GB1403774A - Method of bonding a thread - Google Patents
Method of bonding a threadInfo
- Publication number
- GB1403774A GB1403774A GB3700372A GB3700372A GB1403774A GB 1403774 A GB1403774 A GB 1403774A GB 3700372 A GB3700372 A GB 3700372A GB 3700372 A GB3700372 A GB 3700372A GB 1403774 A GB1403774 A GB 1403774A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diol
- molecular weight
- glycol
- carbon atoms
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 8
- 150000002009 diols Chemical class 0.000 abstract 7
- -1 aliphatic diols Chemical class 0.000 abstract 6
- 150000002148 esters Chemical group 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 150000002334 glycols Chemical class 0.000 abstract 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 3
- 229920000728 polyester Polymers 0.000 abstract 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
- YXVYDRRQLYLXJF-UHFFFAOYSA-N 3,3-dimethyl-1,5-dioxacycloundecane-6,11-dione Chemical compound CC1(C)COC(=O)CCCCC(=O)OC1 YXVYDRRQLYLXJF-UHFFFAOYSA-N 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 241001082241 Lythrum hyssopifolia Species 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 159000000032 aromatic acids Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920001748 polybutylene Polymers 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 229920001195 polyisoprene Polymers 0.000 abstract 1
- 229920006295 polythiol Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 229920006344 thermoplastic copolyester Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C09J167/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
1403774 Bonded yarns and ropes E I DU PONT DE NEMOURS & CO 8 Aug 1972 [9 Aug 1971] 37003/72 Headings D1T and D1W The filaments of a thread, yarn, string cord or rope are bonded together by a thermoplastic copolyester elastomer derived from a dicarboxylic acid having a molecular weight of less than 350, a diol having a molecular weight of less than 250 and a diol (glycol) or polyglycol of molecular weight 350 to 6000, the short chain ester units comprising 15 to 65% by weight of the copolymer and the long chain ester units 35 to 85%. The copolymer having a melt index of less than 150 and a melting point of at least 125C. The filaments may be polyester, nylon or cotton. The dicarboxylic acid may be used as its ester, anhydride or acid chloride. Many aromatic, aliphatic and cycloaliphatic dicarboxylic acids are specified. Aromatic acids of 8 to 16 carbon atoms, particularly phthalic, terephthalic and isophthalic acid and mixtures thereof are preferred. Some p(#-hydroxyethoxy) benzoic acid may also be copolymerised. Specified low molecular weight diols include those with 2 to 15 carbon atoms and especially the aliphatic diols with 2 to 8 carbon atoms. Diol diesters, ethylene oxide and ethylene carbonate are also suitable. The higher (350-6000) molecular weight diol is preferably a poly (alkylene ether) glycol in which the alkylene group is of 2 to 9 carbon atoms. The diol may itself contain ester linkages. Thus a dicarboxymethyl acid of polybutylene glycol may be added to the polymerisation mixture where it is esterified with the low molecular weight diol. Polyester glycols, especially of sterically hindered polyesters, e.g. poly (2, 2-dimethyl-1, 3-propylene adipate) may also be used. Polyformals from pentamethylene glycol and formaldehyde, polythioether glycols, polybutadiene and polyisoprene glycols, their hydrogenation products and glycol esters of dicarboxylic acids formed by oxidation of polyisobutylene-diene copolymers may also be used. Preparation is by ester interchange e.g. dimethylterephalate is heated with a long chain glycol and an excess of short chain diol in at 150 to 260 and the methanol distilled. Organic and inorganic titanate catalysts are listed, as are phenol stabilisers, phthalate ester plasticisers and pigments, dyes, optical brighteners and flame retardants. The binder is applied to the thread &c in an organic solvent or an aqueous dispersion. Pick-up is 1 to 10% by weight.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00170287A US3823031A (en) | 1971-08-09 | 1971-08-09 | Thread bonded with segmented copolyester elastomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1403774A true GB1403774A (en) | 1975-08-20 |
Family
ID=22619294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3700372A Expired GB1403774A (en) | 1971-08-09 | 1972-08-08 | Method of bonding a thread |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3823031A (en) |
| JP (1) | JPS5647307B1 (en) |
| BE (1) | BE787375A (en) |
| CA (1) | CA976435A (en) |
| DE (1) | DE2239271C2 (en) |
| FR (1) | FR2148537B1 (en) |
| GB (1) | GB1403774A (en) |
| IT (1) | IT963827B (en) |
| NL (1) | NL169763C (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1035092A (en) * | 1973-02-20 | 1978-07-18 | E.I. Du Pont De Nemours And Company | Soft thermoplastic segmented copolyesters as pressure sensitive adhesives |
| GB1601372A (en) * | 1978-03-28 | 1981-10-28 | Bostik Ltd | Lasting shoes with hot melt adhesives |
| DE2818386C2 (en) * | 1978-04-27 | 1982-03-11 | Fröhlich & Wolff GmbH, 3436 Hessisch-Lichtenau | Yarn made from a multifilament, synthetic, polymeric material and process for refining such a yarn |
| DE3132059C1 (en) * | 1981-08-13 | 1983-01-13 | Dynamit Nobel Ag, 5210 Troisdorf | Polyether esters for gluing textiles |
| US4992515A (en) * | 1990-01-09 | 1991-02-12 | Shakespeare Company | Nylon terpolymer crosslinked with melamine formaldehyde for coating sewing threads |
| DE19632473C2 (en) * | 1996-08-12 | 2000-06-29 | Inventa Ag | Copolyetherester hot melt adhesives |
| DE19632474C2 (en) * | 1996-08-12 | 2000-06-29 | Inventa Ag | Copolyetherester hot melt adhesives |
| DE19852192C2 (en) | 1998-11-12 | 2003-04-24 | Bayer Ag | Aromatic copolyesters containing active ingredient |
| DE102005048131A1 (en) * | 2005-10-06 | 2007-04-12 | Bayer Innovation Gmbh | Antimicrobial plastic composition with low elution rate and long efficacy |
| DE102007006761A1 (en) | 2007-02-12 | 2008-08-14 | Bayer Innovation Gmbh | Partially neutralized active ingredients containing polymer molding compositions |
| US20120121901A1 (en) * | 2010-11-16 | 2012-05-17 | Lee Bong-Kyu | Water based bond sewing thread and method of manufacturing the same |
| BR112021017570A2 (en) | 2019-03-07 | 2021-11-09 | Covestro Intellectual Property Gmbh & Co Kg | Layered structure for producing a hinge, in particular, for producing multi-layer book covers |
| KR20230092915A (en) | 2020-10-26 | 2023-06-26 | 코베스트로 도이칠란트 아게 | Layered structures with inscriptions as visible security elements |
| AU2022399876A1 (en) | 2021-11-30 | 2024-05-23 | Covestro Deutschland Ag | Special plastic film for the production of security documents |
| DE202022000962U1 (en) | 2022-04-20 | 2022-07-19 | Covestro Deutschland Ag | Layer structure for manufacturing a hinge, especially for manufacturing multi-layer book covers with security features |
| WO2024121010A1 (en) | 2022-12-05 | 2024-06-13 | Covestro Deutschland Ag | Multi-layer construction having good properties for printing |
| AU2024283018A1 (en) | 2023-05-30 | 2025-10-23 | Covestro Deutschland Ag | Printable plastics film for production of security documents |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1234234A (en) * | 1968-02-13 | 1971-06-03 | ||
| US3583878A (en) * | 1968-09-11 | 1971-06-08 | Gazie K Ragep | Surface modifying treatment of polyester fiber articles to impart soil-release properties thereto |
-
0
- BE BE787375D patent/BE787375A/en not_active IP Right Cessation
-
1971
- 1971-08-09 US US00170287A patent/US3823031A/en not_active Expired - Lifetime
-
1972
- 1972-07-31 CA CA148,360A patent/CA976435A/en not_active Expired
- 1972-08-08 IT IT27998/72A patent/IT963827B/en active
- 1972-08-08 GB GB3700372A patent/GB1403774A/en not_active Expired
- 1972-08-08 NL NLAANVRAGE7210837,A patent/NL169763C/en not_active IP Right Cessation
- 1972-08-08 FR FR7228585A patent/FR2148537B1/fr not_active Expired
- 1972-08-09 DE DE2239271A patent/DE2239271C2/en not_active Expired
- 1972-08-09 JP JP7919672A patent/JPS5647307B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US3823031A (en) | 1974-07-09 |
| IT963827B (en) | 1974-01-21 |
| NL7210837A (en) | 1973-02-13 |
| DE2239271C2 (en) | 1986-01-16 |
| CA976435A (en) | 1975-10-21 |
| BE787375A (en) | 1973-02-09 |
| FR2148537A1 (en) | 1973-03-23 |
| NL169763C (en) | 1982-08-16 |
| DE2239271A1 (en) | 1973-02-22 |
| JPS5647307B1 (en) | 1981-11-09 |
| FR2148537B1 (en) | 1976-08-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |