GB1522759A - Polymer entrapped surface active agents - Google Patents
Polymer entrapped surface active agentsInfo
- Publication number
- GB1522759A GB1522759A GB3744276A GB3744276A GB1522759A GB 1522759 A GB1522759 A GB 1522759A GB 3744276 A GB3744276 A GB 3744276A GB 3744276 A GB3744276 A GB 3744276A GB 1522759 A GB1522759 A GB 1522759A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monomer
- methacrylate
- surface active
- acrylate
- active agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004094 surface-active agent Substances 0.000 title abstract 8
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 12
- -1 alkoxyalkyl acrylate Chemical compound 0.000 abstract 8
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 7
- 239000000203 mixture Substances 0.000 abstract 6
- 238000004132 cross linking Methods 0.000 abstract 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 2
- 229910000831 Steel Inorganic materials 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 230000002209 hydrophobic effect Effects 0.000 abstract 2
- 239000010959 steel Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- IAUGBVWVWDTCJV-UHFFFAOYSA-N 1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CCC(S(O)(=O)=O)NC(=O)C=C IAUGBVWVWDTCJV-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 229910000906 Bronze Inorganic materials 0.000 abstract 1
- 229920001651 Cyanoacrylate Polymers 0.000 abstract 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 abstract 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- 238000012644 addition polymerization Methods 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000010974 bronze Substances 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 abstract 1
- 229920006037 cross link polymer Polymers 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 238000004851 dishwashing Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 239000008262 pumice Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 239000008247 solid mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000002459 sustained effect Effects 0.000 abstract 1
- 238000007514 turning Methods 0.000 abstract 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/20—Pills, tablets, discs, rods
- A61K9/2004—Excipients; Inactive ingredients
- A61K9/2022—Organic macromolecular compounds
- A61K9/2027—Organic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyvinyl pyrrolidone, poly(meth)acrylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1522759 Composition with controlled detergent release AIRWICK AG 9 Sept 1976 [10 Sept 1975] 37442/76 Heading C5D A solid composition which will release a sustained and controlled quantity of surface active agent over an extended period of time when contacted with water comprises 20-90 wt. per cent of a cross-linked polymer obtained by the polymerization of 0À5-99À999 mol. per cent of at least one hydrophobic monounsaturated monomer with 0À001-15 mol. per cent of at least one di- or polyunsaturated cross-linking monomer and 0-99À499 mol. per cent of at least one hydrophilic monounsaturated monomer, and having molecularly and homogeneously distributed through the polymer 10-80 wt. per cent of a surface active agent or agents, the amount of cross-linking monomer present being such that the composition is water and solvent insoluble and cohesive without being brittle. The composition may be prepared by carrying out an addition polymerization of the monomers in liquid form in the presence of the surface active agent dissolved in the monomer mixture, the polymerization being initiated by free radical catalysis. The hydrophobic monomer may be an alkyl acrylate or methacrylate having a straight or branched chain C 1 -C 30 group; an alkoxyalkyl acrylate or methacrylate; a haloalkyl acrylate or methacrylate; a cyano acrylate or methacrylate; acrylonitrile; vinyl benzoate; styrene; a 2-ethoxyethyl phenyl acrylate or methacrylate; a cycloaliphatic acrylate or methacrylate; or a vinyl ether. The cross-linking monomer may be a di or polyunsaturated polyester of a polyhydroxyalcohol and an alpha, beta-olefinically unsaturated carboxylic acid; an aliphatic or aromatic polyvinylic monomer; a polyallyl monomer; an allylvinyl monomer; methacrylic acid anhydride; or an alpha, omega-diamino acrylamide. The hydrophilic monomer may be a 3-oxyalkyl or alkyl acrylamide or methacrylamide; a hydroxyalkyl acrylamide or methacrylamide; acrylamide; methacrylamide; acrylamido propane sulphonic acid; an alkyl cellosolve acrylate or methacrylate; an alkylaminoalkyl methacrylate; an ethylenically unsaturated carboxylic acid; or vinyl pyrrolidone. The surface active agent may be an amine salt of an anionic surface active agent, a non-ionic, cationic, or amphoteric surface active agent, or a mixture thereof. Examples relate to the production of blocks of the composition of the invention, which may be inserted between layers of sponge, e.g. polyurethane, with or without abrasive surfaces suitable for dishwashing, automobile washing, and personal hygiene purposes. Another example refers to performing the polymerization in situ on steel wool, polyurethane foam, nylon mesh, cellulose sponge, or granulated material such as pumice, carborundum, or steel, aluminium or bronze turnings.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61206275A | 1975-09-10 | 1975-09-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1522759A true GB1522759A (en) | 1978-08-31 |
Family
ID=24451562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3744276A Expired GB1522759A (en) | 1975-09-10 | 1976-09-09 | Polymer entrapped surface active agents |
Country Status (6)
| Country | Link |
|---|---|
| CH (1) | CH602916A5 (en) |
| DE (1) | DE2640459A1 (en) |
| ES (1) | ES451381A1 (en) |
| FR (1) | FR2323756A1 (en) |
| GB (1) | GB1522759A (en) |
| PT (1) | PT65556B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4189395A (en) | 1978-01-19 | 1980-02-19 | Minnesota Mining And Manufacturing Company | Cleansing pad and method of making the same |
| US4600620A (en) * | 1982-08-13 | 1986-07-15 | Lever Brothers Company | Article suitable for wiping surfaces |
| US4603069A (en) * | 1982-11-26 | 1986-07-29 | Lever Brothers Company | Sheet-like article |
| JPS6239700A (en) * | 1985-08-09 | 1987-02-20 | ユニリ−バ−・ナ−ムロ−ゼ・ベンノ−トシヤ−プ | Product suitable for surface wiping |
| WO1996018718A1 (en) * | 1994-12-14 | 1996-06-20 | Minnesota Mining And Manufacturing Company | Cleansing articles with controlled detergent release and method for their manufacture |
| US6528089B1 (en) | 1997-12-01 | 2003-03-04 | Basf Aktiengesellschaft | Method for producing solid dosing forms |
| EP2502534A1 (en) | 2011-03-22 | 2012-09-26 | Avet AG | A dry, washable and reusable surface cleaning substrate loaded with cleaning composition |
| CN109135944A (en) * | 2018-08-20 | 2019-01-04 | 南京工业职业技术学院 | A kind of cleaning solution and preparation method thereof based on free radical ultraviolet polymerization |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH639416A5 (en) * | 1977-06-27 | 1983-11-15 | Akzo Nv | DETERGENT COMPOSITION CONTAINING ALKALICARBONATE. |
| FR2485370A1 (en) * | 1980-06-30 | 1981-12-31 | Commissariat Energie Atomique | INERTE SUPPORT IN RETICULATED COPOLYMER, METHOD FOR PREPARING THE SAME AND USE THEREOF FOR PRODUCING DELAYED MEDICAMENTS |
| ES2091001T3 (en) * | 1992-04-29 | 1996-10-16 | Unilever Nv | CAPSULE CONTAINING A SUSCEPTIBLE DEGRADATION COMPONENT AND A COMPOSITE POLYMER. |
-
1976
- 1976-09-06 CH CH1128976A patent/CH602916A5/xx not_active IP Right Cessation
- 1976-09-07 PT PT6555676A patent/PT65556B/en unknown
- 1976-09-08 DE DE19762640459 patent/DE2640459A1/en active Pending
- 1976-09-09 FR FR7627181A patent/FR2323756A1/en not_active Withdrawn
- 1976-09-09 ES ES451381A patent/ES451381A1/en not_active Expired
- 1976-09-09 GB GB3744276A patent/GB1522759A/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4189395A (en) | 1978-01-19 | 1980-02-19 | Minnesota Mining And Manufacturing Company | Cleansing pad and method of making the same |
| US4600620A (en) * | 1982-08-13 | 1986-07-15 | Lever Brothers Company | Article suitable for wiping surfaces |
| US4603069A (en) * | 1982-11-26 | 1986-07-29 | Lever Brothers Company | Sheet-like article |
| JPS6239700A (en) * | 1985-08-09 | 1987-02-20 | ユニリ−バ−・ナ−ムロ−ゼ・ベンノ−トシヤ−プ | Product suitable for surface wiping |
| EP0211664A1 (en) * | 1985-08-09 | 1987-02-25 | Unilever Plc | Article suitable for wiping surfaces |
| WO1996018718A1 (en) * | 1994-12-14 | 1996-06-20 | Minnesota Mining And Manufacturing Company | Cleansing articles with controlled detergent release and method for their manufacture |
| US6528089B1 (en) | 1997-12-01 | 2003-03-04 | Basf Aktiengesellschaft | Method for producing solid dosing forms |
| EP2502534A1 (en) | 2011-03-22 | 2012-09-26 | Avet AG | A dry, washable and reusable surface cleaning substrate loaded with cleaning composition |
| WO2012127000A1 (en) | 2011-03-22 | 2012-09-27 | Avet Ag | A dry, washable and reusable surface cleaning substrate loaded with cleaning composition |
| US9532695B2 (en) | 2011-03-22 | 2017-01-03 | Avet Ag | Dry, washable and reusable surface cleaning substrate loaded with cleaning composition |
| CN109135944A (en) * | 2018-08-20 | 2019-01-04 | 南京工业职业技术学院 | A kind of cleaning solution and preparation method thereof based on free radical ultraviolet polymerization |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2640459A1 (en) | 1977-03-31 |
| PT65556A (en) | 1976-10-01 |
| PT65556B (en) | 1978-03-28 |
| CH602916A5 (en) | 1978-08-15 |
| ES451381A1 (en) | 1977-10-01 |
| FR2323756A1 (en) | 1977-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |