[go: up one dir, main page]

GB1467865A - Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles - Google Patents

Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles

Info

Publication number
GB1467865A
GB1467865A GB3281474A GB3281474A GB1467865A GB 1467865 A GB1467865 A GB 1467865A GB 3281474 A GB3281474 A GB 3281474A GB 3281474 A GB3281474 A GB 3281474A GB 1467865 A GB1467865 A GB 1467865A
Authority
GB
United Kingdom
Prior art keywords
ammoxidation
nitriles
olefins
beta
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3281474A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2338111A external-priority patent/DE2338111C2/en
Application filed by BASF SE filed Critical BASF SE
Publication of GB1467865A publication Critical patent/GB1467865A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

1467865 Oxidation/ammoxidation catalysts BASF AG 25 July 1974 [27 July 1973] 32814/ 74 Addition to 1437235 Heading B1E [Also in Division C2] Various oxidation or ammoxidation catalysts within the formula Mo 12 Bi a Me<SP>1</SP> b Me<SP>2</SP> c Me<SP>3</SP> d Me<SP>4</SP> e Me<SP>5</SP> f Zn h O g in which Me<SP>1</SP> is In and/or La and/or Ga and/ or Al, Me<SP>2</SP> is Fe and/or Cu, Me<SP>3</SP> is Ni and/or Co, Me<SP>4</SP> is one or more elements selected from P, B, As, Cr, V and W, Me<SP>5</SP> is one or more metals selected from Ta, Sm, Nb, Ag, Pb, Mn, Re, Sn, Ge, Mg, Ca, Sr, Be and Ba, a is from 0.1 to 6, b is from 0.005 to 3, c is from 0.1 to 8, d is from 0 to 16, e is from 0 to 6, f is from 0 to 3, g is from 36 to 102, and h is greater than zero, e.g. 0.1 to 10 are prepared conventionally by evaporating solutions of appropriate salts in the presence of carrier, e.g. silica sol, and calcining.
GB3281474A 1973-07-27 1974-07-25 Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles Expired GB1467865A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2338111A DE2338111C2 (en) 1972-10-12 1973-07-27 Process for the catalytic oxidation of propylene or isobutylene to acrolein or methacrolein in the gas phase with molecular oxygen

Publications (1)

Publication Number Publication Date
GB1467865A true GB1467865A (en) 1977-03-23

Family

ID=5888103

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3281474A Expired GB1467865A (en) 1973-07-27 1974-07-25 Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles

Country Status (5)

Country Link
JP (2) JPS5047917A (en)
BE (1) BE818210R (en)
FR (1) FR2238693B2 (en)
GB (1) GB1467865A (en)
IT (1) IT1048284B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2118939A (en) * 1982-04-14 1983-11-09 Halcon Sd Group Inc Conversion of alkanes to unsaturated aldehydes
US6333011B1 (en) 1997-04-23 2001-12-25 Basf Aktiengesellschaft Apparatus for measuring temperatures in tubular reactors

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL175175C (en) * 1970-10-30 1984-10-01 Standard Oil Co Ohio PROCESS FOR CONVERTING PROPENE AND / OR ISOBUTENE WITH A MOLECULAR OXYGEN-CONTAINING GAS AND AMMONIA IN THE PRESENCE OF A CATALYST.
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
JPS5231026A (en) * 1975-09-05 1977-03-09 Ube Ind Ltd Process for preparation of acrylonitrile
DE2626887B2 (en) * 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Catalyst for the oxadation of (methacrolein to (meth) acrylic acid
DE2735414A1 (en) * 1976-08-06 1978-02-09 Nippon Zeon Co OXYDATION OF OLEFINS
JPS584691B2 (en) * 1977-11-07 1983-01-27 宇部興産株式会社 Method for producing methacrolein
CA1299193C (en) * 1986-07-17 1992-04-21 Gordon Gene Harkreader Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
CA1305178C (en) * 1986-08-21 1992-07-14 Gordon Gene Harkreader Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
CA1327814C (en) * 1988-09-26 1994-03-15 William George Etzkorn Anhydrous diluents for the isobutylene oxidation reaction to methacrolein and methacrolein oxidation to methacrylic acid
JPH03262748A (en) * 1990-03-12 1991-11-22 Sango:Kk Roof carrier

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2118939A (en) * 1982-04-14 1983-11-09 Halcon Sd Group Inc Conversion of alkanes to unsaturated aldehydes
US6333011B1 (en) 1997-04-23 2001-12-25 Basf Aktiengesellschaft Apparatus for measuring temperatures in tubular reactors
US6657088B2 (en) 1997-04-23 2003-12-02 Basf Aktiengesellschaft Temperature measurements in tubular reactors during treatment of fluid masses

Also Published As

Publication number Publication date
FR2238693A2 (en) 1975-02-21
BE818210R (en) 1975-01-29
FR2238693B2 (en) 1978-12-15
JPS5820944B2 (en) 1983-04-26
JPS5047917A (en) 1975-04-28
IT1048284B (en) 1980-11-20
JPS5695144A (en) 1981-08-01

Similar Documents

Publication Publication Date Title
DE2560480C2 (en) Process for producing a regenerated catalyst
GB1437235A (en) Catalytic oxidation or ammoxidation of alpha-olefins
GB1492115A (en) Catalysts for use in and process for preparing acrylonitrile
GB1467865A (en) Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles
GB1523141A (en) Process for the oxidation of olefins using catalysts containing various promoter elements
GB1489559A (en) Catalytic process for the preparation of acrylic acid or methacrylic acid
GB1174777A (en) Process for Oxidising Olefins to Aldehydes
GB1492267A (en) Production of unsaturated acids from the corresponding aldehydes
GB1374460A (en) Catalyst composition
GB1513335A (en) Process and a catalyst for the preparation of unsaturated carboxylic acid
GB1201050A (en) Reduction process
GB1525577A (en) Oxidation catalyst
GB1385244A (en) Process for producing acrolein or mixtures of acrolein and acrylic acid and catalyst therefor
GB1473035A (en) Catalyst and process for producing unsaturated carboxylic acid
SE7406934L (en)
GB1283369A (en) Catalysts containing antimony oxide and process for their production
GB1412059A (en) Process for production of acrylic acid
GB1447098A (en) Superior catalyst prepared by impregnation of preformed matrix and processes using said catalyst
GB1425221A (en) Process for the manufacture of unsaturated aldehydes, acids and nitriles
GB1477029A (en) Catalyst compositions especially useful for preparation of unsaturated acids
GB1448947A (en) Oxidation catalyst and method of manufacturing methacrylic acid using same
GB1496890A (en) Manufacture of magnetic materials which exhibit exchange anisotropy
GB1237954A (en)
GB1456752A (en) Catalyst and process for the production of unsaturated carbonyl compounds
GB1346626A (en) Catalyst and process for the preparation of unsaturated carbonyl compounds

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee