GB1518342A - Inhibiting corrosion - Google Patents
Inhibiting corrosionInfo
- Publication number
- GB1518342A GB1518342A GB22657/75A GB2265775A GB1518342A GB 1518342 A GB1518342 A GB 1518342A GB 22657/75 A GB22657/75 A GB 22657/75A GB 2265775 A GB2265775 A GB 2265775A GB 1518342 A GB1518342 A GB 1518342A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amine
- mono
- acid
- phosphoric acid
- ethylhexyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000007797 corrosion Effects 0.000 title abstract 4
- 238000005260 corrosion Methods 0.000 title abstract 4
- 230000002401 inhibitory effect Effects 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 8
- -1 amine salt Chemical class 0.000 abstract 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 3
- 239000000314 lubricant Substances 0.000 abstract 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- XEGAKAFEBOXGPV-UHFFFAOYSA-N 2,3,3a,4-tetrahydro-1h-benzotriazole Chemical compound C1C=CC=C2NNNC12 XEGAKAFEBOXGPV-UHFFFAOYSA-N 0.000 abstract 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012964 benzotriazole Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- CJYAHFDVLLKRNX-UHFFFAOYSA-N dibutyl 2-ethylhexyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCC(CC)CCCC CJYAHFDVLLKRNX-UHFFFAOYSA-N 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 239000010696 ester oil Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000004519 grease Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- OMFOZENGCKJYTL-UHFFFAOYSA-N octadec-1-enyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCC=COP(O)(O)=O OMFOZENGCKJYTL-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 150000003852 triazoles Chemical class 0.000 abstract 1
- OHRVKCZTBPSUIK-UHFFFAOYSA-N tridodecyl phosphate Chemical group CCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCC)OCCCCCCCCCCCC OHRVKCZTBPSUIK-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
1518342 Corrosion inhibitor RHEINCHEMIE RHEINAU GmbH 23 May 1975 [20 June 1974] 22657/75 Heading C7E [Also in Division C5] A corrosion inhibitor for metals for addition to a lubricant consists of a solution of benzotriazole and/or tetrahydrobenzotriazole in a solvent chosen from (1) an amine salt of a carboxylic acid (2) an amine salt of a phosphoric acid (3) a phosphoric acid trialkyl ester and/or (4) an amine alkyl benzene sulphonate, and optionally also contains a free amine, a free carboxylic acid, free phosphoric acid or a mono-or di-ester of phosphoric acid. The acid in (1) may be an aliphatic C 6 -C 18 mono-carboxylic acid, e.g. capric, caproic, i-nonanic, i-palmitic or oleic and the amine n-hexyl, t-octyl, t-isotetradecyl, oleyl, dicyclohexyl-amine or aniline. In (2), the amine may be the same, the acid H 3 PO 4 or its mono- or di-alkyl esters, e.g. mono-butyl-, di-butyl-, di-2-ethylhexyl or mono-octadecenyl-phosphate. Compound (3) may be tri-butyl-, tri-2-ethylhexyl-, tridodecyl- or dibutyl 2-ethylhexyl-phosphate; (4) may be a salt of an amine as in (1) above with an alkylbenzene sulphonic acid having 1-18C atoms in the alkyl group. The triazole is present in amount 0À01-0À1 wt. per cent in the lubricant, which may be a mineral oil on a paraffin, naphthenic, aromatic or mixed basis, and/or a synthesis oil, e.g. an ester oil or alkyl benzene, or a lubricating grease, and inhibits corrosion of Cu in contact with the lubricant.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2429512A DE2429512C2 (en) | 1974-06-20 | 1974-06-20 | Use of a concentrated solution of benzotriazole and / or tetrahydrobenzotriazole as a corrosion protection agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1518342A true GB1518342A (en) | 1978-07-19 |
Family
ID=5918459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22657/75A Expired GB1518342A (en) | 1974-06-20 | 1975-05-23 | Inhibiting corrosion |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS616153B2 (en) |
| DE (1) | DE2429512C2 (en) |
| FR (1) | FR2275568A1 (en) |
| GB (1) | GB1518342A (en) |
