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GB1465912A - Foamable vinyl polymers containing surfactants - Google Patents

Foamable vinyl polymers containing surfactants

Info

Publication number
GB1465912A
GB1465912A GB3446973A GB3446973A GB1465912A GB 1465912 A GB1465912 A GB 1465912A GB 3446973 A GB3446973 A GB 3446973A GB 3446973 A GB3446973 A GB 3446973A GB 1465912 A GB1465912 A GB 1465912A
Authority
GB
United Kingdom
Prior art keywords
mixture
acid
weight
vinyl chloride
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3446973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3446973A priority Critical patent/GB1465912A/en
Priority to IT25336/74A priority patent/IT1017278B/en
Priority to DK388274AA priority patent/DK137959B/en
Priority to NL7409738A priority patent/NL7409738A/en
Priority to DE2434681A priority patent/DE2434681A1/en
Priority to FR7425083A priority patent/FR2237929B1/fr
Priority to US05/490,191 priority patent/US3959188A/en
Priority to JP49083086A priority patent/JPS5070465A/ja
Priority to BE146779A priority patent/BE817898A/en
Priority to CA205,185A priority patent/CA1045300A/en
Publication of GB1465912A publication Critical patent/GB1465912A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

1465912 Foamable vinyl chloride polymer/ surfactant compositions IMPERIAL CHEMICAL INDUSTRIES Ltd 10 July 1974 [19 July 1973] 34469/73 Heading C3C A foamable composition comprises a homo- or copolymer of vinyl chloride, a non-ionic surfactant and an anionic surfactant which is a salt of an organic acid and a mono- or dialkanolamine in which the salt is an alkylbenzene carboxylate, organosulphonate, an alkyl ether sulphate (a compound obtained by sulphating an alcohol of 10 to 14 carbon atoms, in which the alcohol has previously been reacted with one ethylene oxide unit per molecule) or organophosphate which preferably contains at least one carbon chain of 7-22 carbon atoms, a chain of 7-22 propylene oxide or higher alkylene oxide units, or the carbon chain forms the alkyl moiety of an alkyl benzene group (e.g. a pdodecylbenzene sulphonate). The organic acid may be a C 10-14 fatty acid. The non-ionic surfactant may be an alkoxylate (especially ethoxylate) of an alkylphenol wherein the alkoxylate preferably comprises 5-20 alkylene oxide units and the alkylphenol preferably comprises at least one alkyl group of C 5-15 (e.g. p-octylphenolethoxylate or p-nonylphenol ethoxylate containing 13-15 ethylene oxide units), or may be an alkoxylate of an alcohol, a fatty acid amide or an amine which are preferably saturated aliphatic compounds of 5-20 carbon atoms. The vinyl chloride polymer may be a copolymer of vinyl chloride with vinylacetate, acrylonitrile or vinylidene chloride. The composition may also comprise a plasticizer which may be a chlorinated paraffin, a butadiene/acrylonitrile copolymer or an ester. Preferred esters are tricresylphosphate, or an ester of orthophthalic acid, sebacic acid or adipic acid with benzylalcohol or a C 4-14 alkanol or mixtures of C 4-14 alkanols (e.g. di-iso-octylphthalate, di(2-ethylhexylphthalate), the diester of o-phthalic acid with a mixture of C 7-9 alkanols, such a mixture being available under the Registered Trade Mark "ALPHANOL"). The compositions may contain up to 20% by weight of total surfactant, based on the weight of the composition, wherein the weight ratio of anionic to non-ionic surfactant is preferably 1 : 5 to 5 : 1 and preferably contain 20-60% by weight of plasticizer, based on the weight of the composition. In the examples, a p-nonylphenol/ethylene oxide condensate was added to a mixture of dodecylbenzenesulphonic acid and the diester of o-phthalic acid with a mixture of C 7-9 alcohols neutralized with (1), (2), (4) monoethanolamine; (3) n-propanolamine. The mixtures thus obtained were added to a mixture of polyvinylchloride, vinylchloride/- vinylacetate copolymer, limestone filler and a plasticizer mixture consisting of butyl benzylphthalate, a chlorinated paraffin and the diester of o-phthalic acid with a mixture of C 7-9 alcohols to yield foamable compositions. The wet foam, dry foam densities (g./ml.) of the products are (1) 0À49, 0À48; (2) 0À28, 0À28; (3) 0À30, 0À30; (4) 0À34, 0À35.
GB3446973A 1973-07-19 1973-07-19 Foamable vinyl polymers containing surfactants Expired GB1465912A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB3446973A GB1465912A (en) 1973-07-19 1973-07-19 Foamable vinyl polymers containing surfactants
IT25336/74A IT1017278B (en) 1973-07-19 1974-07-18 SURFACTANTS AND THEIR USES IN EXPANDABLE FOAM POLYMER COMPOUNDS
DK388274AA DK137959B (en) 1973-07-19 1974-07-18 Foamy homo- or copolymer of vinyl chloride.
NL7409738A NL7409738A (en) 1973-07-19 1974-07-18 PROCESS FOR PREPARING SURFACE-ACTIVE FORMULATIONS AND FOAMMABLE VINYL POLY MORE COMPOSITIONS CONTAINING SUCH FORMULATION.
DE2434681A DE2434681A1 (en) 1973-07-19 1974-07-18 VINYL CHLORIDE POLYMER-BASED FOAMABLE COMPOSITION AND THEIR USE FOR VINYL CHLORIDE HOMO AND COPOLYMER FOAMS
FR7425083A FR2237929B1 (en) 1973-07-19 1974-07-18
US05/490,191 US3959188A (en) 1973-07-19 1974-07-19 Surfactants and their use in foamable polymer compositions
JP49083086A JPS5070465A (en) 1973-07-19 1974-07-19
BE146779A BE817898A (en) 1973-07-19 1974-07-19 SURFACTANTS AND THEIR USE IN EXPANSIBLE POLYMER COMPOSITIONS
CA205,185A CA1045300A (en) 1973-07-19 1974-07-19 Surfactants and their use in foamable polymer compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3446973A GB1465912A (en) 1973-07-19 1973-07-19 Foamable vinyl polymers containing surfactants

Publications (1)

Publication Number Publication Date
GB1465912A true GB1465912A (en) 1977-03-02

Family

ID=10366029

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3446973A Expired GB1465912A (en) 1973-07-19 1973-07-19 Foamable vinyl polymers containing surfactants

Country Status (10)

Country Link
US (1) US3959188A (en)
JP (1) JPS5070465A (en)
BE (1) BE817898A (en)
CA (1) CA1045300A (en)
DE (1) DE2434681A1 (en)
DK (1) DK137959B (en)
FR (1) FR2237929B1 (en)
GB (1) GB1465912A (en)
IT (1) IT1017278B (en)
NL (1) NL7409738A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994004602A1 (en) * 1992-08-11 1994-03-03 Nauchno-Kommercheskoye Predpriyatiye 'polimerplast' Composition for obtaining foamed polyvinylchloride material and method of obtaining it
US5705538A (en) * 1992-08-11 1998-01-06 Polimerplast Composition for obtaining foamed polyvinylchloride material and method of obtaining it

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61130350A (en) * 1984-11-30 1986-06-18 Nippon Zeon Co Ltd Mechanically foamable plastisol composition
US6500873B2 (en) * 2000-09-07 2002-12-31 Occidental Chemical Corporation Polyvinyl chloride resins and method of preparation and use in the production of whitened polyvinyl chloride foam

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1518817A (en) * 1967-02-06 1968-03-29 Pechiney Saint Gobain Process for manufacturing thermoplastic resin foam
DE1694131B2 (en) * 1967-02-10 1976-03-04 Hoechst Ag, 6000 Frankfurt PROCESS FOR PRODUCING RIGID FOAM COMPOSITIONS FROM VINYL CHLORIDE POLYMERIZATE DISPERSIONS
FR1519852A (en) * 1967-02-23 1968-04-05 Pechiney Saint Gobain Compositions for the manufacture of foam products from thermoplastic resins, in particular from vinyl resins
GB1186118A (en) * 1969-02-10 1970-04-02 Leo Feit Improved Vinyl Compositions.
FR2139885B1 (en) * 1971-05-29 1973-07-13 Huels Chemische Werke Ag

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994004602A1 (en) * 1992-08-11 1994-03-03 Nauchno-Kommercheskoye Predpriyatiye 'polimerplast' Composition for obtaining foamed polyvinylchloride material and method of obtaining it
US5705538A (en) * 1992-08-11 1998-01-06 Polimerplast Composition for obtaining foamed polyvinylchloride material and method of obtaining it

Also Published As

Publication number Publication date
IT1017278B (en) 1977-07-20
DE2434681A1 (en) 1975-02-06
DK388274A (en) 1975-03-17
NL7409738A (en) 1975-01-21
BE817898A (en) 1975-01-20
DK137959C (en) 1978-11-06
US3959188A (en) 1976-05-25
JPS5070465A (en) 1975-06-11
DK137959B (en) 1978-06-12
FR2237929B1 (en) 1978-01-20
FR2237929A1 (en) 1975-02-14
CA1045300A (en) 1978-12-26

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee