GB1484087A - Preparation of cellular vinyl polymers - Google Patents
Preparation of cellular vinyl polymersInfo
- Publication number
- GB1484087A GB1484087A GB45865/74A GB4586574A GB1484087A GB 1484087 A GB1484087 A GB 1484087A GB 45865/74 A GB45865/74 A GB 45865/74A GB 4586574 A GB4586574 A GB 4586574A GB 1484087 A GB1484087 A GB 1484087A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- butyltin
- vinyl chloride
- stabilizer
- blowing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000001413 cellular effect Effects 0.000 title abstract 2
- 229920002554 vinyl polymer Polymers 0.000 title 1
- 239000004604 Blowing Agent Substances 0.000 abstract 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 5
- 239000012190 activator Substances 0.000 abstract 3
- 239000003381 stabilizer Substances 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 abstract 2
- 235000019399 azodicarbonamide Nutrition 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- WCRDXYSYPCEIAK-UHFFFAOYSA-N dibutylstannane Chemical compound CCCC[SnH2]CCCC WCRDXYSYPCEIAK-UHFFFAOYSA-N 0.000 abstract 2
- 239000012760 heat stabilizer Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- RZBBHEJLECUBJT-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS RZBBHEJLECUBJT-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000006057 Non-nutritive feed additive Substances 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- VRFNYSYURHAPFL-UHFFFAOYSA-N [(4-methylphenyl)sulfonylamino]urea Chemical compound CC1=CC=C(S(=O)(=O)NNC(N)=O)C=C1 VRFNYSYURHAPFL-UHFFFAOYSA-N 0.000 abstract 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000000732 arylene group Chemical group 0.000 abstract 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 1
- RGCPMRIOBZXXBR-UHFFFAOYSA-N butan-1-olate;dibutyltin(2+) Chemical compound CCCCO[Sn](CCCC)(CCCC)OCCCC RGCPMRIOBZXXBR-UHFFFAOYSA-N 0.000 abstract 1
- UGGGKQQQXZWAKN-RPEJVSFFSA-H butyltin(3+) (Z)-2-dodecylbut-2-enedioate Chemical compound CCCC[Sn+3].CCCC[Sn+3].CCCCCCCCCCCC\C(C([O-])=O)=C\C([O-])=O.CCCCCCCCCCCC\C(C([O-])=O)=C\C([O-])=O.CCCCCCCCCCCC\C(C([O-])=O)=C\C([O-])=O UGGGKQQQXZWAKN-RPEJVSFFSA-H 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract 1
- 235000013539 calcium stearate Nutrition 0.000 abstract 1
- 239000008116 calcium stearate Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- -1 organo tin compounds Chemical class 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 235000019809 paraffin wax Nutrition 0.000 abstract 1
- 235000019271 petrolatum Nutrition 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 238000010094 polymer processing Methods 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- RVXKJRWBHPHVOV-UHFFFAOYSA-L zinc;oct-2-enoate Chemical compound [Zn+2].CCCCCC=CC([O-])=O.CCCCCC=CC([O-])=O RVXKJRWBHPHVOV-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/101—Agents modifying the decomposition temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
1484087 Heat stabilizer/blowing agent activator for vinyl chloride polymers M & T INTERNATIONAL BV 23 Oct 1974 [25 Oct 1973] 45865/74 Heading C3C A composition for the preparation of cellular vinyl chloride polymers comprises: (i) 100 parts by weight of a vinyl chloride homopolymer or a copolymer of vinyl chloride with up to 50% by weight of at least one copolymerizable ethylenically unsaturated monomer; (ii) 0.1-10 parts by weight of a heat decomposable blowing agent; (iii) 0.1-10 parts by weight of a combined blowing agent activator and heat stabilizer which comprises: (I) 5-99% by weight of a diorganotin compound of formula (II) 1-95%, by weight, based on component (I), of an auxiliary activator-stabilizer selected from organo tin compounds of the general formula wherein R<SP>1</SP> represents C 1-18 alkyl, R<SP>2</SP> represents C 4-18 alkyl or R<SP>1</SP> and R<SP>2</SP> are cycloalkyl, aryl, alkaryl or aralkyl, each of which contain 6-18 carbon atoms, R<SP>3</SP> is R<SP>1</SP>, X represents a radical selected from wherein R<SP>4</SP> represents C 1-12 alkylene, C 6-12 arylene, or aralkylene, R<SP>5</SP> and R<SP>6</SP> are R<SP>2</SP>, R<SP>7</SP> represents the residue resulting from the removal of the hydrogen atom(s) from the hydroxyl group of a phenol or an alcohol, said alcohol being C 2-18 and comprising 1-4 hydroxyl radicals and R<SP>8</SP> represents and a is 1 or 2. Additionally the blowing agent may be di-n-butyltin laurate, monobutyltin tris (n-dodecyl maleate), di-n-butyltin bis-(isooctyl maleate), di-n-butyltin di-n-butoxide or zinc octenoate. Preferred copolymers are vinyl chloride with at least one of vinyl acetate, vinylidene chloride, ethylene, acrylonitrile and esters of acrylic or methacrylic acids whilst the preferred blowing agents are azobisformamide and p-toluenesulphonylsemicarbazide. The examples illustrate different combinations of stabilizer activator with blowing agents and a specific formulation consisted of polyvinylchloride, calcium carbonate, an acrylic polymer processing aid, acrylonitrile/butadiene styrene terpolymer, titanium dioxide, azobisformamide, paraffin wax, calcium stearate and, as stabilizer di - n - butyltin - S,S<SP>1</SP> - bis - (isooctylmercaptoacetate), or Ba/Cd carboxylates as controls, and 90 : 10 weight ratio of di-n-butyltin- S,S<SP>1</SP> - bis - (tri - n - decylmercaptide) and di - nbutyltin dilaurate as illustrating the invention.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40941473A | 1973-10-25 | 1973-10-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1484087A true GB1484087A (en) | 1977-08-24 |
Family
ID=23620393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB45865/74A Expired GB1484087A (en) | 1973-10-25 | 1974-10-23 | Preparation of cellular vinyl polymers |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5542101B2 (en) |
| CA (1) | CA1049700A (en) |
| DE (1) | DE2522510C2 (en) |
| FR (1) | FR2311798A1 (en) |
| GB (1) | GB1484087A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3067234D1 (en) * | 1979-02-22 | 1984-05-03 | Ciba Geigy Ag | Mixtures consisting of an organo-tin alcoholate and an organo-tin mercaptide; their use as stabilizers for chlorinated polymers |
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
| JPS58180661A (en) * | 1982-04-12 | 1983-10-22 | 三井東圧化学株式会社 | Vinyl chloride resin nonwoven fiber structure |
| CN102336981A (en) * | 2011-05-27 | 2012-02-01 | 湖北众联塑业有限公司 | Processing modifier for polyvinyl chloride plastic-wood material |
| CN102336982A (en) * | 2011-05-27 | 2012-02-01 | 湖北众联塑业有限公司 | Processing modifier for polyvinyl chloride sealing strips |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1229521A (en) * | 1968-09-16 | 1971-04-21 | ||
| US3706679A (en) * | 1970-08-06 | 1972-12-19 | Goodyear Tire & Rubber | Vinyl resin blowable into a rigid smooth skin microcellular profile |
| FR2229702B1 (en) * | 1973-05-14 | 1976-05-07 | Rhone Poulenc Ind |
-
1974
- 1974-10-22 JP JP12107774A patent/JPS5542101B2/ja not_active Expired
- 1974-10-23 GB GB45865/74A patent/GB1484087A/en not_active Expired
- 1974-10-24 CA CA212,225A patent/CA1049700A/en not_active Expired
-
1975
- 1975-05-21 DE DE2522510A patent/DE2522510C2/en not_active Expired
- 1975-05-23 FR FR7516184A patent/FR2311798A1/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5074669A (en) | 1975-06-19 |
| FR2311798B1 (en) | 1979-01-19 |
| DE2522510C2 (en) | 1986-01-30 |
| JPS5542101B2 (en) | 1980-10-28 |
| CA1049700A (en) | 1979-02-27 |
| AU7325274A (en) | 1976-03-18 |
| FR2311798A1 (en) | 1976-12-17 |
| DE2522510A1 (en) | 1976-12-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |