GB1462601A - Oxazolidine and thiazolidine 'arbodithioates and their use as vulcanisation accelerators - Google Patents
Oxazolidine and thiazolidine 'arbodithioates and their use as vulcanisation acceleratorsInfo
- Publication number
- GB1462601A GB1462601A GB64175A GB64175A GB1462601A GB 1462601 A GB1462601 A GB 1462601A GB 64175 A GB64175 A GB 64175A GB 64175 A GB64175 A GB 64175A GB 1462601 A GB1462601 A GB 1462601A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pyridine
- oxazolidine
- thiazolidine
- amine
- alkylammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OGYGFUAIIOPWQD-UHFFFAOYSA-N 1,3-thiazolidine Chemical compound C1CSCN1 OGYGFUAIIOPWQD-UHFFFAOYSA-N 0.000 title abstract 2
- WYNCHZVNFNFDNH-UHFFFAOYSA-N Oxazolidine Chemical compound C1COCN1 WYNCHZVNFNFDNH-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004073 vulcanization Methods 0.000 title abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 2
- 101710178035 Chorismate synthase 2 Proteins 0.000 abstract 1
- 101710152694 Cysteine synthase 2 Proteins 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/04—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/04—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
- C08K5/47—Thiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
1462601 Heterocyclic carbodithioates PENNWALT CORP 7 Jan 1975 [1 Feb 1974] 641/75 Addition to 1418833 Heading C2C Novel compounds of formula where X is S or O, R, R<SP>1</SP>, R<SP>2</SP> and R<SP>3</SP> are H, C 1-8 alkyl, CCl 3 , phenyl or substituted phenyl wherein the substituents are selected from NR<SP>4</SP>R<SP>5</SP>, OR<SP>4</SP> and Cl where R<SP>4</SP> and R<SP>5</SP> are H or C 1-8 alkyl, M is Na, K, Cd, Cu, Fe, tri-C 1-8 - alkylammonium or phenyldi-C 1-8 -alkylammonium and y is 1-3 according to the valency of M, are prepared by reacting an appropriate oxazolidine or thiazolidine with CS 2 and a salt or oxide of the desired metal or an amine at 0-100‹ C., preferably in a solvent in the presence of a basic amine. Excess amine may also be used as solvent and the metal salts may be prepared using pyridine as solvents in which case pyridine adducts of the products are generally obtained. The pyridine may be removed from the adduct by heating. One salt may be converted to another. The above compounds are used as vulcanization accelerators in curing elastomers, reducing bloom.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/438,819 US3943143A (en) | 1973-04-30 | 1974-02-01 | Oxazolidine and thiazolidine derived carbodithioate compositions useful as vulcanization accelerators |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1462601A true GB1462601A (en) | 1977-01-26 |
Family
ID=23742148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB64175A Expired GB1462601A (en) | 1974-02-01 | 1975-01-07 | Oxazolidine and thiazolidine 'arbodithioates and their use as vulcanisation accelerators |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5832175B2 (en) |
| FR (1) | FR2259830B2 (en) |
| GB (1) | GB1462601A (en) |
| IT (1) | IT1046760B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5234273A (en) * | 1975-09-09 | 1977-03-16 | Akuto Bokujiyou Kk | Cylinder apparatus in feed forming device |
| US4099003A (en) * | 1976-06-11 | 1978-07-04 | Pennwalt Corporation | Non-blooming accelerator and process for vulcanization of epdm elastomers |
-
1975
- 1975-01-07 GB GB64175A patent/GB1462601A/en not_active Expired
- 1975-01-30 IT IT47933/75A patent/IT1046760B/en active
- 1975-01-30 FR FR7502931A patent/FR2259830B2/fr not_active Expired
- 1975-01-31 JP JP50012607A patent/JPS5832175B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT1046760B (en) | 1980-07-31 |
| FR2259830A2 (en) | 1975-08-29 |
| JPS50109240A (en) | 1975-08-28 |
| JPS5832175B2 (en) | 1983-07-11 |
| FR2259830B2 (en) | 1978-07-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |