with reference to the accompanying drawings, in which:
Figure lisa cross-section of the casting on a plane passing through its axis of revolution,
Figure 2 is the section (on an enlarged scale) of a block a b c d taken from the wall ab, having a thickness of 230 mm, of the casting, from which block test pieces for testing impact strength and tensile strength are cut, and
Figure 3 is the section (on an enlarged scale) of a block e f g h taken from the same casting, the test pieces being taken from a wall, having a thickness of 110mm,ata depth of55 mm.
The casting is a body of revolution having a weight of 15 tonnes, a height of 1240 mm, an external diameter at the base of4510 mm, and an internal diameter at its upper part of 3100 mm.
This casting is made of a grade of iron containing spheroidal graphite and having the following analysis, by weight: total carbon 3.45% equivalent carbon 4.12% silicon 2.02% sulphur 0.007%
phosphorus 0.020%
manganese 0.130%
magnesium 0.053%
nickel 0.27%
The average ferrite content is 92% and the propor
tion of spheroidal graphite is 80%.
At a b c d, a small block has been cut out, which is
shown on an enlarged scale in Figure 2. In this Fig
ure, the black circle represents the location of the
test piece for testing tensile strength and the black
square represents the location of the test pieces for
testing impact strength.
For this thickness of 230 mm, and at 120 mm from the external wall of the casting, the three measurements of Charpy impact strength, standardised to
KCU, were, in Joules per square centimetre: 26.3, 27.5 and 28.8, that is to say an average of: 27.5 J/cm2.
The average of the measurements on the three test pieces for testing tensile strength was found to be:
279 MPa for the elastic limit at 0.002 (that is to say 0.2%).
363 MPa for the tensile strength.
14.3% for the elongation.
Another block e f g h, shown on an enlarged scale in Figure 3, was cut from this same casting (ef = 210 mm). In this Figure also, the black circle represents the location of the test pieces for testing tensile strength and the black square represents the location of the test pieces for testing impact strength.
At this level, the thickness of the casting is 110 mm. For this thickness of 110 mm, and at about 55 mm from the external wall of the casting, the three measurements of Charpy impact strength, standardised to KCU, were, in Joules per square centimetre: 37.5,39.4 and 36.9, that is to say an average of: 37.9 J/cm2.
The average of the measurements carried out on the three test pieces for testing tensile strength was found to be:
252 MPa for the elastic limit at 0.002 (that is to say 0.2%).
387 MPa for the tensile strength.
25% for the elongation.
Claims (1)
1. An iron casting which contains spheroidal graphite and has a ferritic structure and which contains, by weight:
3.40 to 3.70% total carbon,
4.10 to 4.40% equivalent carbon,
2.0 to 2.22% silicon,
0.20 to 0.30% nickel, 0.10 to 0.20% manganese, 0.05to 0.07% magnesium,
up to 0.04% copper,
up to 0.05% chromium,
less than 0.08% molybdenum,
less than 0.10pro vanadium,
less than 0.002% lead, antimony and
bismuth together, less than 0.015% titanium, less than 0.010% cerium,
less than 0.010% sulphur, and
less than 0.040% phosphorus,
the metal mass of the casting, as rough cast, having
a minimum dimension of from 100 to 230 mm and
the casting having the following characteristics, as
tested on the material in the core of the metal mass,
a proportion of ferrite of at least 90%, a tensile
strength of at least 360 MPa, an elastic limit of at
least 250 MPa, an elongation of at least 14%, and a
Charpy impact strength (standardised to KCU) of at
least 23 J/cm2.
2. A casting according to claim 1, in which
spheroidal graphite constitutes at least 80% of the
total graphite present.
3. An iron casting substantially as herein described with reference to the accompanying drawings.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8014638A FR2486100A1 (en) | 1980-07-01 | 1980-07-01 | MASSIVE SPHEROIDAL GRAPHITE CAST IRON |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB2079315A true GB2079315A (en) | 1982-01-20 |
Family
ID=9243720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8119841A Withdrawn GB2079315A (en) | 1980-07-01 | 1981-06-26 | Ferritic spheroidal-graphite iron for casting thick sections without segregation |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE889425A (en) |
| DE (1) | DE3125986A1 (en) |
| FR (1) | FR2486100A1 (en) |
| GB (1) | GB2079315A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2203448A (en) * | 1987-03-09 | 1988-10-19 | Hitachi Metals Ltd | Nodular cast iron |
| GB2265154A (en) * | 1992-02-18 | 1993-09-22 | Cofap | Nodular cast iron and method for making it |
| US5858127A (en) * | 1996-08-02 | 1999-01-12 | Gunite Corporation | Metal alloys and brake drums made from such alloys |
| RU2156810C1 (en) * | 2000-01-21 | 2000-09-27 | Общество с ограниченной ответственностью "Экономист" | Method for making high strength cast iron with spheroidal and vermiculite type graphite |
| US6572712B2 (en) | 2000-12-14 | 2003-06-03 | Waupaca Foundry, Inc. | Compacted graphite iron brake drum |
| FR2839727A1 (en) * | 2002-05-14 | 2003-11-21 | Technologica Sarl | Production and hot forming of components of spheroidal graphite iron with elevated mechanical characteristics with an essentially bainitic structure |
| FR2866351A1 (en) * | 2004-02-12 | 2005-08-19 | Technologica Sarl | Manufacture of high-precision components from cast iron with spheroidal graphite produces moulded blank of identical volume to component which is then shaped by hot plastic deformation |
| CN103103454A (en) * | 2011-11-15 | 2013-05-15 | 上海施耐德日盛机械(集团)有限公司 | Screw alloy for double-screw air compressor and preparation method of screw alloy |
| WO2017013165A1 (en) * | 2015-07-22 | 2017-01-26 | Eickhoff Giesserei Gmbh | Ferritic cast iron having spheroidal graphite |
| CN112410654A (en) * | 2020-10-30 | 2021-02-26 | 江苏华龙铸铁型材有限公司 | Columnar nodular cast iron material and vertical continuous casting process thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1483304B1 (en) * | 1965-12-07 | 1970-10-22 | Schulten Baumer Dr Rer Pol Uwe | Use of pig iron as the starting material for the production of ductile cast iron with spheroidal graphite in the as-cast state |
| DE1758038A1 (en) * | 1968-03-23 | 1970-12-10 | Rheinische Stahlwerke | Tough cast iron with spheroidal graphite in the as-cast state |
-
1980
- 1980-07-01 FR FR8014638A patent/FR2486100A1/en active Pending
-
1981
- 1981-06-26 GB GB8119841A patent/GB2079315A/en not_active Withdrawn
- 1981-06-29 BE BE0/205246A patent/BE889425A/en unknown
- 1981-07-01 DE DE19813125986 patent/DE3125986A1/en not_active Withdrawn
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2203448A (en) * | 1987-03-09 | 1988-10-19 | Hitachi Metals Ltd | Nodular cast iron |
| GB2203448B (en) * | 1987-03-09 | 1991-05-22 | Hitachi Metals Ltd | Nodular cast iron |
| GB2265154A (en) * | 1992-02-18 | 1993-09-22 | Cofap | Nodular cast iron and method for making it |
| US5858127A (en) * | 1996-08-02 | 1999-01-12 | Gunite Corporation | Metal alloys and brake drums made from such alloys |
| RU2156810C1 (en) * | 2000-01-21 | 2000-09-27 | Общество с ограниченной ответственностью "Экономист" | Method for making high strength cast iron with spheroidal and vermiculite type graphite |
| WO2001053545A1 (en) * | 2000-01-21 | 2001-07-26 | Obschestvo S Ogranichennoi Otvetstvennostiju 'ekonomist' | Method for producing high-duty cast iron with globular and vermiculite graphite |
| US6572712B2 (en) | 2000-12-14 | 2003-06-03 | Waupaca Foundry, Inc. | Compacted graphite iron brake drum |
| FR2839727A1 (en) * | 2002-05-14 | 2003-11-21 | Technologica Sarl | Production and hot forming of components of spheroidal graphite iron with elevated mechanical characteristics with an essentially bainitic structure |
| WO2003100107A1 (en) * | 2002-05-14 | 2003-12-04 | Technologica | Method for production and forming of cast pieces of spheroidal graphite with improved mechanical properties |
| FR2866351A1 (en) * | 2004-02-12 | 2005-08-19 | Technologica Sarl | Manufacture of high-precision components from cast iron with spheroidal graphite produces moulded blank of identical volume to component which is then shaped by hot plastic deformation |
| EP1566459A3 (en) * | 2004-02-12 | 2007-06-27 | Technologica Sarl | Process for producing cast pieces of spheroidal graphite with high geometrical and dimensional precision and improved mechanical properties |
| CN103103454A (en) * | 2011-11-15 | 2013-05-15 | 上海施耐德日盛机械(集团)有限公司 | Screw alloy for double-screw air compressor and preparation method of screw alloy |
| CN103103454B (en) * | 2011-11-15 | 2014-11-05 | 上海施耐德日盛机械(集团)有限公司 | Screw alloy for double-screw air compressor and preparation method of screw alloy |
| WO2017013165A1 (en) * | 2015-07-22 | 2017-01-26 | Eickhoff Giesserei Gmbh | Ferritic cast iron having spheroidal graphite |
| CN107949649A (en) * | 2015-07-22 | 2018-04-20 | 艾柯夫铸造有限责任公司 | Ferrite cast iron with globular graphite |
| CN112410654A (en) * | 2020-10-30 | 2021-02-26 | 江苏华龙铸铁型材有限公司 | Columnar nodular cast iron material and vertical continuous casting process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3125986A1 (en) | 1982-03-11 |
| BE889425A (en) | 1981-12-29 |
| FR2486100A1 (en) | 1982-01-08 |
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