GB1456031A - Process for the thermal conversion of metal chlorides to metal oxides - Google Patents
Process for the thermal conversion of metal chlorides to metal oxidesInfo
- Publication number
- GB1456031A GB1456031A GB5623673A GB5623673A GB1456031A GB 1456031 A GB1456031 A GB 1456031A GB 5623673 A GB5623673 A GB 5623673A GB 5623673 A GB5623673 A GB 5623673A GB 1456031 A GB1456031 A GB 1456031A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bed
- metal
- oxides
- chlorides
- dec
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910001510 metal chloride Inorganic materials 0.000 title abstract 4
- 229910044991 metal oxide Inorganic materials 0.000 title abstract 4
- 150000004706 metal oxides Chemical class 0.000 title abstract 4
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 239000007789 gas Substances 0.000 abstract 3
- 239000000446 fuel Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 235000021110 pickles Nutrition 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Compounds Of Iron (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Treating Waste Gases (AREA)
- Silicon Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
Abstract
1456031 Conversion of metal chlorides to metal oxides METALLGESELLSCHAFT AG 4 Dec 1973 [14 Dec 1972] 56236/73 Heading C1A Metal chlorides are converted to oxides by forming a bed of the metal oxide particles at least 350 mm. deep (when static) fluidized by introducing a free-O 2 -containing gas and fuel so that the velocity of all the gases traversing the bed is determined by the equation 0À34 #<SP>0À9</SP># W G #0À56 #<SP>0À9</SP> where W G is the velocity calculated on the cross-section of the chamber in the absence of the bed and # is the density of the metal oxide, the pressure drop across the bed being 1200-2400 mm. of water, the metal chloride being introduced at least 250 mm. above the grate, the bed temperature being between that at which the chloride reacts or the fuel ignites and that at which the oxides sinter, and withdrawing oxide granules below the entry point of the chlorides. The bed may be kept at a substantially constant level and at 800-1100‹ C. The feed may be a used pickle bath. When Fe 2 O 3 is the product W G may be 1À5-2À5 m/sec., the bed height 350-750 mm. and its temperature 800‹ C. The effluent gas may be passed through a cyclone to remove fine particles, which may be re-cycled to the bed, then through a venturi scrubber in contact with the feed liquor and finally through a washer to absorb HCl. NiO is also exemplified.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2261083A DE2261083C3 (en) | 1972-12-14 | 1972-12-14 | Process for the thermal cracking of metal chlorides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1456031A true GB1456031A (en) | 1976-11-17 |
Family
ID=5864351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5623673A Expired GB1456031A (en) | 1972-12-14 | 1973-12-04 | Process for the thermal conversion of metal chlorides to metal oxides |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5644004B2 (en) |
| BE (1) | BE808643A (en) |
| BR (1) | BR7309510D0 (en) |
| CA (1) | CA1008636A (en) |
| DE (1) | DE2261083C3 (en) |
| ES (1) | ES420737A1 (en) |
| FR (1) | FR2210439B1 (en) |
| GB (1) | GB1456031A (en) |
| IT (1) | IT1002220B (en) |
| SE (1) | SE402448B (en) |
| SU (1) | SU518120A3 (en) |
| ZA (1) | ZA737992B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2524541C2 (en) * | 1975-06-03 | 1986-08-21 | Aluminium Pechiney, Lyon | Process for the thermal cracking of aluminum chloride hydrate |
| US4086321A (en) * | 1976-06-21 | 1978-04-25 | Carl A. Holley | Producing pure iron oxides |
| DE2636855C2 (en) * | 1976-08-16 | 1986-08-21 | Aluminium Pechiney, Lyon | Process for the thermal cracking of aluminum chloride hydrate |
| DE2636854C2 (en) * | 1976-08-16 | 1986-08-21 | Aluminium Pechiney, Lyon | Process for the thermal cracking of aluminum chloride hydrate |
| DE2730646C3 (en) * | 1977-07-07 | 1982-04-01 | Metallgesellschaft Ag, 6000 Frankfurt | Process for the thermal cleavage of metal chlorides of bivalent or polyvalent metals |
| DE2805906C2 (en) * | 1978-02-13 | 1986-08-14 | Aluminium Pechiney, Lyon | Process for the thermal cracking of aluminum chloride hydrate |
| DE3900181A1 (en) * | 1989-01-05 | 1990-07-12 | Atzger Juergen | Method for the thermal processing of residual products of flue gas purification plants and fluidised-bed combustion plants, producing utilisable feedstocks |
| JPH0675205U (en) * | 1993-04-02 | 1994-10-25 | 五ツ星産業株式会社 | Athletic shoes |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB860301A (en) * | 1958-03-21 | 1961-02-01 | British Titan Products | Improvements in or relating to exothermic reactions |
| US3440009A (en) * | 1966-07-19 | 1969-04-22 | Little Inc A | Processing of spent hydrochloric acid pickle liquor |
-
1972
- 1972-12-14 DE DE2261083A patent/DE2261083C3/en not_active Expired
-
1973
- 1973-10-15 ZA ZA737992A patent/ZA737992B/en unknown
- 1973-11-21 ES ES420737A patent/ES420737A1/en not_active Expired
- 1973-11-23 FR FR7341766A patent/FR2210439B1/fr not_active Expired
- 1973-12-04 GB GB5623673A patent/GB1456031A/en not_active Expired
- 1973-12-04 BR BR9510/73A patent/BR7309510D0/en unknown
- 1973-12-10 CA CA187,760A patent/CA1008636A/en not_active Expired
- 1973-12-10 IT IT32065/73A patent/IT1002220B/en active
- 1973-12-12 JP JP13927473A patent/JPS5644004B2/ja not_active Expired
- 1973-12-12 SE SE7316810A patent/SE402448B/en unknown
- 1973-12-14 SU SU1978626A patent/SU518120A3/en active
- 1973-12-14 BE BE138871A patent/BE808643A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| SU518120A3 (en) | 1976-06-15 |
| BR7309510D0 (en) | 1974-08-29 |
| DE2261083A1 (en) | 1974-07-11 |
| JPS4996997A (en) | 1974-09-13 |
| BE808643A (en) | 1974-06-14 |
| FR2210439B1 (en) | 1978-03-10 |
| ZA737992B (en) | 1974-11-27 |
| DE2261083C3 (en) | 1979-05-31 |
| IT1002220B (en) | 1976-05-20 |
| AU6142573A (en) | 1975-04-17 |
| FR2210439A1 (en) | 1974-07-12 |
| DE2261083B2 (en) | 1978-10-05 |
| SE402448B (en) | 1978-07-03 |
| ES420737A1 (en) | 1976-04-01 |
| CA1008636A (en) | 1977-04-19 |
| JPS5644004B2 (en) | 1981-10-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19921204 |