GB1519473A - Process for the preparation of ethylene-butadiene copolymers - Google Patents
Process for the preparation of ethylene-butadiene copolymersInfo
- Publication number
- GB1519473A GB1519473A GB30117/75A GB3011775A GB1519473A GB 1519473 A GB1519473 A GB 1519473A GB 30117/75 A GB30117/75 A GB 30117/75A GB 3011775 A GB3011775 A GB 3011775A GB 1519473 A GB1519473 A GB 1519473A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- trichloroacetic acid
- butadiene
- compound
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 238000007334 copolymerization reaction Methods 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 abstract 2
- 239000007848 Bronsted acid Substances 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 abstract 1
- 150000005826 halohydrocarbons Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- VHFUHRXYRYWELT-UHFFFAOYSA-N methyl 2,2,2-trichloroacetate Chemical compound COC(=O)C(Cl)(Cl)Cl VHFUHRXYRYWELT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- PVFOMCVHYWHZJE-UHFFFAOYSA-N trichloroacetyl chloride Chemical compound ClC(=O)C(Cl)(Cl)Cl PVFOMCVHYWHZJE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003682 vanadium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1519473 Copolymerization of ethylene and butadiene ANIC SpA 17 July 1975 [2 Aug 1974] 30117/75 Heading C3P Ethylene and butadiene are copolymerized in a hydrocarbon or halohydrocarbon solvent using a catalyst system comprising (a) a vanadium compound (b) a compound of the formula AlR1R2X where R1 and R2 are selected from hydrogen and C1-C18 hydrocarbyl groups and X is halogen (c) a Lewis or Bronsted acid other than an organic compound containing a -CX3 group where X is halogen and (d) an organic-compound containing a -CX3 group. In the examples the copolymerization is carried out in toluene in the presence of hydrogen vanadium di or triacetylacetonate, AlEt2Cl, and either AlEtCl2 and one of methyltrichloroacetate, CCl4, trichloroacetic acid or trichloroacetic acid chloride or trichloroacetic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25933/74A IT1017868B (en) | 1974-08-02 | 1974-08-02 | PROCEDURE FOR THE PREPARATION IN HIGH YIELD OF COPOLYMERS OF ETHYLENE WITH 1.3 BUTADIENE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1519473A true GB1519473A (en) | 1978-07-26 |
Family
ID=11218175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30117/75A Expired GB1519473A (en) | 1974-08-02 | 1975-07-17 | Process for the preparation of ethylene-butadiene copolymers |
Country Status (25)
| Country | Link |
|---|---|
| JP (1) | JPS5137983A (en) |
| AT (1) | AT342859B (en) |
| AU (1) | AU8286475A (en) |
| BE (1) | BE832053A (en) |
| BR (1) | BR7504978A (en) |
| CA (1) | CA1043943A (en) |
| DD (1) | DD119253A5 (en) |
| DE (1) | DE2534493C2 (en) |
| DK (1) | DK351575A (en) |
| ES (1) | ES440486A1 (en) |
| FR (1) | FR2280654A1 (en) |
| GB (1) | GB1519473A (en) |
| HU (1) | HU170894B (en) |
| IL (1) | IL47730A0 (en) |
| IT (1) | IT1017868B (en) |
| LU (1) | LU73122A1 (en) |
| MW (1) | MW4275A1 (en) |
| NL (1) | NL7509283A (en) |
| NO (1) | NO752703L (en) |
| RO (1) | RO68285A (en) |
| SE (1) | SE7508740L (en) |
| SU (1) | SU707523A3 (en) |
| TR (1) | TR18961A (en) |
| ZA (2) | ZA754377B (en) |
| ZM (1) | ZM10075A1 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322450A (en) | 1979-09-24 | 1982-03-30 | Scott Paper Company | Surface replication on a coated substrate |
| US4427732A (en) | 1980-10-02 | 1984-01-24 | Scott Paper Company | Surface replication on a coated substrate |
| US5332793A (en) * | 1993-06-28 | 1994-07-26 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5342907A (en) * | 1993-06-28 | 1994-08-30 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5410003A (en) * | 1994-03-31 | 1995-04-25 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylenes |
| US5416053A (en) * | 1993-06-28 | 1995-05-16 | Union Carbide Chemicals & Plastics Technology Corporation | Homogenous polyethylenes and ethylene/propylene copolymers rubbers |
| US5480850A (en) * | 1993-06-28 | 1996-01-02 | Union Carbide Chemical & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5492986A (en) * | 1994-03-31 | 1996-02-20 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing homogeneous polyethylenes |
| US5502127A (en) * | 1994-03-31 | 1996-03-26 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylene |
| EP3344667A4 (en) * | 2015-08-31 | 2019-07-31 | Bridgestone Corporation | COPOLYMERIZATION OF POLYENES AND ALKENES |
| CN119192498A (en) * | 2023-06-26 | 2024-12-27 | 中国石油化工股份有限公司 | Ethylene-butadiene polymer and preparation method thereof and vulcanized rubber |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52156195A (en) * | 1976-06-22 | 1977-12-26 | Mitsubishi Chem Ind Ltd | Production of solid catalyst and olefin polymers |
| JPS52156795A (en) * | 1976-06-23 | 1977-12-27 | Mitsubishi Chem Ind Ltd | Production of solid catalyst and olefin polymers |
| US4607019A (en) * | 1984-12-12 | 1986-08-19 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| US4579835A (en) * | 1984-12-12 | 1986-04-01 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use |
| IT1263862B (en) * | 1993-03-31 | 1996-09-04 | Enichem Polimeri | PROCEDURE FOR THE (CO) POLYMERIZATION OF ETHYLENE |
| IT1269805B (en) * | 1994-05-20 | 1997-04-15 | Enichem Spa | CATALYST FOR THE (CO) POLYMERIZATION OF ETHYLENE AND PROCEDURE FOR ITS OBTAINMENT |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3055875A (en) * | 1960-07-05 | 1962-09-25 | Union Carbide Corp | Modified ethylene polymers |
| US3301834A (en) * | 1963-09-11 | 1967-01-31 | Hercules Inc | Polymerization of olefins |
| FR1477275A (en) * | 1965-05-08 | 1967-04-14 | Huels Chemische Werke Ag | Process for preparing high molecular weight amorphous copolymers, from 1-olefins alone or in mixture with poly-olefins |
| DE1720643A1 (en) * | 1967-04-05 | 1971-06-16 | Bunawerke Huels Gmbh | Process for the production of amorphous copolymers from ethylene and higher alpha-olefins in suspensions with modified organometallic mixed catalysts |
-
1974
- 1974-08-02 IT IT25933/74A patent/IT1017868B/en active
-
1975
- 1975-07-08 ZA ZA00754377A patent/ZA754377B/en unknown
- 1975-07-08 ZA ZA00754374A patent/ZA754374B/en unknown
- 1975-07-09 AU AU82864/75A patent/AU8286475A/en not_active Expired
- 1975-07-12 MW MW42/75A patent/MW4275A1/en unknown
- 1975-07-17 GB GB30117/75A patent/GB1519473A/en not_active Expired
- 1975-07-18 IL IL47730A patent/IL47730A0/en unknown
- 1975-07-21 CA CA231,871A patent/CA1043943A/en not_active Expired
- 1975-07-22 ZM ZM100/75A patent/ZM10075A1/en unknown
- 1975-07-29 ES ES440486A patent/ES440486A1/en not_active Expired
- 1975-07-29 FR FR7523696A patent/FR2280654A1/en active Granted
- 1975-07-29 TR TR18961A patent/TR18961A/en unknown
- 1975-07-30 DD DD187569A patent/DD119253A5/xx unknown
- 1975-07-30 SU SU752156911A patent/SU707523A3/en active
- 1975-07-31 LU LU73122A patent/LU73122A1/xx unknown
- 1975-08-01 SE SE7508740A patent/SE7508740L/en unknown
- 1975-08-01 DK DK351575A patent/DK351575A/en unknown
- 1975-08-01 NO NO752703A patent/NO752703L/no unknown
- 1975-08-01 DE DE2534493A patent/DE2534493C2/en not_active Expired
- 1975-08-01 BE BE158880A patent/BE832053A/en unknown
- 1975-08-01 JP JP50093238A patent/JPS5137983A/ja active Pending
- 1975-08-01 AT AT599875A patent/AT342859B/en not_active IP Right Cessation
- 1975-08-01 HU HU75SA00002829A patent/HU170894B/en unknown
- 1975-08-02 RO RO7583049A patent/RO68285A/en unknown
- 1975-08-04 NL NL7509283A patent/NL7509283A/en not_active Application Discontinuation
- 1975-08-04 BR BR7504978*A patent/BR7504978A/en unknown
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322450A (en) | 1979-09-24 | 1982-03-30 | Scott Paper Company | Surface replication on a coated substrate |
| US4427732A (en) | 1980-10-02 | 1984-01-24 | Scott Paper Company | Surface replication on a coated substrate |
| US5480850A (en) * | 1993-06-28 | 1996-01-02 | Union Carbide Chemical & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5342907A (en) * | 1993-06-28 | 1994-08-30 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5416053A (en) * | 1993-06-28 | 1995-05-16 | Union Carbide Chemicals & Plastics Technology Corporation | Homogenous polyethylenes and ethylene/propylene copolymers rubbers |
| US5332793A (en) * | 1993-06-28 | 1994-07-26 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5410003A (en) * | 1994-03-31 | 1995-04-25 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylenes |
| US5492986A (en) * | 1994-03-31 | 1996-02-20 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing homogeneous polyethylenes |
| US5502127A (en) * | 1994-03-31 | 1996-03-26 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylene |
| EP3344667A4 (en) * | 2015-08-31 | 2019-07-31 | Bridgestone Corporation | COPOLYMERIZATION OF POLYENES AND ALKENES |
| US10882933B2 (en) | 2015-08-31 | 2021-01-05 | Bridgestone Corporation | Copolymerization of polyenes and alkenes |
| CN119192498A (en) * | 2023-06-26 | 2024-12-27 | 中国石油化工股份有限公司 | Ethylene-butadiene polymer and preparation method thereof and vulcanized rubber |
| CN119192498B (en) * | 2023-06-26 | 2025-11-11 | 中国石油化工股份有限公司 | Ethylene-butadiene polymer, process for producing the same, and vulcanized rubber |
Also Published As
| Publication number | Publication date |
|---|---|
| LU73122A1 (en) | 1976-03-02 |
| DE2534493C2 (en) | 1982-02-25 |
| MW4275A1 (en) | 1976-10-13 |
| ZM10075A1 (en) | 1976-04-21 |
| AT342859B (en) | 1978-04-25 |
| CA1043943A (en) | 1978-12-05 |
| FR2280654B1 (en) | 1979-08-24 |
| SU707523A3 (en) | 1979-12-30 |
| ES440486A1 (en) | 1977-02-16 |
| JPS5137983A (en) | 1976-03-30 |
| NL7509283A (en) | 1976-02-04 |
| DE2534493A1 (en) | 1976-02-12 |
| ATA599875A (en) | 1977-08-15 |
| RO68285A (en) | 1980-08-15 |
| ZA754377B (en) | 1976-07-28 |
| BR7504978A (en) | 1976-07-27 |
| TR18961A (en) | 1978-01-19 |
| FR2280654A1 (en) | 1976-02-27 |
| IL47730A0 (en) | 1975-10-15 |
| SE7508740L (en) | 1976-02-03 |
| ZA754374B (en) | 1976-07-28 |
| DD119253A5 (en) | 1976-04-12 |
| DK351575A (en) | 1976-02-03 |
| AU8286475A (en) | 1977-01-13 |
| BE832053A (en) | 1976-02-02 |
| NO752703L (en) | 1976-02-03 |
| HU170894B (en) | 1977-09-28 |
| IT1017868B (en) | 1977-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |