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GB1468160A - Hydrocarbon conversion process - Google Patents

Hydrocarbon conversion process

Info

Publication number
GB1468160A
GB1468160A GB4659073A GB4659073A GB1468160A GB 1468160 A GB1468160 A GB 1468160A GB 4659073 A GB4659073 A GB 4659073A GB 4659073 A GB4659073 A GB 4659073A GB 1468160 A GB1468160 A GB 1468160A
Authority
GB
United Kingdom
Prior art keywords
catalyst
bar
hydrodesulphurization
partial pressure
pore volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4659073A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Priority to GB4659073A priority Critical patent/GB1468160A/en
Priority to BE1006196A priority patent/BE820198A/en
Priority to CA210,553A priority patent/CA1038789A/en
Priority to IT7428024A priority patent/IT1033100B/en
Priority to SE7412460A priority patent/SE400987B/en
Priority to DE19742447303 priority patent/DE2447303A1/en
Priority to JP49113384A priority patent/JPS6027712B2/en
Priority to NL7413047A priority patent/NL7413047A/en
Priority to AU73960/74A priority patent/AU491580B2/en
Priority to ZA00746298A priority patent/ZA746298B/en
Priority to FR7433309A priority patent/FR2246622B1/fr
Publication of GB1468160A publication Critical patent/GB1468160A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1468160 Hydrodesulphurization of heavy oils SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 9 April 1974 [5 Oct 1973] 46590/73 Heading C5E The catalytic hydrodesulphurization, without catalyst replenishment, of vanadium- and nickel-containing residual hydrocarbon oils is carried out under a water-vapour partial pressure of 0À5-30 bar in the presence of a catalyst having a total pore volume above 0À30 ml./g., and being either in the form of particles of which less than 10% of the total pore volume is in pores with a diameter above 100 nm and the specific average pore diameter (p) and specific average particle diameter (d) are such that when P H2 is the hydrogen partial pressure in bar, p is in nm and d is in mm or of agglomerates having more than 10% of their pore volume in pores of diameter above 100 nm and formed from such particles. The hydrodesulphurization can be carried out at 300-475‹ C. and a hydrogen partial pressure of 30-200 bar using a catalyst comprising Ni and/or Co together with Mo and/or W on an alumina or silica-alumina support. The water can be added in admixture with the liquid feed, as steam, or as a precursor such as an alcohol. The feed can be subjected to a preliminary hydrodemetallization using a catalyst comprising Ni+V on a silica carrier.
GB4659073A 1973-10-05 1973-10-05 Hydrocarbon conversion process Expired GB1468160A (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
GB4659073A GB1468160A (en) 1973-10-05 1973-10-05 Hydrocarbon conversion process
BE1006196A BE820198A (en) 1973-10-05 1974-09-23 PROCESS FOR CONVERSION OF HYDROCARBONS
CA210,553A CA1038789A (en) 1973-10-05 1974-10-02 Hydrocarbon conversion process
IT7428024A IT1033100B (en) 1973-10-05 1974-10-02 PROCESS FOR THE CONVERSION OF HYDROCARBONS
SE7412460A SE400987B (en) 1973-10-05 1974-10-03 PROCEDURE FOR CATALYTIC HYDRODULFULRATION WITHOUT CATALYST FILLING OF VANADIN- AND NICKEL-CONTAINING CARBOHYDRATE STARTERS IN THE PRESENCE OF WHEAT AND AN INSIDE COLATOR AND OF A NERVAR
DE19742447303 DE2447303A1 (en) 1973-10-05 1974-10-03 PROCESS FOR CATALYTIC HYDRATING DESULFURIZATION OF HYDROCARBON RESIDUAL SOILS
JP49113384A JPS6027712B2 (en) 1973-10-05 1974-10-03 Hydrocarbon conversion method
NL7413047A NL7413047A (en) 1973-10-05 1974-10-03 METHOD FOR CONVERSION OF HYDROCARBON
AU73960/74A AU491580B2 (en) 1973-10-05 1974-10-03 Process forthe catalytic hydrodesulphurization of residual hydrocarbon oils
ZA00746298A ZA746298B (en) 1973-10-05 1974-10-03 Hydrocarbon conversion process
FR7433309A FR2246622B1 (en) 1973-10-05 1974-10-03

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4659073A GB1468160A (en) 1973-10-05 1973-10-05 Hydrocarbon conversion process

Publications (1)

Publication Number Publication Date
GB1468160A true GB1468160A (en) 1977-03-23

Family

ID=10441857

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4659073A Expired GB1468160A (en) 1973-10-05 1973-10-05 Hydrocarbon conversion process

Country Status (9)

Country Link
JP (1) JPS6027712B2 (en)
BE (1) BE820198A (en)
CA (1) CA1038789A (en)
DE (1) DE2447303A1 (en)
FR (1) FR2246622B1 (en)
GB (1) GB1468160A (en)
IT (1) IT1033100B (en)
NL (1) NL7413047A (en)
ZA (1) ZA746298B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900711A (en) * 1988-03-23 1990-02-13 Harshaw/Filtrol Partnership Hydrotreating catalyst

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS601056B2 (en) * 1980-02-19 1985-01-11 千代田化工建設株式会社 Hydrotreatment of heavy hydrocarbon oils containing asphaltenes
JPH0627425Y2 (en) * 1983-01-26 1994-07-27 三菱製紙株式会社 No-carbon paper for kanji printer
DE68907361T2 (en) * 1988-03-23 1993-10-14 Engelhard Corp Hydrogen treatment catalyst and process.
WO2014176197A1 (en) * 2013-04-24 2014-10-30 Shell Oil Company Activation of a hydroprocessing catalyst with steam

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7214647A (en) * 1972-10-30 1972-12-27 Hydro-desulphurising residual hydrocarbons - on catalysts with pore diameter and particle size related to hydrogen pressure

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900711A (en) * 1988-03-23 1990-02-13 Harshaw/Filtrol Partnership Hydrotreating catalyst

Also Published As

Publication number Publication date
JPS6027712B2 (en) 1985-07-01
JPS5065508A (en) 1975-06-03
CA1038789A (en) 1978-09-19
DE2447303C2 (en) 1988-01-14
FR2246622B1 (en) 1979-03-16
FR2246622A1 (en) 1975-05-02
BE820198A (en) 1975-03-24
IT1033100B (en) 1979-07-10
ZA746298B (en) 1975-10-29
DE2447303A1 (en) 1975-04-17
NL7413047A (en) 1975-04-08

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19930409