GB1517067A - Production of dispersions of polyvinyl acetate - Google Patents
Production of dispersions of polyvinyl acetateInfo
- Publication number
- GB1517067A GB1517067A GB26003/76A GB2600376A GB1517067A GB 1517067 A GB1517067 A GB 1517067A GB 26003/76 A GB26003/76 A GB 26003/76A GB 2600376 A GB2600376 A GB 2600376A GB 1517067 A GB1517067 A GB 1517067A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetate
- component
- polyvinyl
- dispersions
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title abstract 5
- 229920002689 polyvinyl acetate Polymers 0.000 title abstract 3
- 239000011118 polyvinyl acetate Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 4
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 239000003607 modifier Substances 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- VFGRALUHHHDIQI-UHFFFAOYSA-N butyl 2-hydroxyacetate Chemical compound CCCCOC(=O)CO VFGRALUHHHDIQI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 abstract 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 229910021472 group 8 element Inorganic materials 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
1517067 Production of polyvinyl acetategrafted-PVA dispersions ANIC SpA 23 June 1976 [24 June 1975] 26003/76 Heading C3P An aqueous dispersion of polyvinyl acetate in which the polyvinyl acetate is grafted on to a polyvinyl alcohol, is prepared by polymerizing vinyl acetate in aqueous dispersion in the presence of (a) at least one peroxide and/or persulphate, (b) a reducing agent comprising at least one mono- and/or dicarboxylic acid, (c) an acetate and/or sulphate of an element of Group VIII of the Periodic Table, (d) a bicarbonate and/or an acetate of an alkali and/or alkaline earth metal and (e) polyvinyl alcohol or a partially esterified polyvinyl alcohol; component (d) being added throughout the polymerization. An optional additional component is a modifier which is an aldehyde with a boiling point under 70 C. or an ester of a butyl alcohol with a boiling point above 150 C. Specific examples of component (b) are formic acid, tartaric acid, maleic acid and oxalic acid. Preferred Group VIII elements for the salt of component (c) are Fe and Co. Specific optional modifiers are propionaldehyde, acetaldehyde, crotonaldehyde, butyraldehyde, and butyl glycolate. The dispersions are used as adhesives.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT24703/75A IT1039354B (en) | 1975-06-24 | 1975-06-24 | PROCEDURE FOR THE PRODUCTION OF POLYACETOVINYL DISPERSIONS AND THUS OBTAINED DISPERSIONS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1517067A true GB1517067A (en) | 1978-07-12 |
Family
ID=11214455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26003/76A Expired GB1517067A (en) | 1975-06-24 | 1976-06-23 | Production of dispersions of polyvinyl acetate |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS5952167B2 (en) |
| AT (1) | AT353005B (en) |
| BE (1) | BE843350A (en) |
| CH (1) | CH623834A5 (en) |
| DE (1) | DE2625859B2 (en) |
| DK (1) | DK145894C (en) |
| EG (1) | EG12447A (en) |
| ES (1) | ES449476A1 (en) |
| FI (1) | FI61501C (en) |
| FR (1) | FR2315509A1 (en) |
| GB (1) | GB1517067A (en) |
| IE (1) | IE43835B1 (en) |
| IT (1) | IT1039354B (en) |
| LU (1) | LU75201A1 (en) |
| NL (1) | NL7606870A (en) |
| NO (1) | NO145577C (en) |
| PT (1) | PT65260B (en) |
| SE (1) | SE422327B (en) |
| TR (1) | TR18814A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108219043A (en) * | 2016-12-21 | 2018-06-29 | 中国石化集团四川维尼纶厂 | A kind of preparation method of polyvinyl acetate emulsion |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57100107A (en) * | 1980-12-12 | 1982-06-22 | Daicel Chem Ind Ltd | Preparation of adhesive |
| JPS59109568A (en) * | 1982-12-14 | 1984-06-25 | Daicel Chem Ind Ltd | High-speed adhesive for paper |
| CA1261538A (en) * | 1984-07-19 | 1989-09-26 | Ronald W. Novak | Aldehyde or imine oxygen scavengers for vinyl polymerizations |
| GB8729702D0 (en) * | 1987-12-21 | 1988-02-03 | Unilever Plc | Emulsion polymerisation |
| JP2707597B2 (en) * | 1988-05-16 | 1998-01-28 | 三井石油化学工業株式会社 | Method for producing fluorine-containing polyolefin |
| DE102006006579A1 (en) * | 2006-02-13 | 2007-08-23 | Wacker Polymer Systems Gmbh & Co. Kg | Process for the production of molded parts from cork particles |
| US9733003B2 (en) | 2012-12-27 | 2017-08-15 | OXEN, Inc. | Ice maker |
| JP2019031581A (en) * | 2015-12-28 | 2019-02-28 | 株式会社クラレ | Low degree of polymerization vinyl alcohol polymer powder excellent in hue and method for producing the same |
| WO2025254140A1 (en) * | 2024-06-05 | 2025-12-11 | 株式会社クラレ | Method for producing modified poly(vinyl alcohol) |
-
1975
- 1975-06-24 IT IT24703/75A patent/IT1039354B/en active
-
1976
- 1976-06-09 DE DE2625859A patent/DE2625859B2/en not_active Withdrawn
- 1976-06-15 FR FR7618070A patent/FR2315509A1/en active Granted
- 1976-06-16 DK DK269576A patent/DK145894C/en not_active IP Right Cessation
- 1976-06-16 SE SE7606890A patent/SE422327B/en unknown
- 1976-06-18 ES ES449476A patent/ES449476A1/en not_active Expired
- 1976-06-20 EG EG363/76A patent/EG12447A/en active
- 1976-06-21 FI FI761789A patent/FI61501C/en not_active IP Right Cessation
- 1976-06-21 LU LU75201A patent/LU75201A1/xx unknown
- 1976-06-22 TR TR18814A patent/TR18814A/en unknown
- 1976-06-22 NO NO762164A patent/NO145577C/en unknown
- 1976-06-23 AT AT458276A patent/AT353005B/en not_active IP Right Cessation
- 1976-06-23 GB GB26003/76A patent/GB1517067A/en not_active Expired
- 1976-06-23 PT PT65260A patent/PT65260B/en unknown
- 1976-06-23 NL NL7606870A patent/NL7606870A/en not_active Application Discontinuation
- 1976-06-24 CH CH812276A patent/CH623834A5/en not_active IP Right Cessation
- 1976-06-24 IE IE1373/76A patent/IE43835B1/en unknown
- 1976-06-24 BE BE168261A patent/BE843350A/en not_active IP Right Cessation
- 1976-06-24 JP JP51073914A patent/JPS5952167B2/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108219043A (en) * | 2016-12-21 | 2018-06-29 | 中国石化集团四川维尼纶厂 | A kind of preparation method of polyvinyl acetate emulsion |
Also Published As
| Publication number | Publication date |
|---|---|
| SE7606890L (en) | 1976-12-25 |
| FR2315509A1 (en) | 1977-01-21 |
| JPS5952167B2 (en) | 1984-12-18 |
| NO145577C (en) | 1982-04-21 |
| NL7606870A (en) | 1976-12-28 |
| FI761789A7 (en) | 1976-12-25 |
| NO145577B (en) | 1982-01-11 |
| DK145894C (en) | 1983-09-19 |
| IE43835L (en) | 1976-12-24 |
| AT353005B (en) | 1979-10-25 |
| FI61501C (en) | 1982-08-10 |
| LU75201A1 (en) | 1977-02-17 |
| TR18814A (en) | 1977-11-01 |
| NO762164L (en) | 1976-12-28 |
| DE2625859A1 (en) | 1976-12-30 |
| IE43835B1 (en) | 1981-06-03 |
| PT65260A (en) | 1976-07-01 |
| DK145894B (en) | 1983-04-05 |
| ES449476A1 (en) | 1977-07-16 |
| BE843350A (en) | 1976-12-24 |
| FI61501B (en) | 1982-04-30 |
| SE422327B (en) | 1982-03-01 |
| DK269576A (en) | 1976-12-25 |
| CH623834A5 (en) | 1981-06-30 |
| EG12447A (en) | 1979-03-31 |
| FR2315509B1 (en) | 1979-08-31 |
| IT1039354B (en) | 1979-12-10 |
| PT65260B (en) | 1977-12-07 |
| ATA458276A (en) | 1979-03-15 |
| DE2625859B2 (en) | 1980-10-30 |
| JPS524585A (en) | 1977-01-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |