GB1465063A - Method of bonding an aromatic polyamide filamentary material to a rubber composition - Google Patents
Method of bonding an aromatic polyamide filamentary material to a rubber compositionInfo
- Publication number
- GB1465063A GB1465063A GB2479773A GB2479773A GB1465063A GB 1465063 A GB1465063 A GB 1465063A GB 2479773 A GB2479773 A GB 2479773A GB 2479773 A GB2479773 A GB 2479773A GB 1465063 A GB1465063 A GB 1465063A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filamentary material
- resin
- rubber
- formaldehyde
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 9
- 229920001971 elastomer Polymers 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000005060 rubber Substances 0.000 title abstract 5
- 239000004760 aramid Substances 0.000 title abstract 2
- 229920003235 aromatic polyamide Polymers 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 abstract 4
- 239000011347 resin Substances 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- -1 aromatic hydroxy compound Chemical class 0.000 abstract 2
- 239000000470 constituent Substances 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 239000000806 elastomer Substances 0.000 abstract 2
- 229920001568 phenolic resin Polymers 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 abstract 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- YCGKJPVUGMBDDS-UHFFFAOYSA-N 3-(6-azabicyclo[3.1.1]hepta-1(7),2,4-triene-6-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2C=3C=C2C=CC=3)=C1 YCGKJPVUGMBDDS-UHFFFAOYSA-N 0.000 abstract 1
- 244000043261 Hevea brasiliensis Species 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 208000037062 Polyps Diseases 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 abstract 1
- 229920003052 natural elastomer Polymers 0.000 abstract 1
- 229920001194 natural rubber Polymers 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Moulding By Coating Moulds (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
1465063 Bonding rubber and filamentary material DUNLOP Ltd 16 May 1974 [24 May 1973] 24797/73 Heading B5N Aromatic polyamide filamentary material, particularly reinforcing cords for tyres, belts and hoses, is bonded to a rubber composition by (1) applying an aqueous solution or dispersion of an epoxy resin to the filamentary material and drying the coated material; (2) applying an aqueous dispersion of an elastomer and the constituents necessary to form a phenol-formaldehyde resin to the cooled filamentary material and drying this coating; and (3) assembling the coated material with a composition containing rubber together with resin precursors and vulcanizing this composition in control with the coated material, usually under heat and pressure. The rubber composition may comprise natural rubber, styrene-butadiene copolymer, polybutadiene or cis-1,4-polyisoprene and the resin precursors may be an aromatic hydroxy compound and a methylene donor compound which react on heating to form a thermosetting aldehyde condensation resin. The filamentary material may be fibres of polyp-benzamide, poly(1,4-phenylene terephthalamide) or poly- (1,3-phenylene isophthalamide) and may be coated by dipping. The elastomer applied in step (2) may be a butadiene-styrene copolymer or a butadiene-styrene-vinyl pyridine terpolymer and the phenol-formaldehyde constituents may comprise an incompletely condensed resin or formaldehyde together with resorcinol, inaminophenol or 1,3- or 1,5-dihydroxynaphthalene.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2479773A GB1465063A (en) | 1973-05-24 | 1973-05-24 | Method of bonding an aromatic polyamide filamentary material to a rubber composition |
| ZA743201A ZA743201B (en) | 1973-05-24 | 1974-05-20 | A method of bonding aromatic polyamide filamentary materials to rubber compositions |
| CA200,449A CA1037220A (en) | 1973-05-24 | 1974-05-21 | Method of bonding aromatic polyamide filamentary materials to rubber compositions |
| BE144598A BE815366A (en) | 1973-05-24 | 1974-05-21 | PROCESS FOR WELDING A FILAMENTOUS AROMATIC POLYAMIDE MATERIAL TO A RUBBER COMPOSITION |
| LU70132A LU70132A1 (en) | 1973-05-24 | 1974-05-21 | |
| AU69229/74A AU483740B2 (en) | 1973-05-24 | 1974-05-22 | Method of bonding an aromatic polyamide filamentary material toa rubber composition |
| NL7406899A NL7406899A (en) | 1973-05-24 | 1974-05-22 | |
| DK282474A DK282474A (en) | 1973-05-24 | 1974-05-22 | |
| JP49058040A JPS5041984A (en) | 1973-05-24 | 1974-05-24 | |
| FR7418091A FR2230657B1 (en) | 1973-05-24 | 1974-05-24 | |
| DE19742425221 DE2425221A1 (en) | 1973-05-24 | 1974-05-24 | PROCESS FOR BINDING A THREAD MATERIAL COMPOSED OF AROMATIC POLYAMIDES TO A RUBBER MIXTURE |
| IT7423778A IT1059517B (en) | 1973-05-24 | 1974-06-10 | METHOD FOR COMBINING A MENTAL ROW MATERIAL OF AROMATIC POLYAMIDE WITH A RUBBER COMPOSITION |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2479773A GB1465063A (en) | 1973-05-24 | 1973-05-24 | Method of bonding an aromatic polyamide filamentary material to a rubber composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1465063A true GB1465063A (en) | 1977-02-23 |
Family
ID=10217379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2479773A Expired GB1465063A (en) | 1973-05-24 | 1973-05-24 | Method of bonding an aromatic polyamide filamentary material to a rubber composition |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5041984A (en) |
| BE (1) | BE815366A (en) |
| CA (1) | CA1037220A (en) |
| DE (1) | DE2425221A1 (en) |
| DK (1) | DK282474A (en) |
| FR (1) | FR2230657B1 (en) |
| GB (1) | GB1465063A (en) |
| IT (1) | IT1059517B (en) |
| LU (1) | LU70132A1 (en) |
| NL (1) | NL7406899A (en) |
| ZA (1) | ZA743201B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1083073A (en) * | 1975-03-20 | 1980-08-05 | Ian Biggs | Reinforcement for elastomeric articles |
| CA1172414A (en) * | 1981-02-10 | 1984-08-14 | Warren J. Bodendorf | High temperature gasketing material incorporating organic fibers |
| JPS585243A (en) * | 1981-07-02 | 1983-01-12 | Mitsuboshi Belting Ltd | Method of bonding aromatic polyamide fiber and rubber compound |
| FR2538808B1 (en) * | 1982-12-29 | 1986-09-05 | Commissariat Energie Atomique | POLYMERIZABLE COMPOSITION BASED ON EPOXIDE RESIN, ITS USE FOR THE TREATMENT OF POLYAMIDE FIBER CABLES AND TRANSMISSION BELT MADE FROM THE CABLE THUS PROCESSED |
| US6153359A (en) * | 1995-06-01 | 2000-11-28 | Hitachi Chemical Company, Ltd. | Process for producing multilayer printed circuit boards |
| CN102191691A (en) * | 2011-03-02 | 2011-09-21 | 骏马化纤股份有限公司 | Gum dipping liquid |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717542A (en) * | 1971-06-30 | 1973-02-20 | Monsanto Co | Flexible rubber articles reinforced with fiber of certain polyamide-hydrazide polymers |
-
1973
- 1973-05-24 GB GB2479773A patent/GB1465063A/en not_active Expired
-
1974
- 1974-05-20 ZA ZA743201A patent/ZA743201B/en unknown
- 1974-05-21 CA CA200,449A patent/CA1037220A/en not_active Expired
- 1974-05-21 BE BE144598A patent/BE815366A/en unknown
- 1974-05-21 LU LU70132A patent/LU70132A1/xx unknown
- 1974-05-22 DK DK282474A patent/DK282474A/da unknown
- 1974-05-22 NL NL7406899A patent/NL7406899A/xx unknown
- 1974-05-24 JP JP49058040A patent/JPS5041984A/ja active Pending
- 1974-05-24 DE DE19742425221 patent/DE2425221A1/en not_active Withdrawn
- 1974-05-24 FR FR7418091A patent/FR2230657B1/fr not_active Expired
- 1974-06-10 IT IT7423778A patent/IT1059517B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| NL7406899A (en) | 1974-11-26 |
| DK282474A (en) | 1975-01-20 |
| FR2230657B1 (en) | 1977-03-11 |
| AU6922974A (en) | 1975-11-27 |
| FR2230657A1 (en) | 1974-12-20 |
| DE2425221A1 (en) | 1974-12-12 |
| LU70132A1 (en) | 1974-10-09 |
| CA1037220A (en) | 1978-08-29 |
| ZA743201B (en) | 1975-05-28 |
| IT1059517B (en) | 1982-06-21 |
| JPS5041984A (en) | 1975-04-16 |
| BE815366A (en) | 1974-09-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |