GB1326628A - Stabilisation of polymeric materials - Google Patents
Stabilisation of polymeric materialsInfo
- Publication number
- GB1326628A GB1326628A GB4753570A GB4753570A GB1326628A GB 1326628 A GB1326628 A GB 1326628A GB 4753570 A GB4753570 A GB 4753570A GB 4753570 A GB4753570 A GB 4753570A GB 1326628 A GB1326628 A GB 1326628A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- textile
- multifunctional compound
- multifunctional
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 11
- 230000006641 stabilisation Effects 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 11
- 239000004753 textile Substances 0.000 abstract 6
- 239000003153 chemical reaction reagent Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- -1 2-hydroxylethyl Chemical class 0.000 abstract 2
- 239000000835 fiber Substances 0.000 abstract 2
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 abstract 2
- 238000011084 recovery Methods 0.000 abstract 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 abstract 1
- IOCXBXZBNOYTLQ-UHFFFAOYSA-N 3-nitrobenzene-1,2-diamine Chemical compound NC1=CC=CC([N+]([O-])=O)=C1N IOCXBXZBNOYTLQ-UHFFFAOYSA-N 0.000 abstract 1
- 101100188555 Arabidopsis thaliana OCT6 gene Proteins 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 abstract 1
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 238000000137 annealing Methods 0.000 abstract 1
- 125000004069 aziridinyl group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 abstract 1
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 abstract 1
- 125000001810 isothiocyanato group Chemical group *N=C=S 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical group O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 230000008520 organization Effects 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 abstract 1
- 229960001553 phloroglucinol Drugs 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 229940079877 pyrogallol Drugs 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 230000008707 rearrangement Effects 0.000 abstract 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/487—Aziridinylphosphines; Aziridinylphosphine-oxides or sulfides; Carbonylaziridinyl or carbonylbisaziridinyl compounds; Sulfonylaziridinyl or sulfonylbisaziridinyl compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
1326628 Stabilisation of textile fibres COMMONWEALTH SCIENTIFIC & INDUSTRIAL RESEARCH ORGANIZATION 6 Oct 1970 [7 Oct 1969] 47535/70 Heading D1P A method, for treating a textile material to improve its resistance to and recovery from deformation comprises heating the material in an atmosphere in which the relative humidity is between 50 and 95%, preferably 65 to 90%, at a temperature of from 30‹C to 150‹C, preferably 40 to 150‹C for a period of from 5 minutes to 2 weeks, preferably 5 minutes to 3 days, thereby to improve the resistance to and recovery from wrinkling of the material; and treating the material with at least one multifunctional compound which is capable of undergoing a reaction with the material under conditions which do not deanneal the material. Preferably the temperature is from 100 to 120‹C. and the heating period is from 10 minutes to 4 hours. The term multifunctional compound refers to compounds small enough to deffuse into the fibre, which possess at least two reactive sites or groups and is capable of undergoing reaction with itself, with another such compound and directly or indirectly with the substance of the textile fibre giving new chemical linkages. The multifunctional compound may be applied to the textile material before, during or after exposure of the textile material to the annealing conditions is the elevated temperature and the increased relative humidity. Furthermore two or more multifunctional compounds or two or more reactants which together give rise to a multifunctional compound may be applied. It is possible to apply one multifunctional compound at one stage of the procedure and another compound at a subsequent stage, forming a three dimensionally cross-linked polymeric structure involving reactive sites in the textile fibres. The multifunctional compound contains at least two reactive groups selected from formyl (aldehydo), epoxy, aziridinyl, O- and N-methylol or alkylmethyl activated C-methylol, isocyanato and isothiocyanato, displaceable halogen, vinyl and activated 2-hydroxylethyl and O-derivatives thereof, sites capable of generating free radicals on irradiation, hydroxyl, amino, carbamyl, carboxyl, aliphatic and heterocyclic imino, imido and mercapto. Preferably the first reagent is a compound selected from melamine and its hydroxymethyl derivatives (particularly monomethylolmelamine), resorcinol, pyrogallol, #- resorcyl aldehyde, phloroglucinol, n-phenylenediamine and p-phenylenediamine. The second reagent is formaldehyde, either in its gaseous form or as paraformaldehyde. Preferably 1 to 10% of both reagents are used (based on the weight of the material). Materials treated by the method are cotton, wool, silk, nylon and all polymer materials which can undergo molecular rearrangement.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU6193969 | 1969-10-07 | ||
| AU20762/70A AU446115B2 (en) | 1969-10-07 | 1970-10-06 | Improvements in and relating tothe stabilisation of polymeric materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1326628A true GB1326628A (en) | 1973-08-15 |
Family
ID=25618000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4753570A Expired GB1326628A (en) | 1969-10-07 | 1970-10-06 | Stabilisation of polymeric materials |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU446115B2 (en) |
| DE (1) | DE2048931A1 (en) |
| GB (1) | GB1326628A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0787228A4 (en) * | 1994-10-17 | 1998-09-02 | Commw Scient Ind Res Org | Chemically assisted protein annealing treatment |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4329218A1 (en) * | 1993-08-31 | 1995-03-02 | Beiersdorf Ag | Continuous impregnation process |
-
1970
- 1970-10-06 AU AU20762/70A patent/AU446115B2/en not_active Expired
- 1970-10-06 DE DE19702048931 patent/DE2048931A1/en active Pending
- 1970-10-06 GB GB4753570A patent/GB1326628A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0787228A4 (en) * | 1994-10-17 | 1998-09-02 | Commw Scient Ind Res Org | Chemically assisted protein annealing treatment |
| US5928383A (en) * | 1994-10-17 | 1999-07-27 | The Commonwealth Scientific And Industrial Research Organization | Chemically assisted protein annealing treatment |
| KR100397770B1 (en) * | 1994-10-17 | 2003-11-20 | 컴먼웰스 사이언티픽 앤드 인더스트리알 리써치 오가니제이션 | Chemically assisted protein annealing treatment |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2076270A (en) | 1972-04-13 |
| AU446115B2 (en) | 1974-02-26 |
| DE2048931A1 (en) | 1971-05-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |