GB1469302A - Synthetic resins and process for obtaining them - Google Patents
Synthetic resins and process for obtaining themInfo
- Publication number
- GB1469302A GB1469302A GB3037974A GB3037974A GB1469302A GB 1469302 A GB1469302 A GB 1469302A GB 3037974 A GB3037974 A GB 3037974A GB 3037974 A GB3037974 A GB 3037974A GB 1469302 A GB1469302 A GB 1469302A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- polymer
- agglomerated
- copolymer
- grafting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003002 synthetic resin Polymers 0.000 title 1
- 239000000057 synthetic resin Substances 0.000 title 1
- 229920001971 elastomer Polymers 0.000 abstract 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- 229920001577 copolymer Polymers 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000005060 rubber Substances 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- -1 vinylidene aromatic compound Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
1469302 Grafting agglomerated butadienealkyl acrylate rubbers RHONE-PROGIL SA 9 July 1974 [11 July 1973] 30379/74 Heading C3G A resin comprises 2 to 80% by weight of a rubbery polymer and 98 to 20% by weight of a polymer partly grafted upon the rubbery polymer and comprised of 100 to 50% by weight of a vinyl or vinylidene aromatic compound and 0 to 50% by weight of at least one acrylic or methacrylic derivative, wherein the rubbery polymer is a cross-linked copolymer comprised of from 95 to 50% by weight of butadiene and from 5 to 50% by weight of a C 1 to C 10 -alkyl acrylate, the gel ratio of the rubbery copolymer being greater than 80% and the swelling index less than 25, and 10 to 90% of the rubbery polymer being agglomerated before grafting into particles of diameter 0À03 to 10 microns and the degree of grafting of the polymer being from 0À1 to 250%. Examples are given in which butadiene/n-butyl acrylate copolymer latex is agglomerated with polyethylene glycol before being grafted with styrene and acrylonitrile. The graft polymers produced are blended with styrene-acrylonitrile copolymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7325395A FR2239503B1 (en) | 1973-07-11 | 1973-07-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1469302A true GB1469302A (en) | 1977-04-06 |
Family
ID=9122402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3037974A Expired GB1469302A (en) | 1973-07-11 | 1974-07-09 | Synthetic resins and process for obtaining them |
Country Status (11)
| Country | Link |
|---|---|
| AT (1) | AT339045B (en) |
| BE (1) | BE817507A (en) |
| DE (1) | DE2432953C2 (en) |
| DK (1) | DK369974A (en) |
| ES (1) | ES428180A1 (en) |
| FR (1) | FR2239503B1 (en) |
| GB (1) | GB1469302A (en) |
| IT (1) | IT1016902B (en) |
| NL (1) | NL164058C (en) |
| NO (1) | NO145578C (en) |
| SE (1) | SE419450B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4460749A (en) * | 1981-01-13 | 1984-07-17 | Bayer Aktiengesellschaft | Rubber powders |
| GB2194949A (en) * | 1986-09-13 | 1988-03-23 | Nihon Plant Gijutsu Kabushiki | Graft polymerisation of monomers on rubber |
| US5336720A (en) * | 1991-06-05 | 1994-08-09 | Rohm And Haas Company | Impact resistant polymers |
| WO1998020057A1 (en) * | 1996-11-04 | 1998-05-14 | Lg Chemical Limited | A process for producing thermoplastic resins having high impact strength |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0725853B2 (en) * | 1989-04-01 | 1995-03-22 | 三菱化学株式会社 | Graft copolymer resin |
| JPH09509209A (en) * | 1994-02-22 | 1997-09-16 | ザ ダウ ケミカル カンパニー | Method for producing multimodal ABS polymer |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1103243A (en) * | 1964-07-28 | 1968-02-14 | Kanegafuchi Chemical Ind | Thermoplastic compositions containing graft polymers and vinyl chloride polymers and process of making same |
| GB1105187A (en) * | 1965-01-25 | 1968-03-06 | Kanegafuchi Chemical Ind | Method of manufacturing butadiene-methylmethacrylate-vinyl aromatic polymer compositions |
| US3536786A (en) * | 1967-09-18 | 1970-10-27 | Goodrich Co B F | High-impact,high temperature thermoplastic and method of preparing same |
-
1973
- 1973-07-11 FR FR7325395A patent/FR2239503B1/fr not_active Expired
-
1974
- 1974-07-09 DE DE2432953A patent/DE2432953C2/en not_active Expired
- 1974-07-09 NL NL7409247.A patent/NL164058C/en not_active IP Right Cessation
- 1974-07-09 GB GB3037974A patent/GB1469302A/en not_active Expired
- 1974-07-09 NO NO742511A patent/NO145578C/en unknown
- 1974-07-09 SE SE7409031A patent/SE419450B/en not_active IP Right Cessation
- 1974-07-10 AT AT572174A patent/AT339045B/en not_active IP Right Cessation
- 1974-07-10 BE BE146439A patent/BE817507A/en not_active IP Right Cessation
- 1974-07-10 DK DK369974A patent/DK369974A/da not_active Application Discontinuation
- 1974-07-10 IT IT52035/74A patent/IT1016902B/en active
- 1974-07-11 ES ES428180A patent/ES428180A1/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4460749A (en) * | 1981-01-13 | 1984-07-17 | Bayer Aktiengesellschaft | Rubber powders |
| GB2194949A (en) * | 1986-09-13 | 1988-03-23 | Nihon Plant Gijutsu Kabushiki | Graft polymerisation of monomers on rubber |
| GB2194949B (en) * | 1986-09-13 | 1990-08-22 | Nihon Plant Gijutsu Kabushiki | Process for producing graft polymer for abs resin manufacture or abs resin itself |
| US5336720A (en) * | 1991-06-05 | 1994-08-09 | Rohm And Haas Company | Impact resistant polymers |
| US6080815A (en) * | 1996-04-11 | 2000-06-27 | Lg Chemical Limited | Process for producing thermoplastic resins having high impact strength |
| WO1998020057A1 (en) * | 1996-11-04 | 1998-05-14 | Lg Chemical Limited | A process for producing thermoplastic resins having high impact strength |
Also Published As
| Publication number | Publication date |
|---|---|
| DK369974A (en) | 1975-03-17 |
| IT1016902B (en) | 1977-06-20 |
| DE2432953A1 (en) | 1975-01-30 |
| FR2239503B1 (en) | 1976-04-30 |
| NL164058C (en) | 1980-11-17 |
| DE2432953C2 (en) | 1982-04-15 |
| NL7409247A (en) | 1975-01-14 |
| ATA572174A (en) | 1977-01-15 |
| NO145578B (en) | 1982-01-11 |
| SE419450B (en) | 1981-08-03 |
| BE817507A (en) | 1975-01-10 |
| FR2239503A1 (en) | 1975-02-28 |
| NO145578C (en) | 1982-04-21 |
| NL164058B (en) | 1980-06-16 |
| SE7409031L (en) | 1975-01-13 |
| NO742511L (en) | 1975-02-10 |
| AT339045B (en) | 1977-09-26 |
| ES428180A1 (en) | 1976-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |