GB1400286A - Process for the curing of acrylic acid adducts with ionising rays - Google Patents
Process for the curing of acrylic acid adducts with ionising raysInfo
- Publication number
- GB1400286A GB1400286A GB3937172A GB3937172A GB1400286A GB 1400286 A GB1400286 A GB 1400286A GB 3937172 A GB3937172 A GB 3937172A GB 3937172 A GB3937172 A GB 3937172A GB 1400286 A GB1400286 A GB 1400286A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- coatings
- curing
- rays
- tri
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title 1
- 238000000576 coating method Methods 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- -1 allyl compound Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 230000005855 radiation Effects 0.000 abstract 2
- 150000003254 radicals Chemical class 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004641 Diallyl-phthalate Substances 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract 1
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 abstract 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000011953 free-radical catalyst Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/022—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations
- C08F299/024—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polycondensates with side or terminal unsaturations the unsaturation being in acrylic or methacrylic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/12—Polycondensates containing more than one epoxy group per molecule of polycarboxylic acids with epihalohydrins or precursors thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
1400286 Coated products CIBA-GEIGY AG 24 Aug 1972 [3 Sept 1971] 39371/72 Heading B2E [Also in Division C3] Cured polyester-polyacrylate coatings are obtained by coating on a substrate and then irradiating with ionising radiation a compound of the formula: wherein R 1 , R 3 and R' 3 each independently represent H or methyl, A is a divalent or trivalent organic radical such that the compound of formula: is a di- or tri-glycidyl compound in which R 2 and R 2 ' represent H, or is a cycloaliphatic di- or tri-epoxide in which R 2 and/or R' 2 is linked to A and R 2 or R' 2 if not so linked represents H, B represents a polyester radical in which branched or unbranched alkylene and/or alkenylene chains alternate with carboxylic acid ester groups, the quotient Z/Q (where Z is the number of carbon atoms present in the recurring structural unit of B, and Q is the number of carboxylic acid ester linkages present in said recurring unit) is at least 3, the total number of carbon atoms present in B is at least 8, and n is 1 or 2. The above compound may optionally be mixed with a copolymerisable compound such as an ester of acrylic or methacrylic acid, acrylonitrile, methacrylonitrile, styrene, divinyl benzene, a vinyl ester or an allyl compound, e.g. diallyl phthalate. The curable coatings may also include a plasticiser, filler or pigment. Coatings may be produced on metal, wood, plastics, glass, paper or leather. Suitable forms of ionising radiation for effecting curing include X-rays, gamma rays and accelerated electrons. The curable material can advantageously be subjected to a heattreatment before, during or after curing. If desired a free radical catalyst, e.g. a peroxide, azo compound or persulphate, may be added to the curable material. In Examples coatings are formed on electrolytically pretreated iron sheet, galvanised steel sheet, hardwood-fibre sheets and ABS plastics sheets.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1294771A CH545323A (en) | 1971-09-03 | 1971-09-03 | Process for curing acrylic acid adducts with ionizing radiation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1400286A true GB1400286A (en) | 1975-07-16 |
Family
ID=4387873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3937172A Expired GB1400286A (en) | 1971-09-03 | 1972-08-24 | Process for the curing of acrylic acid adducts with ionising rays |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS4836287A (en) |
| AT (1) | AT317383B (en) |
| CH (1) | CH545323A (en) |
| DE (1) | DE2243190A1 (en) |
| FR (1) | FR2152051A5 (en) |
| GB (1) | GB1400286A (en) |
| IT (1) | IT967116B (en) |
| NL (1) | NL7211882A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4393181A (en) | 1982-06-30 | 1983-07-12 | Shell Oil Company | Polyfunctional phenolic-melamine epoxy resin curing agents |
| US4440802A (en) * | 1982-04-03 | 1984-04-03 | Ciba-Geigy Corporation | Preparation of prepregs from cellulosic fibers using water-borne resin compositions |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5072967A (en) * | 1973-10-30 | 1975-06-16 | ||
| AU3870478A (en) * | 1977-08-09 | 1980-02-14 | Somar Mfg | High energy radiation cruable resist material |
-
1971
- 1971-09-03 CH CH1294771A patent/CH545323A/en not_active IP Right Cessation
-
1972
- 1972-08-24 GB GB3937172A patent/GB1400286A/en not_active Expired
- 1972-08-31 NL NL7211882A patent/NL7211882A/xx unknown
- 1972-09-01 FR FR7231113A patent/FR2152051A5/fr not_active Expired
- 1972-09-01 AT AT753772A patent/AT317383B/en not_active IP Right Cessation
- 1972-09-01 DE DE19722243190 patent/DE2243190A1/en active Pending
- 1972-09-02 IT IT2878172A patent/IT967116B/en active
- 1972-09-02 JP JP8832372A patent/JPS4836287A/ja active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4440802A (en) * | 1982-04-03 | 1984-04-03 | Ciba-Geigy Corporation | Preparation of prepregs from cellulosic fibers using water-borne resin compositions |
| US4393181A (en) | 1982-06-30 | 1983-07-12 | Shell Oil Company | Polyfunctional phenolic-melamine epoxy resin curing agents |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4836287A (en) | 1973-05-28 |
| DE2243190A1 (en) | 1973-03-08 |
| NL7211882A (en) | 1973-03-06 |
| CH545323A (en) | 1973-12-15 |
| FR2152051A5 (en) | 1973-04-20 |
| IT967116B (en) | 1974-02-28 |
| AT317383B (en) | 1974-08-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |