GB1536590A - Preparation of an ultrastable faujasite having hydrogen and metal cations - Google Patents
Preparation of an ultrastable faujasite having hydrogen and metal cationsInfo
- Publication number
- GB1536590A GB1536590A GB2521976A GB2521976A GB1536590A GB 1536590 A GB1536590 A GB 1536590A GB 2521976 A GB2521976 A GB 2521976A GB 2521976 A GB2521976 A GB 2521976A GB 1536590 A GB1536590 A GB 1536590A
- Authority
- GB
- United Kingdom
- Prior art keywords
- faujasite
- per cent
- alkali
- oxide
- calcining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012013 faujasite Substances 0.000 title abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 3
- 239000001257 hydrogen Substances 0.000 title abstract 3
- 150000001768 cations Chemical class 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 3
- -1 hydrogen ions Chemical class 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 1
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
Abstract
1536590 Faujasite treatment W R GRACE & CO 17 June 1976 25219/76 Heading C1A A faujasite is treated to improve its heat and steam solubility by (a) treating a faujasite having a SiO 2 : Al 2 O 3 molar ratio of at least 3À5 to ionexchange with hydrogen ions or cations which thermally decompose to leave hydrogen ions, until the alkali-metal content (expressed as oxide) is less than 1 wt. per cent; (b) calcining the exchanged zeolite and then (c) introducing non- alkali metal cations by exchange at pH 1.5 to 3.5. Preferably step (a) comprises initially exchanging to an alkali-metal content of 1-4 wt. per cent, calcining at 1300-1500‹ F., then further exchanging to below 1 wt. per cent, the faujasite then being separated, washed and dried. Preferably in step (c) 1-6 wt. per cent (calculated as oxide) of rare-earth, Ca, Mg, Co, Ni, Cu and/or iron is incorporated. The treated faujasite may be mixed with 50-95 wt. per cent (based on final composition) of an inorganic oxide matrix (e.g. silica-alumina plus kaolin clay) and used as a catalyst for cracking hydrocarbons.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2521976A GB1536590A (en) | 1976-06-17 | 1976-06-17 | Preparation of an ultrastable faujasite having hydrogen and metal cations |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2521976A GB1536590A (en) | 1976-06-17 | 1976-06-17 | Preparation of an ultrastable faujasite having hydrogen and metal cations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1536590A true GB1536590A (en) | 1978-12-20 |
Family
ID=10224147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2521976A Expired GB1536590A (en) | 1976-06-17 | 1976-06-17 | Preparation of an ultrastable faujasite having hydrogen and metal cations |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1536590A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4612298A (en) * | 1981-12-07 | 1986-09-16 | Ashland Oil, Inc. | Carbo-metallic oil conversion catalysts |
| EP0226781A1 (en) * | 1985-11-08 | 1987-07-01 | Air Products And Chemicals, Inc. | Alkylation of aromatic amines in the presence of acidic, crystalline molecular sieves |
| US4877514A (en) * | 1981-12-07 | 1989-10-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion process and catalysts |
| FR2660578A1 (en) * | 1990-04-09 | 1991-10-11 | Elf Aquitaine | CATALYST BASED ON HIGH-RATIO FAUJASITE IF: AL SYNTHESIS AND ITS APPLICATION TO ACID CATALYSIS REACTIONS CARRIED OUT ON HYDROCARBONIC LOADS. |
| WO2007068752A1 (en) * | 2005-12-16 | 2007-06-21 | Basf Aktiengesellschaft | Nickel-containing catalyst and method for oligomerizing olefins |
| US12533664B2 (en) | 2022-12-19 | 2026-01-27 | Saudi Arabian Oil Company | Type II hydrotreating catalyst for hydrocarbon oil and method for hydrotreating hydrocarbon oil |
-
1976
- 1976-06-17 GB GB2521976A patent/GB1536590A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4612298A (en) * | 1981-12-07 | 1986-09-16 | Ashland Oil, Inc. | Carbo-metallic oil conversion catalysts |
| US4877514A (en) * | 1981-12-07 | 1989-10-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion process and catalysts |
| EP0226781A1 (en) * | 1985-11-08 | 1987-07-01 | Air Products And Chemicals, Inc. | Alkylation of aromatic amines in the presence of acidic, crystalline molecular sieves |
| FR2660578A1 (en) * | 1990-04-09 | 1991-10-11 | Elf Aquitaine | CATALYST BASED ON HIGH-RATIO FAUJASITE IF: AL SYNTHESIS AND ITS APPLICATION TO ACID CATALYSIS REACTIONS CARRIED OUT ON HYDROCARBONIC LOADS. |
| WO1991015293A1 (en) * | 1990-04-09 | 1991-10-17 | Societe Nationale Elf Aquitaine | Catalyst based on a faujasite and its application |
| WO2007068752A1 (en) * | 2005-12-16 | 2007-06-21 | Basf Aktiengesellschaft | Nickel-containing catalyst and method for oligomerizing olefins |
| US12533664B2 (en) | 2022-12-19 | 2026-01-27 | Saudi Arabian Oil Company | Type II hydrotreating catalyst for hydrocarbon oil and method for hydrotreating hydrocarbon oil |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |