GB1529818A - 1,2,4-triazolyl alkanols and their use as pesticides - Google Patents
1,2,4-triazolyl alkanols and their use as pesticidesInfo
- Publication number
- GB1529818A GB1529818A GB49656/75A GB4965675A GB1529818A GB 1529818 A GB1529818 A GB 1529818A GB 49656/75 A GB49656/75 A GB 49656/75A GB 4965675 A GB4965675 A GB 4965675A GB 1529818 A GB1529818 A GB 1529818A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- hydrogen
- halogen
- nov
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
1529818 1,2,4 - Triazole derivatives IMPERIAL CHEMICAL INDUSTRIES Ltd 22 Nov 1976 [3 Dec 1975 16 Nov 1976] 49656/75 and 47666/76 Heading C2C Novel 1,2,4-triazole derivatives of the formula: wherein R<SP>1</SP> and R<SP>2</SP> are independently hydrogen or optionally substituted hydrocarbyl; Y is hydrogen, halogen, nitro, alkyl, alkoxy or optionally substituted amino, n is an integer of 1 to 5; each of the Y groups may be the same or different when n is greater than 1, provided that Y is other than hydrogen or halogen when R<SP>1</SP> and R<SP>2</SP> are both hydrogen; or a salt or metal complex thereof, are prepared by reacting a compound of the formula: either with a reducing agent such as LiAlH 4 or sodium borohydride in an inert solvent, or with a Grignard reagent. The novel compounds possess fungicidal properties. The starting materials of Formula II above may be prepared by reacting 1,2,4-triazole or a salt thereof with an α-haloketone of the formula: wherein X is halogen. Reference has been directed by the Comptroller to Specification 1,464,224.
Priority Applications (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB49656/75A GB1529818A (en) | 1975-12-03 | 1975-12-03 | 1,2,4-triazolyl alkanols and their use as pesticides |
| IE2581/76A IE44186B1 (en) | 1975-12-03 | 1976-11-24 | 1,2,4-triazolyl alkanols and their use as pesticides |
| ZA767086A ZA767086B (en) | 1975-12-03 | 1976-11-26 | Heterocyclic compounds and their use as pesticides |
| US05/745,780 US4690941A (en) | 1975-12-03 | 1976-11-29 | Certain triazole compounds and their use as fungicides |
| NLAANVRAGE7613372,A NL189128C (en) | 1975-12-03 | 1976-12-01 | PROCESS FOR THE PREPARATION OF 1,2,4-TRIAZOLIC COMPOUNDS, METHOD FOR PREPARING PREPARATIONS FOR FUNGI CONTAINING THESE COMPOUNDS, AND METHOD FOR COMBATING PLANT DISEASES |
| AU20144/76A AU2014476A (en) | 1975-12-03 | 1976-12-01 | 1,2,4-triazole derivatives |
| HU76IE768A HU178586B (en) | 1975-12-03 | 1976-12-01 | Fungicide composition containing 1,2,4-triasole derivatives and process for producing the active agents |
| IL51033A IL51033A0 (en) | 1975-12-03 | 1976-12-01 | Triazole derivatives and their use as pesticides |
| BR7608117A BR7608117A (en) | 1975-12-03 | 1976-12-02 | PROCESS TO PREPARE A PESTICIDE COMPOUND, AND COMPOUND OBTAINED |
| IT30044/76A IT1123636B (en) | 1975-12-03 | 1976-12-02 | 1,2,4-TRIAZOLE DERIVATIVES, THEIR PREPARATION AND THEIR USE AS PESTICIDES |
| FR7636427A FR2333799A1 (en) | 1975-12-03 | 1976-12-03 | NEW 1,2,4-TRIAZOLIC COMPOUNDS AND THEIR APPLICATION AS FUNGICIDES |
| DE19762654890 DE2654890A1 (en) | 1975-12-03 | 1976-12-03 | 1,2,4-TRIAZOLE COMPOUNDS AND FUNGICIDALS CONTAINING THESE COMPOUNDS |
| JP51144829A JPS5271471A (en) | 1975-12-03 | 1976-12-03 | 1*2*44triazole compound and pasteurizing agent containing the same |
| US06/322,711 US4472415A (en) | 1975-12-03 | 1981-11-18 | Heterocyclic triazolylethanol compounds and their use as fungicides |
| US06/613,404 US4620011A (en) | 1975-12-03 | 1984-05-24 | Triazolyl ethanol derivatives |
| US07/060,865 US4912121A (en) | 1975-12-03 | 1987-06-12 | Heterocyclic compounds and their use as pesticides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB49656/75A GB1529818A (en) | 1975-12-03 | 1975-12-03 | 1,2,4-triazolyl alkanols and their use as pesticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1529818A true GB1529818A (en) | 1978-10-25 |
Family
ID=10453095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB49656/75A Expired GB1529818A (en) | 1975-12-03 | 1975-12-03 | 1,2,4-triazolyl alkanols and their use as pesticides |
Country Status (3)
| Country | Link |
|---|---|
| BR (1) | BR7608117A (en) |
| GB (1) | GB1529818A (en) |
| ZA (1) | ZA767086B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0015756A1 (en) * | 1979-03-07 | 1980-09-17 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them |
| EP0015639A3 (en) * | 1979-02-09 | 1980-10-01 | Imperial Chemical Industries Plc | Enantiomers of triazole compounds, a process for preparing them, their use as plant fungicides and growth regulating agents and compositions containing them |
| EP0047057A3 (en) * | 1980-08-26 | 1982-05-12 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them |
| EP0047594A3 (en) * | 1980-08-18 | 1982-06-09 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and plant growth regulators and compositions containing them |
| US4532234A (en) * | 1982-09-07 | 1985-07-30 | Basf Aktiengesellschaft | Neopentyl-phenethyltriazoles, their preparation and fungicides containing these compounds |
| GB2156807A (en) * | 1984-04-05 | 1985-10-16 | Ici Plc | Azolyl propanols |
| US4554007A (en) * | 1979-03-20 | 1985-11-19 | Sumitomo Chemical Company, Limited | Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
| EP0086304B1 (en) * | 1982-02-03 | 1986-07-02 | Imperial Chemical Industries Plc | Heterocyclic compounds useful as pesticides and processes for making them |
| EP0153803A3 (en) * | 1984-01-24 | 1986-09-03 | Pfizer Limited | Triazole antifungal agents |
| GB2175301A (en) * | 1985-05-03 | 1986-11-26 | Ici Plc | Plant growth regulant triazole and imidazole |
| EP0194064A3 (en) * | 1985-03-06 | 1988-11-17 | Imperial Chemical Industries Plc | Azolyl substituted aralkyl compounds |
| US5854062A (en) * | 1993-04-16 | 1998-12-29 | Zeneca Limited | Catalyzed enantiomeric selection of 1,2-diols and their cyclization to produce oxiranes |
| EP1304037A4 (en) * | 2000-07-27 | 2004-05-12 | Riken | FLOWERING REGULATORS |
| US6989351B2 (en) | 2000-07-26 | 2006-01-24 | Riken | Metabolic inhibitors against brassinosteroids |
-
1975
- 1975-12-03 GB GB49656/75A patent/GB1529818A/en not_active Expired
-
1976
- 1976-11-26 ZA ZA767086A patent/ZA767086B/en unknown
- 1976-12-02 BR BR7608117A patent/BR7608117A/en unknown
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0015639A3 (en) * | 1979-02-09 | 1980-10-01 | Imperial Chemical Industries Plc | Enantiomers of triazole compounds, a process for preparing them, their use as plant fungicides and growth regulating agents and compositions containing them |
| EP0015756A1 (en) * | 1979-03-07 | 1980-09-17 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them |
| US4554007A (en) * | 1979-03-20 | 1985-11-19 | Sumitomo Chemical Company, Limited | Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
| EP0047594A3 (en) * | 1980-08-18 | 1982-06-09 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and plant growth regulators and compositions containing them |
| EP0047057A3 (en) * | 1980-08-26 | 1982-05-12 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them |
| EP0086304B1 (en) * | 1982-02-03 | 1986-07-02 | Imperial Chemical Industries Plc | Heterocyclic compounds useful as pesticides and processes for making them |
| US4532234A (en) * | 1982-09-07 | 1985-07-30 | Basf Aktiengesellschaft | Neopentyl-phenethyltriazoles, their preparation and fungicides containing these compounds |
| EP0153803A3 (en) * | 1984-01-24 | 1986-09-03 | Pfizer Limited | Triazole antifungal agents |
| US4689337A (en) * | 1984-04-05 | 1987-08-25 | Imperial Chemical Industries Plc | Insecticidal use of azolyl propanols |
| GB2156807A (en) * | 1984-04-05 | 1985-10-16 | Ici Plc | Azolyl propanols |
| AU578940B2 (en) * | 1984-04-05 | 1988-11-10 | Imperial Chemical Industries Plc | 1,1-bis (substituted phenyl)-2-(1H-azol-1-yl) propanol and ethers thereof |
| US4833159A (en) * | 1984-04-05 | 1989-05-23 | Imperial Chemical Industries Plc | Insecticidal azolyl propanols |
| EP0194064A3 (en) * | 1985-03-06 | 1988-11-17 | Imperial Chemical Industries Plc | Azolyl substituted aralkyl compounds |
| GB2175301A (en) * | 1985-05-03 | 1986-11-26 | Ici Plc | Plant growth regulant triazole and imidazole |
| GB2175301B (en) * | 1985-05-03 | 1989-09-13 | Ici Plc | Heterocyclic compounds |
| US4871389A (en) * | 1985-05-03 | 1989-10-03 | Imperial Chemical Industries Plc | Heterocyclic compounds |
| US5854062A (en) * | 1993-04-16 | 1998-12-29 | Zeneca Limited | Catalyzed enantiomeric selection of 1,2-diols and their cyclization to produce oxiranes |
| US5912355A (en) * | 1993-04-16 | 1999-06-15 | Zeneca Limited | Chiral synthesis of tertiary alcohols with a hydrolase |
| US6989351B2 (en) | 2000-07-26 | 2006-01-24 | Riken | Metabolic inhibitors against brassinosteroids |
| EP1304037A4 (en) * | 2000-07-27 | 2004-05-12 | Riken | FLOWERING REGULATORS |
| US6958311B2 (en) | 2000-07-27 | 2005-10-25 | Riken | Flowering regulators |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA767086B (en) | 1977-10-26 |
| BR7608117A (en) | 1977-11-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 704A | Declaration that licence is not available as of right for an excepted use (par. 4a/1977) | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19961121 |