GB1568550A - Self-curing and water-soluble mould - Google Patents

Description

(54) SELF-CURING AND WATER-SOLUBLE MOLD (71) We, NATIONAL RESEARCH INSTITUTE FOR METALS, an Organisation of the Japanese Government of 3-I 2, 2-chome, Nakameguro, Meguro-ku, Tokyo, Japan, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:- This invention relates to a process for producing a water-soluble mold, suitable for use in casting aluminum alloys, copper alloys, cast irons and cast steels, and to a method of casting metals using a mold thus produced.

The term "water-soluble mold" denotes a mold which can easily disintegrate by being immersed in water after a molten metal has been cast in the mold, or a mold which can be disintegrated by slight impact.

Various kinds of molds are used in the casting industry. All of these molds are produced by mixing refactory particles with from 1.5 to 6% of an inorganic or organic binder, and shaping the mixture. The molds are then strengthened, and molten metals are poured thereinto to produce castings. Of these molds, green sand molds gain most widespread acceptance because of their low cost and superior moldability. The "green sand mold denotes a mold which is produced by adding a small amount of water to a mixture of an aggregate, such as silica sand, and a binder, such as bentonite, and shaping the mixture by a mechanical compressive force. The mold strength is obtained by the physical cohering force of bentonite.

Since the green sand mold cannot gain sufficient strength by merely being allowed to stand in the open atmosphere after shaping, it is necessary to strengthen it by applying a mechanical force. However, the use of such a technique still cannot increase the strength of the green sand mold beyond as low as about 0.3 to 1.5 kg/cm2 in terms of compressive strength, and therefore, the green sand molds are extremely unsatisfactory for production of large castings. Moreover, they have another defect.When, for example, molten cast iron is poured into a green sand mold, that part of the mold which has contacted or is in the vicinity of the high temperature molten cast iron is heated to a temperature of as high as 800 to 1100 C. As a result, the silica sand and bentonite are sintered at the heated part - and become vitreous, and the vitrified material coalesces firmly to the resulting casting. It is essential therefore to finish the casting by, for example, shot blasting so as to remove the vitreous substance from it. In this finishing operation, heavy vibration, noises, and dust occur to worsen the working environment.

Accordingly, high-strength molds have been desired in order to eliminate the defect that large castings are difficult to produce by green sand and molds. Recent investigations in an effort to eliminate this defect have resulted in the rapid development of self-cured molds, and various other methods have also been under investigation.

Generally, a "self-cured mold" is a mold which is produced by adding a binder and a small amount of a curing agent to refractory particles as aggregate and shaping the mixture, and which cures by being allowed to stand after shaping.

Inorganic binders used for producing self-curing molds are roughly divided into the following types: (1) a mixture of sodium silicate as a main binder and a small amount of Fe-Si, Al, Zr, Al4C,, CaO, SiO2, 2CaO, SiO2, slag, or a phosphoric acid salt as a curing agent; (2) a mixture of acid aluminum phosphate as a main binder with a small amount of an Al powder as a curing agent, and (3) a mixture of a blast furnace slag as a main binder with a small amount of NaOH, KOH or Ca(OH)2 as a curing agent. Self-curing molds containing the sodium silicate-type binder shown in classification (I) above are now most widely used.

These self-curing molds generally have a compressive strength of 1 to 10 kg/cm2 after a period of 1 hour and 10 to 30 kg/cm2 after a period of 24 hours, and cure to a considerably rigid structure. Since compressive strengths of at least about 20 kg/cm2 are usually considered to be sufficient for molds used to produce large castings, these self-curing molds can be used to produce large casting. However, almost all the conventional self-cured molds are water-insoluble, and therefore mold releasing, known as "knock-out", after casting must be performed by a mechanical method of applying a heavy impact. This involves heavy vibration, noises and dust which will worsen the working environment and also increase the cost of production. The same problem would occur also if a mold were to be produced using silica and an alkali metal phosphate.

According to the present invention there is provided a process for producing a water-soluble mold (as hereinbefore defined), which process comprises shaping a mixture of (A) 100 parts by weight of alumina refractory particles, (B) 1 to 5 parts by weight of potassium phosphate and/or sodium phosphate, (C) 0.2 to 3 parts by weight of an aluminium powder, and a suitable amount of water into a mold of the desired form; and allowing the mold to self-cure. The shaped mixture of components (A), (B), and (C) and water can self-cure merely by being allowed to stand in an open atmosphere, the curing proceeding by a chemical reaction which takes place during standing. The self-cure may be promoted by heating. The mixture of components (A), (B), (C) and water may be formed by adding water to a mixture of components (A), (B) and (C).

The present invention also provides a method of casting metals which comprises pouring a molten metal into a water-soluble mold prepared in accordance with the present invention, allowing the metal to cool and solidify and then immersing the mold in water or subjecting the mold to a mechanical impact in order to cause the mold to disintegrate and the metal casting to be freed.

The term "mold", as used in the present specification, is meant to include both a mold for producing cavity-free castings and a core for producing cavitycontaining castings.

The important requirement of the process of this invention is to use alumina refractory particles as an aggregate (component A), potassium phosphate and/or sodium phosphate as a binder (component B), and an aluminum powder as a curing agent (component C). It is believed that in the process of this invention, an exothermic reaction between the aluminum powder and the phosphate gives aluminum phosphate, and as a result, a curing reaction proceeds.

The use of alumina as an aggregate is of utmost importance in the process of this invention so that the resulting mold can disintegrate easily simply by immersing the mold in water after a molten metal has been poured therein and a casting produced. Use of silica now in common acceptance, instead of the alumina, would lead to the loss of the water-solubility of the mold after molten metal has been poured therein because of its contact with molten metal at high temperatures (for example, a copper alloy will be heated to about 950"C, and a cast iron, to about I 100"C) although before pouring such a mould derived from silica is water-soluble.

In contrast, the mold containing alumina as an aggregate in accordance with this invention retains its water-solubility even after it has been subjected to heat by pouring a molten metal therein. Thus, using molds prepared in accordance with the present invention it is possible to release the mold from castings by merely immersing it in water without requiring such a mechanical method which will generate vibration, noises and dust. Preferably, the operation of immersing the mold in water for knock-out is carried out after the casting has been allowed to cool to a certain temperature, because the quality of the casting would be debased if the mold is immersed in water while the casting is still at too high temperatures. It is not necessary however to cool the casting to room temperature, but cooling of it to a temperature which does not deteriorate the quality of the casting during water immersion suffices. For example, in the case of cast iron, it is sufficient to cool the mold to about 700"C.

The particle size of the alumina particles used as component (A) is not critical.

Alumina particles having sizes usually used in the casting industry, for example from 75 to 150 mesh, can be conveniently used. Mesh sizes throughout the Specification are based on the Japanese Industrial Standard. Aluminum used as component (C) must be powdery in order to ensure good reactivity, and its suitable particle size is smaller than 200 mesh. The amount of water to be added to the mixture of components (A), (B) and (C) is not critical, and a suitable amount is usually 1 to 10 parts by weight per 100 parts by weight of component (A). The mixture obtained by mixing water is shaped into a mold by any known method, and then cured by being allowed to stand in the open atmosphere.

The strength of the mold obtained by the process described above generally depends upon the amounts of components (B) and (C), and tends to be higher the larger the amounts of components (B) and (C). It is possible therefore to produce castings having a compressive strength of more than 20 kg/cm2 if the amounts of components (B) and (C) are large. When the amounts of components (B) and (C) are small, the resulting mold may not have sufficient strength for production of large castings, but can be satisfactorily used if so much strength is not required.

According to a preferred embodiment of the present invention, the following components (D) and/or (E) may be present in the mixture admixed with water: Component (D).

1 to 5 parts by weight of at least one alkali metal aluminate selected from potassium aluminate and sodium aluminate Component (E).

1 to 5 parts by weight of at least one alkali metal carbonate selected from potassium carbonate and sodium carbonate.

The aluminate as an optional component (D) is considered to induce an exothermic reaction with the aluminium powder thus giving alumina gel which will promote the curing reaction. Generally, the use of aluminate salts tends to increase the strength of the resulting mold considerably.

The carbonate as an optional component (E) also tends to contribute to an increase in the strength of molds although not to such a degree as is achieved by the aluminates. The most important effect obtained by the addition of component (E) is to reduce the humidification of the mold. Molds obtained by those embodiments of the invention which do not use component (E), i.e. the method using components (A), (B) and (C) and the method using components (A), (B), (C) and (D), have some hygroscopicity, and upon standing in the open atmosphere for a long time of, say, several days, may soften at their surfaces and decrease in mold strength.

This sometimes becomes a trouble when pouring of a metal into the mold is not done immediately after shaping but after several days from the shaping of the mold. The use of component (E) is beneficial for avoiding this trouble.

While the present invention primarily contemplates the spontaneous curing of molds after shaping, it is possible to heat the surface of the molds locally in order to promote the curing reaction. Particularly, when the mold is of small size, the heat dissipating area of the mold per unit volume increases, and the exothermic reaction mentioned hereinabove tends to fail. This retards the rate of curing reaction. In such a case, it is advantageous to employ the above-mentioned method of local heating.

The water-soluble self-cured molds in accordance with this invention is especially suitable for production of castings of aluminum alloys, copper alloys, cast irons and cast steels. In spite of the fact that the molds of the invention are selfcuring, they are water-solubeand easily disintegrable in water both after curing and after pouring of molten metals. Knock-out of the molds in the production of castings, therefore, becomes easy, and a technical advantage can be obtained in the casting process. Moreover, since a knock-out operation becomes easy, a reduction in the cost of production can be expected, and the working environment can be markedly improved.

Runs 1(A) to 10(A) of Example 1 below, Runs 1(A) to 6(A) of Example 2 below and Example 3 below illustrate the present invention.

Example 1.

100 Parts by weight of alumina particles having a particle diameter of 75 to 150 mesh as refractory particles (component A) was mixed with the components shown in Table 1 in the amounts indicated. Runs in which these alumina particles are employed as the Aggregate are hereinafter designated "(A)" Runs. For Comparative purposes, a corresponding weight of silica particles were employed in Runs hereinafter designated "(S)" Runs. Three parts by weight of water was mixed with each of the resulting mixtures, and from each of the resulting mixtures, cylindrical test samples having a diameter of 50 cm and a height of 50 cm were prepared.In order to promote curing, one end surface of each of the cylindrical test samples was placed for 5 minutes on an iron plate heated at 130"C. Then, the samples were each turned upside down, and the other end surface was placed on the iron plate for 5 minutes. The test samples were then removed from the iron plate, and allowed to stand in the open atmosphere. The curing reaction continued during this time, but ended within one hour after standing. The test samples which had been allowed to stand for one hour were tested for compressive strength and water solubility.

Furthermore, in order to simulate heating of molds by the pouring of molten metals, the test samples which had been left to stand for 1 hour were placed in ovens held at a temperature of 950"C and 1100"C respectively. After the central portion of each sample reached the heating temperature, the samples were placed therein for an additional 10 hours. Then, the samples were withdrawn from the ovens, cooled to room temperature, and tested for water-solubility.

The results of experiments are shown in Table 1.

The results shown in Table 1 show that when alumina was used as the aggregate, both the unheated cured samples and the heated cured samples showed good water solubility, but that when silica was used as the aggregate, the heated cured samples had markedly reduced water solubility although the unheated cured samples showed good water solubility.

Runs Nos. 11 and 12 in Table 1 were comparative experiments in which the aluminum powder as component (C) was not used. It can be seen that in this case, the strengths of the molds were too low to be feasible.

Table 1

c -(I I-T .s, in parts O X O X Q)C'r( solubilit Run No. we t Co onens 4reate ressive 1 hour ~ heated 3 C i) > < &commat; > e &commat; x i) X Gi) powder 00\ i- -- ~ ~ ~ ~ K3PO4 -------------- Al mesh A 0 1 1 0.2 - S 2 Oo )( Za rl < U 6 r aC ab U K;V H 5 at 2 ~ ,- ~ + cbv 6 1 0.2 - A 0 o x at &verbar; n M l l l H sU P C ~ h fc ~ ~ ~ &verbar; O e a l o N uo u ue f N m t < N o , N , S ~N ~ 4 ~&commat; Table 1 (Cont'd)

ç m 4 ~ O X > XX X O ~ Id U a, o C 0 3 x x x x O Run No. wei ~ ~ ~ ~ &commat; Q .

-lmo PRd N X X N < q p^ ~ ~ ~ ~ ~ ~ ~ ~ ~ 03U mEl 6 Q) oh0u 12 3 P N AJ A 0.8 Co Fh C F i > ffi ~~ gc~ 4 O , N > ~ ~ Ps H ~t e o n b tO C. > O r1 N * A refers to the case of using alumina, and S refers to the case of using silica (for comparative purposes) Example 2.

In Example 1, potassium salts were used as the phosphate (Component B), aluminate (component D) and carbonate (component E). In example 2, sodium salts, and a mixture of sodium and potassium salts were used as these components as shown in Table 2, and otherwise, the conditions employed were the same as set forth in Example 1.

The results of experiments are shown in Table 2. It can be seen that in Example 2, substantially the same results as in Example 1 were obtained.

Table 2

p O ~ O x O ~ a x 3 ~ &commat; x Wat ubi it Thn No. wei t of Co on nt O {i) ~ (d) O a cd O g 0a9a5t0o1s1t00o0 a: k k P 9 h i 1 re - 1 A N N Co ut N S 2. )( 4 - 4 2 3 A 26 S el CQ < razzzitc 20 0 X a, S 1 6 - 4 2 4 A 2 Co X N ~ Q ~ ~ Q Q aN ~ N ~~ N ~ 0m o C) N - o N > X ~ Q C O O O N ~ N 4 3 m A ~ N H Q 4 4 Example 3.

In accordance with the recipe shown in Run No. 5 in Example 1 in Table 1, a mold for a differential gear case of an automobile having a weight of about 2 kg was produced, and cured by allowing it to stand in the open atmosphere. The curing was completed in about one hour. After pouring a molten cast iron into this mold, it was allowed to stand in the open atmosphere for 1 hour to cool it to a temperature of about 700 C. When it was gradually immersed in water, the mold disintegrated easily, and a complete casting free from any mold adhering thereto was obtained.

Claims (11)

WHAT WE CLAIM IS:

1. A process for producing a water-soluble mold (as hereinbefore defined), which process comprises shaping a mixture of (A) 100 parts by weight of alumina refractory particles, (B) 1 to 5 parts by weight of potassium phosphate and/or sodium phosphate, (C) 0.2 to 3 parts by weight of an aluminum powder, and a suitable amount of water into a mold of the desired form: and allowing the mold to self-cure.

2. A process according to claim 1 wherein said mixture is formed by adding water to a mixture of components (A), (B) and (C).

3. A process according to any one of the preceding claims wherein said mixture further contains (D) 1 to 5 parts by weight of potassium aluminate and/or sodium aluminate.

4. A process according to any one of the preceding claims wherein said mixture further contains (E) 1 to 5 parts by weight of potassium carbonate and/or sodium carbonate.

5. A process according to claim 1 substantially as hereinbefore described with reference to any one of Runs 6(A) to 9(A) of Example 1 and Runs 3 (A) to 6 (A) of Example 2.

6. A process according to claim 1 substantially as hereinbefore described with reference to any one of Runs 1(A) to 5(A) and 10(A) of Example 1 and Runs 1(A) and 2(A) of Example 2.

7. A water-soluble mold which has been prepared by a process as claimed in any one of the preceding claims.

8. A method of casting metals which comprises pouring a molten metal into a mold as claimed in claim 7, allowing the molten metal to cool and solidify, and then immersing the mold in water or subjecting the mold to a mechanical impact in order to cause the mold to disintegrate and the metal casting to be freed.

9. A method according to claim 8 wherein said metal is an aluminium alloy, a copper alloy, iron or steel.

10. A method according to claim 8 substantially as hereinbefore described with reference to Example 3.

11. A metal casting which has been prepared by a method as claimed in any one of claims 8 to 10.