| IT (1) | IT1044127B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2414547A1 (en) * | 1978-01-11 | 1979-08-10 | Exxon Research Engineering Co | Synthetic ester lubricants - contg. ammonium phosphate ester and ammonium organo-sulphonate, esp. useful as aircraft turbine lubricants |
| FR2414548A1 (en) * | 1978-01-13 | 1979-08-10 | Exxon Research Engineering Co | Synthetic ester lubricants for aircraft engines - contg. ammonium organo-sulphonate as EP additive |
| US4342596A (en) | 1980-04-10 | 1982-08-03 | Conner Alvin James Sen | Non-petroleum based metal corrosion inhibitor |
| US6046144A (en) * | 1997-06-02 | 2000-04-04 | R.T. Vanderbilt Co., Inc. | Combination of phosphate based additives and sulfonate salts for hydraulic fluids and lubricating compositions |
| RU2353708C1 (en) * | 2007-07-20 | 2009-04-27 | Институт органической химии Уфимского научного центра РАН | Protection method of steel against corrosion in mineralised trolly medium |
| WO2010037746A1 (en) * | 2008-09-30 | 2010-04-08 | Shell Internationale Research Maatschappij B.V. | Grease composition |
| RU2448198C2 (en) * | 2010-07-08 | 2012-04-20 | Государственное учреждение "Научно-исследовательский технологический институт гербицидов и регуляторов роста растений с опытно-экспериментальным производством Академии наук Республики Башкортостан" | Metal corrosion inhibition method |
| US8236205B1 (en) | 2011-03-11 | 2012-08-07 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles and other triazoles and methods for using same |
| US8236204B1 (en) | 2011-03-11 | 2012-08-07 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles solubilized in activating solvents and methods for using same |
| CN105392924A (en) * | 2013-10-17 | 2016-03-09 | 株式会社自动网络技术研究所 | Composition having oil film retention function, anticorrosion agent using same, and insulated electric wire with terminal |
| US9309205B2 (en) | 2013-10-28 | 2016-04-12 | Wincom, Inc. | Filtration process for purifying liquid azole heteroaromatic compound-containing mixtures |
| US10858585B2 (en) | 2018-01-03 | 2020-12-08 | Ecolab Usa Inc. | Benzotriazole derivatives as corrosion inhibitors |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6039179A (en) * | 1983-08-12 | 1985-02-28 | Neos Co Ltd | Rust and dust preventing agent |
| US4511481A (en) * | 1983-08-31 | 1985-04-16 | Mobil Oil Corporation | Multifunctional additives |
| JPS6077868A (en) * | 1984-07-20 | 1985-05-02 | 凸版印刷株式会社 | extruded tube container |
| FR2687412B1 (en) * | 1992-02-14 | 1998-06-05 | Atochem Elf Sa | CARBOXYLIC ACID CORROSION INHIBITOR COMPOSITION AND ITS APPLICATION FOR INHIBITING CORROSION. |
| DE69325828D1 (en) * | 1992-02-14 | 1999-09-09 | Atochem Elf Sa | Use to inhibit copper corrosion of a composition consisting of heptansoiuce or its derivatives and sodium tetraborate. |
| DE69519690T2 (en) * | 1994-02-11 | 2001-06-28 | The Lubrizol Corp., Wickliffe | Metal-free hydraulic fluid with amine salt |
| JP2009108263A (en) * | 2007-10-31 | 2009-05-21 | Nsk Ltd | Grease composition and rolling bearing |
| JP5476077B2 (en) * | 2008-09-30 | 2014-04-23 | 昭和シェル石油株式会社 | Grease composition for resin lubrication |
| JP5476076B2 (en) * | 2008-09-30 | 2014-04-23 | 昭和シェル石油株式会社 | Grease composition for resin lubrication |
| JP5643634B2 (en) * | 2010-02-15 | 2014-12-17 | 昭和シェル石油株式会社 | Grease composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL108246C (en) * | 1956-05-14 | |||
| GB811675A (en) * | 1956-08-29 | 1959-04-08 | Ilford Ltd | Improvements in or relating to anti-freeze compositions |
| NL124784C (en) * | 1963-02-06 | |||
| FR1538431A (en) * | 1965-03-11 | 1968-09-06 | Dow Chemical Co | Non-corrosive dry cleaning composition |
| JPS522731B2 (en) * | 1972-06-03 | 1977-01-24 |
-
1974
- 1974-06-20 DE DE2429512A patent/DE2429512C2/en not_active Expired
-
1975
- 1975-05-23 GB GB22657/75A patent/GB1518342A/en not_active Expired
- 1975-06-18 IT IT50093/75A patent/IT1044127B/en active
- 1975-06-18 JP JP50073250A patent/JPS616153B2/ja not_active Expired
- 1975-06-20 FR FR7519393A patent/FR2275568A1/en active Granted
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2414547A1 (en) * | 1978-01-11 | 1979-08-10 | Exxon Research Engineering Co | Synthetic ester lubricants - contg. ammonium phosphate ester and ammonium organo-sulphonate, esp. useful as aircraft turbine lubricants |
| FR2414548A1 (en) * | 1978-01-13 | 1979-08-10 | Exxon Research Engineering Co | Synthetic ester lubricants for aircraft engines - contg. ammonium organo-sulphonate as EP additive |
| US4342596A (en) | 1980-04-10 | 1982-08-03 | Conner Alvin James Sen | Non-petroleum based metal corrosion inhibitor |
| US6046144A (en) * | 1997-06-02 | 2000-04-04 | R.T. Vanderbilt Co., Inc. | Combination of phosphate based additives and sulfonate salts for hydraulic fluids and lubricating compositions |
| RU2353708C1 (en) * | 2007-07-20 | 2009-04-27 | Институт органической химии Уфимского научного центра РАН | Protection method of steel against corrosion in mineralised trolly medium |
| CN102239240B (en) * | 2008-09-30 | 2013-08-28 | 国际壳牌研究有限公司 | Grease composition |
| WO2010037746A1 (en) * | 2008-09-30 | 2010-04-08 | Shell Internationale Research Maatschappij B.V. | Grease composition |
| US9096813B2 (en) | 2008-09-30 | 2015-08-04 | Shell Oil Company | Grease composition |
| RU2448198C2 (en) * | 2010-07-08 | 2012-04-20 | Государственное учреждение "Научно-исследовательский технологический институт гербицидов и регуляторов роста растений с опытно-экспериментальным производством Академии наук Республики Башкортостан" | Metal corrosion inhibition method |
| US8535568B2 (en) | 2011-03-11 | 2013-09-17 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles solubilized in activating solvents and methods for using same |
| US8236204B1 (en) | 2011-03-11 | 2012-08-07 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles solubilized in activating solvents and methods for using same |
| US8535567B2 (en) | 2011-03-11 | 2013-09-17 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles solubilized in activating solvents and methods for using same |
| US8535569B2 (en) | 2011-03-11 | 2013-09-17 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles and other triazoles and methods for using same |
| US8236205B1 (en) | 2011-03-11 | 2012-08-07 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles and other triazoles and methods for using same |
| US9447322B2 (en) | 2011-03-11 | 2016-09-20 | Wincom, Inc. | Corrosion inhibitor compositions comprising tetrahydrobenzotriazoles solubilized in activating solvents and methods for using same |
| CN105392924A (en) * | 2013-10-17 | 2016-03-09 | 株式会社自动网络技术研究所 | Composition having oil film retention function, anticorrosion agent using same, and insulated electric wire with terminal |
| EP2980273A4 (en) * | 2013-10-17 | 2016-07-20 | Autonetworks Technologies Ltd | COMPOSITION HAVING OIL FILM RETENTION FUNCTION, ANTI-CORROSION AGENT USING THE SAME, AND ISOLATED ELECTRIC WIRE WITH TERMINAL |
| US20160211053A1 (en) * | 2013-10-17 | 2016-07-21 | Autonetworks Technologies, Ltd. | Composition having oil film retention function, anticorrosive agent using same, and insulated terminated electric wire |
| US10559403B2 (en) | 2013-10-17 | 2020-02-11 | Autonetworks Technologies, Ltd. | Composition having oil film retention function, anticorrosive agent using same, and insulated terminated electric wire |
| US9309205B2 (en) | 2013-10-28 | 2016-04-12 | Wincom, Inc. | Filtration process for purifying liquid azole heteroaromatic compound-containing mixtures |
| US9802905B2 (en) | 2013-10-28 | 2017-10-31 | Wincom, Inc. | Filtration process for purifying liquid azole heteroaromatic compound-containing mixtures |
| US10858585B2 (en) | 2018-01-03 | 2020-12-08 | Ecolab Usa Inc. | Benzotriazole derivatives as corrosion inhibitors |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2275568A1 (en) | 1976-01-16 |
| JPS5114150A (en) | 1976-02-04 |
| FR2275568B1 (en) | 1982-07-30 |
| DE2429512C2 (en) | 1982-04-01 |
| JPS616153B2 (en) | 1986-02-24 |
| DE2429512A1 (en) | 1976-01-08 |
| IT1044127B (en) | 1980-03-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |