GB1406395A - Bipolar electrode assemblies for electrolytic cells - Google Patents
Bipolar electrode assemblies for electrolytic cellsInfo
- Publication number
- GB1406395A GB1406395A GB5191273A GB5191273A GB1406395A GB 1406395 A GB1406395 A GB 1406395A GB 5191273 A GB5191273 A GB 5191273A GB 5191273 A GB5191273 A GB 5191273A GB 1406395 A GB1406395 A GB 1406395A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fluoride
- electrode
- solid
- cathode
- cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000000712 assembly Effects 0.000 title 1
- 238000000429 assembly Methods 0.000 title 1
- 229910052719 titanium Inorganic materials 0.000 abstract 7
- 239000010936 titanium Substances 0.000 abstract 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 4
- 210000004027 cell Anatomy 0.000 abstract 4
- 239000004020 conductor Substances 0.000 abstract 3
- 238000005192 partition Methods 0.000 abstract 3
- 239000007787 solid Substances 0.000 abstract 3
- 229910000831 Steel Inorganic materials 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- -1 polyethylene Polymers 0.000 abstract 2
- 239000010959 steel Substances 0.000 abstract 2
- 229910052715 tantalum Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- 229910001369 Brass Inorganic materials 0.000 abstract 1
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 abstract 1
- 241000627951 Osteobrama cotio Species 0.000 abstract 1
- 235000008098 Oxalis acetosella Nutrition 0.000 abstract 1
- 240000007930 Oxalis acetosella Species 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 229910006404 SnO 2 Inorganic materials 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000010951 brass Substances 0.000 abstract 1
- 239000012267 brine Substances 0.000 abstract 1
- 210000005056 cell body Anatomy 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910003460 diamond Inorganic materials 0.000 abstract 1
- 239000010432 diamond Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- 239000006104 solid solution Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 125000006850 spacer group Chemical group 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
1406395 Bipolar electrode for electrolytic cell DIAMOND SHAMROCK CORP 8 Nov 1973 [9 Nov 1972] 51912/73 Heading C7B A bipolar electrode for an electrolytic cell comprises at least one rigid conductor 12 extending on both sides of a non-conducting partition 11 which divides the cell in use, and an anode 13 and cathode 14 connected to opposite extremities of the conductor in opposed spaced parallel relation to the partition, at least one electrode being so connected via conductive movable means 15 which are arranged for adjustable movement of the electrode towards an opposed electrode of opposite charge in use in the cell. The means 15 may be resilient, as shown, with insulating spacers 18 eg, of an inert halocarbon polymer, to prevent short circuiting. The partition may be PVC, PVdC or polyethylene. The conductors 12 may be Ti, Ti on Cu, or Ta. Members 15 may be Ti, Ti on brass, steel or Ni. The anode may be solid or foraminous and may be segmented. The substrate thereof may be Ti, Ta, Nb or Zr coated with Pt or an alloy thereof or a solid solution of an oxide of Pt, Ru, Pd, Ir, Rh and/or Os and an oxide of Ti, Ta, Zr and/or Nb, to which may optionally be added SnO 2 , CoTiO 3 , PV fluoride orPVd fluoride. The cathode may also be solid or foraminous, optionally segmented and may be of (stainless) steel, Ni, Ti, Pb or Pt with or without a solid oxide solution coating as above. A diaphragm or membrane may cover the cathode. The cell body may be PV fluoride or PVd fluoride for brine electrolysis or the manufacture of alkali and alkaline earth metal hypochlorites, chlorates and perchlorates.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US305063A US3873437A (en) | 1972-11-09 | 1972-11-09 | Electrode assembly for multipolar electrolytic cells |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1406395A true GB1406395A (en) | 1975-09-17 |
Family
ID=23179163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5191273A Expired GB1406395A (en) | 1972-11-09 | 1973-11-08 | Bipolar electrode assemblies for electrolytic cells |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3873437A (en) |
| JP (1) | JPS5713636B2 (en) |
| AR (1) | AR200745A1 (en) |
| AU (1) | AU475206B2 (en) |
| BE (1) | BE807053A (en) |
| CA (1) | CA1027517A (en) |
| DE (1) | DE2355876C2 (en) |
| ES (1) | ES420298A1 (en) |
| FR (1) | FR2206131B1 (en) |
| GB (1) | GB1406395A (en) |
| IT (1) | IT996412B (en) |
| NL (1) | NL7315338A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2001102A (en) * | 1977-07-01 | 1979-01-24 | Oronzio De Nora Impianti | Monopolar electrolytic diaphragm cells and anodes for such cells and to a method of inserting and removing the anodes into and out of the cells |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4013525A (en) * | 1973-09-24 | 1977-03-22 | Imperial Chemical Industries Limited | Electrolytic cells |
| FR2280432A1 (en) * | 1974-07-29 | 1976-02-27 | Rhone Poulenc Ind | ELECTROLYSIS CELL WITH BIPOLAR ELEMENTS FOR ELECTROLYSIS IN PARTICULAR ALKALINE SALT SOLUTIONS |
| FR2297672A1 (en) * | 1975-01-14 | 1976-08-13 | Rech Tech Et Indles | ELECTROLYZER |
| US4069130A (en) * | 1975-01-29 | 1978-01-17 | Kerr-Mcgee Chemical Corporation | Bipolar electrode and method for constructing same |
| US4085027A (en) * | 1975-01-29 | 1978-04-18 | Kerr-Mcgee Chemical Corporation | Hybrid bipolar electrode |
| US4040935A (en) * | 1975-04-11 | 1977-08-09 | Basf Wyandotte Corporation | Protective covering for electrolytic filter press cell frames |
| US4033849A (en) * | 1975-05-09 | 1977-07-05 | Diamond Shamrock Corporation | Electrode and apparatus for forming the same |
| US4053385A (en) * | 1975-10-30 | 1977-10-11 | Basf Wyandotte Corporation | Bonding stable materials to resinous cell frames |
| US4026785A (en) * | 1975-12-22 | 1977-05-31 | Olin Corporation | Adjustable electrode |
| US4028213A (en) * | 1976-02-09 | 1977-06-07 | Olin Corporation | Variable gap anode assembly for electrolytic cells |
| GB1581348A (en) * | 1976-08-04 | 1980-12-10 | Ici Ltd | Bipolar unit for electrolytic cell |
| US4101395A (en) * | 1976-08-30 | 1978-07-18 | Tokuyama Soda Kabushiki Kaisha | Cathode-structure for electrolysis |
| US4080279A (en) * | 1976-09-13 | 1978-03-21 | The Dow Chemical Company | Expandable anode for electrolytic chlorine production cell |
| GB1533904A (en) * | 1976-11-12 | 1978-11-29 | Ici Ltd | Diaphragm cells |
| US4136235A (en) * | 1977-01-21 | 1979-01-23 | Diamond Shamrock Technologies S.A. | Secondary batteries |
| US4119519A (en) * | 1977-04-04 | 1978-10-10 | Kerr-Mcgee Corporation | Bipolar electrode for use in an electrolytic cell |
| US4098671A (en) * | 1977-04-18 | 1978-07-04 | Gow Enterprises Limited | Cathode for electrolytic process involving hydrogen generation |
| US4096054A (en) * | 1977-10-26 | 1978-06-20 | Olin Corporation | Riserless flexible electrode assembly |
| IT1118243B (en) * | 1978-07-27 | 1986-02-24 | Elche Ltd | MONOPOLAR ELECTROLYSIS CELL |
| US4247376A (en) * | 1979-01-02 | 1981-01-27 | General Electric Company | Current collecting/flow distributing, separator plate for chloride electrolysis cells utilizing ion transporting barrier membranes |
| IT1140510B (en) * | 1980-01-16 | 1986-10-01 | Oronzio De Nora Impianti | BIPOLAR ELECTROLIZER AND ELECTROLYSIS PROCEDURE OF ELECTROLYSIS OF HALIDE |
| JPS5770144A (en) * | 1980-10-17 | 1982-04-30 | Asahi Glass Co Ltd | Organic solution of fluorinated copolymer containing carboxyl group |
| FI72150C (en) * | 1980-11-15 | 1987-04-13 | Asahi Glass Co Ltd | Alkalimetallkloridelektrolyscell. |
| US4469580A (en) * | 1981-03-30 | 1984-09-04 | The Dow Chemical Company | Method of making an improved internally supported electrode |
| US4561959A (en) * | 1983-12-09 | 1985-12-31 | The Dow Chemical Company | Flat-plate electrolytic cell |
| EP0185269A1 (en) * | 1984-12-17 | 1986-06-25 | The Dow Chemical Company | A wholly fabricated electrochemical cell |
| GB8530893D0 (en) * | 1985-12-16 | 1986-01-29 | Ici Plc | Electrode |
| US4668372A (en) * | 1985-12-16 | 1987-05-26 | The Dow Chemical Company | Method for making an electrolytic unit from a plastic material |
| US4670123A (en) * | 1985-12-16 | 1987-06-02 | The Dow Chemical Company | Structural frame for an electrochemical cell |
| ES2028946T3 (en) * | 1987-07-01 | 1992-07-16 | Messerschmitt-Bolkow-Blohm Gesellschaft Mit Beschrankter Haftung | ARRANGEMENT FOR THE ELECTRICAL FEEDING OF THE POROUS ANODE OF THE BIPOLAR PLATES OF CELL BATTERIES IN A FILTER-PRESS GROUP. |
| US5013414A (en) * | 1989-04-19 | 1991-05-07 | The Dow Chemical Company | Electrode structure for an electrolytic cell and electrolytic process used therein |
| US5306410A (en) * | 1992-12-04 | 1994-04-26 | Farmer Thomas E | Method and device for electrically coupling a conductor to the metal surface of an electrolytic cell wall |
| BR9302093A (en) * | 1993-05-28 | 1994-11-29 | Nora Pemelec Do Brasil S A De | Chlor-alkali electrolysis process |
| DE19650228C2 (en) * | 1996-12-04 | 1999-09-02 | Metallgesellschaft Ag | Electrolytic cell with bipolar electrodes |
| JP2000192276A (en) * | 1998-12-25 | 2000-07-11 | Asahi Glass Co Ltd | Bipolar ion exchange membrane electrolytic cell |
| GB2483627A (en) * | 2010-04-06 | 2012-03-21 | Metalysis Ltd | A bipolar electrolysis cell and method of operation |
| ES2676493T3 (en) * | 2014-07-17 | 2018-07-20 | Industrie De Nora S.P.A. | Electrocatalytic generation of chlorine dioxide |
| EP3668966B1 (en) | 2017-08-16 | 2022-09-28 | Amgen Inc. | Adaptive electrode arrangement for implementation in a cell incubator system and applications thereof |
| DE102018209520A1 (en) | 2018-06-14 | 2019-12-19 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | electrolysis cell |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE637692A (en) * | 1962-09-20 | |||
| GB1045816A (en) * | 1964-11-05 | 1966-10-19 | David J Evans Res Ltd | Improvements in or relating to electrodes for electrolytic cells |
| US3441495A (en) * | 1966-05-20 | 1969-04-29 | Electric Reduction Co | Bipolar electrolytic cell |
| US3616445A (en) * | 1967-12-14 | 1971-10-26 | Electronor Corp | Titanium or tantalum base electrodes with applied titanium or tantalum oxide face activated with noble metals or noble metal oxides |
| US3562008A (en) * | 1968-10-14 | 1971-02-09 | Ppg Industries Inc | Method for producing a ruthenium coated titanium electrode |
| US3770611A (en) * | 1971-11-24 | 1973-11-06 | Olin Corp | Multiple tier horizontal diaphragm cells |
| US3752757A (en) * | 1972-06-07 | 1973-08-14 | Basf Wyandotte Corp | Bipolar electrode seal at barrier sheet |
-
1972
- 1972-11-09 US US305063A patent/US3873437A/en not_active Expired - Lifetime
-
1973
- 1973-11-06 ES ES420298A patent/ES420298A1/en not_active Expired
- 1973-11-08 AU AU62277/73A patent/AU475206B2/en not_active Expired
- 1973-11-08 IT IT53575/73A patent/IT996412B/en active
- 1973-11-08 BE BE137519A patent/BE807053A/en unknown
- 1973-11-08 DE DE2355876A patent/DE2355876C2/en not_active Expired
- 1973-11-08 NL NL7315338A patent/NL7315338A/xx not_active Application Discontinuation
- 1973-11-08 AR AR250904A patent/AR200745A1/en active
- 1973-11-08 GB GB5191273A patent/GB1406395A/en not_active Expired
- 1973-11-08 CA CA185,370A patent/CA1027517A/en not_active Expired
- 1973-11-08 FR FR7339691A patent/FR2206131B1/fr not_active Expired
- 1973-11-09 JP JP12556773A patent/JPS5713636B2/ja not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2001102A (en) * | 1977-07-01 | 1979-01-24 | Oronzio De Nora Impianti | Monopolar electrolytic diaphragm cells and anodes for such cells and to a method of inserting and removing the anodes into and out of the cells |
| GB2001102B (en) * | 1977-07-01 | 1982-01-20 | Oronzio De Nora Impianti | Improvements relating to monopolar electrolytic diaphragm cells and anodes for such cells and to a method of inserting and removing the anodes into and out of the cells |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7315338A (en) | 1974-05-13 |
| ES420298A1 (en) | 1977-01-01 |
| JPS5713636B2 (en) | 1982-03-18 |
| BE807053A (en) | 1974-05-08 |
| DE2355876A1 (en) | 1974-05-16 |
| AR200745A1 (en) | 1974-12-13 |
| IT996412B (en) | 1975-12-10 |
| US3873437A (en) | 1975-03-25 |
| FR2206131A1 (en) | 1974-06-07 |
| AU475206B2 (en) | 1976-08-12 |
| JPS49134573A (en) | 1974-12-25 |
| AU6227773A (en) | 1975-05-08 |
| FR2206131B1 (en) | 1977-06-03 |
| CA1027517A (en) | 1978-03-07 |
| DE2355876C2 (en) | 1982-12-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |