GB1414174A - Process for preparing block copolymers containing a-methyl styrene - Google Patents
Process for preparing block copolymers containing a-methyl styreneInfo
- Publication number
- GB1414174A GB1414174A GB5722572A GB5722572A GB1414174A GB 1414174 A GB1414174 A GB 1414174A GB 5722572 A GB5722572 A GB 5722572A GB 5722572 A GB5722572 A GB 5722572A GB 1414174 A GB1414174 A GB 1414174A
- Authority
- GB
- United Kingdom
- Prior art keywords
- block
- styrene
- forming
- elastomeric block
- number average
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 title abstract 3
- 229920001400 block copolymer Polymers 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 239000003999 initiator Substances 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 abstract 1
- 229940072049 amyl acetate Drugs 0.000 abstract 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 abstract 1
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- ZAKVZVDDGSFVRG-UHFFFAOYSA-N prop-1-en-2-ylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 ZAKVZVDDGSFVRG-UHFFFAOYSA-N 0.000 abstract 1
- 229920006132 styrene block copolymer Polymers 0.000 abstract 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
- C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
1414174 Block copolymers STAMICARBON BV 12 Dec 1972 [15 Dec 1971] 57225/72 Heading C3P Elastomeric block copolymers of the general formula A-B-C, at least blocks A and B being linked by styrene units in which A is a non- elastomeric block derived from α-methylstyrene units and having a number average M.Wt. of 2000 to 100,000, B is an elastomeric block with a number average M.Wt. of 15,000 to 250,000, and C is a non-elastomeric block with a number average M.Wt. of 2000 to 100,000, and wherein A and C are identical if a linkage agent is used, are prepared by forming a polymer block from α-methyl-styrene at below 0‹ C. with the aid of a monofunctional anionic initiator, reacting the block so formed at below 0‹ C. with 1-100 molar proportion of styrene based on the initiator, forming an elastomeric block at above 0‹ C. and then forming the A-B-C copolymers by adding a linkage agent or by forming a further non-elastomeric block. In examples sec.-butyl lithium is used an initiator and 1,3-butadiene used to form the elastomer block. Amyl acetate, divinyl benzene and methylenediphenylene diisocyanate are used as linkage agents to give as product an α - methyl styrene - styrene - butadienestyrene-α-methyl styrene block copolymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7117171A NL7117171A (en) | 1971-12-15 | 1971-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1414174A true GB1414174A (en) | 1975-11-19 |
Family
ID=19814698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5722572A Expired GB1414174A (en) | 1971-12-15 | 1972-12-12 | Process for preparing block copolymers containing a-methyl styrene |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5037079B2 (en) |
| BE (1) | BE792795A (en) |
| CA (1) | CA1010184A (en) |
| DE (1) | DE2261214A1 (en) |
| FR (1) | FR2165530A5 (en) |
| GB (1) | GB1414174A (en) |
| IT (1) | IT974500B (en) |
| NL (1) | NL7117171A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2169905A (en) * | 1984-12-13 | 1986-07-23 | Japan Synthetic Rubber Co Ltd | Conjugated diene based rubber composition |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4260694A (en) * | 1979-11-29 | 1981-04-07 | Mobil Oil Corporation | p-Methylstyrene diene block copolymers |
| FR2514011A1 (en) * | 1981-10-02 | 1983-04-08 | Philippe Teyssie | CIPO-Patent |
| JP5168460B2 (en) * | 2007-09-28 | 2013-03-21 | 株式会社クラレ | Block copolymer and method for producing the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1189767A (en) * | 1967-04-01 | 1970-04-29 | Polymer Corp | Block Copolymers and their preparation |
-
0
- BE BE792795D patent/BE792795A/en unknown
-
1971
- 1971-12-15 NL NL7117171A patent/NL7117171A/xx unknown
-
1972
- 1972-12-12 GB GB5722572A patent/GB1414174A/en not_active Expired
- 1972-12-13 CA CA158,774A patent/CA1010184A/en not_active Expired
- 1972-12-14 DE DE19722261214 patent/DE2261214A1/en active Pending
- 1972-12-14 FR FR7244485A patent/FR2165530A5/fr not_active Expired
- 1972-12-14 IT IT5473272A patent/IT974500B/en active
- 1972-12-15 JP JP47126044A patent/JPS5037079B2/ja not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2169905A (en) * | 1984-12-13 | 1986-07-23 | Japan Synthetic Rubber Co Ltd | Conjugated diene based rubber composition |
| US4742117A (en) * | 1984-12-13 | 1988-05-03 | Japan Synthetic Rubber Co., Ltd. | Conjugated diene based rubber composition |
| GB2169905B (en) * | 1984-12-13 | 1989-10-18 | Japan Synthetic Rubber Co Ltd |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7117171A (en) | 1973-06-19 |
| FR2165530A5 (en) | 1973-08-03 |
| CA1010184A (en) | 1977-05-10 |
| DE2261214A1 (en) | 1973-06-20 |
| BE792795A (en) | 1973-06-15 |
| IT974500B (en) | 1974-06-20 |
| JPS5037079B2 (en) | 1975-11-29 |
| JPS4867381A (en) | 1973-09-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |