GB1326428A - Process for the oxychlorination of ethylenic hydrocarbons - Google Patents
Process for the oxychlorination of ethylenic hydrocarbonsInfo
- Publication number
- GB1326428A GB1326428A GB4834670A GB4834670A GB1326428A GB 1326428 A GB1326428 A GB 1326428A GB 4834670 A GB4834670 A GB 4834670A GB 4834670 A GB4834670 A GB 4834670A GB 1326428 A GB1326428 A GB 1326428A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- rare earth
- yttrium
- alumina
- earth metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 4
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 5
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 5
- 150000002910 rare earth metals Chemical class 0.000 abstract 5
- 229910052727 yttrium Inorganic materials 0.000 abstract 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract 5
- 239000004005 microsphere Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000005749 Copper compound Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003570 air Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 150000001880 copper compounds Chemical class 0.000 abstract 1
- 229960003750 ethyl chloride Drugs 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 150000002909 rare earth metal compounds Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1326428 Oxychlorination process PRODUITS CHIMIQUES PECHINEY-SAINT-GOBAIN 12 Oct 1970 [13 Oct 1969] 48346/70 Heading C2C [Also in Division B1] An ethylenic hydrocarbon is selectively oxychlorinated by a process wherein the hydrocarbon is contacted, under oxychlorination reaction conditions including a temperature not exceeding 250‹ C., with a catalyst comprising (a) alumina, (b) at least one copper compound and (c) at least one yttrium and/or rare earth metal compound (rare earth metals being defined as elements having atomic numbers of from 5 7 to 71), the catalyst being further characterized in that (i) it contains no extraneously added alkali metal, (ii) yttrium and rare earth metal constitute (on an elemental basis) from 1 to 10 weight per cent of the catalyst and (iii) at least 90 weight per cent of the yttrium and rare earth metal content of the catalyst is constituted by yttrium and/or rare earth metal(s) having an atomic number of at least 62. Copper preferably constitutes (on an elemental basis) at least 5 weight per cent of the catalyst which may be prepared by a conventional procedure involving for example impregnation of alumina which preferably has a surface area of from 150 to 380 m<SP>2</SP>./g. and which may be in the form of microspheres obtained by calcining spray-dried alumina. The selective oxychlorination of ethylene to 1,2-dichloroethane (and by-product ethyl chloride) by contacting a gaseous mixture of ethylene, air and hydrogen chloride, at atmospheric pressure and a temperature of either 220‹ C. or 235‹ C., with a fluidized bed of catalyst is exemplified using various catalysts prepared from the chlorides of copper and of yttrium and/or rare earth metal(s), either singly or in admixture, the alumina being in the form of microspheres having an average diameter of 60 microns, a surface area of 340 m<SP>2</SP>./g. and a pore volume of 0À4 cm<SP>3</SP>./g. A comparative example relates to such oxychlorination using catalyst wherein the alumina is replaced by silica in the form of microspheres having an average diameter of 70 microns, a surface area of 350 m<SP>2</SP>./g. and a pore volume of 0À6 cm<SP>3</SP>./g.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6934962A FR2063365A5 (en) | 1969-10-13 | 1969-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1326428A true GB1326428A (en) | 1973-08-15 |
Family
ID=9041443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4834670A Expired GB1326428A (en) | 1969-10-13 | 1970-10-12 | Process for the oxychlorination of ethylenic hydrocarbons |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE757380A (en) |
| CA (1) | CA989422A (en) |
| DE (1) | DE2050061C3 (en) |
| ES (1) | ES384402A1 (en) |
| FR (1) | FR2063365A5 (en) |
| GB (1) | GB1326428A (en) |
| NL (1) | NL169831C (en) |
| SU (1) | SU488381A3 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5116799A (en) * | 1988-12-26 | 1992-05-26 | Atochem | Oxychlorination of hydrocarbons |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2121854B1 (en) * | 1971-01-16 | 1976-06-11 | Basf Ag | |
| EP0191995A1 (en) * | 1985-01-22 | 1986-08-27 | Chem Systems Inc. | Hydrogenation catalysts and their use |
-
0
- BE BE757380D patent/BE757380A/en not_active IP Right Cessation
-
1969
- 1969-10-13 FR FR6934962A patent/FR2063365A5/fr not_active Expired
-
1970
- 1970-09-15 SU SU1478193A patent/SU488381A3/en active
- 1970-10-05 NL NL7014569A patent/NL169831C/en not_active IP Right Cessation
- 1970-10-09 CA CA095,267A patent/CA989422A/en not_active Expired
- 1970-10-10 ES ES384402A patent/ES384402A1/en not_active Expired
- 1970-10-12 DE DE19702050061 patent/DE2050061C3/en not_active Expired
- 1970-10-12 GB GB4834670A patent/GB1326428A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5116799A (en) * | 1988-12-26 | 1992-05-26 | Atochem | Oxychlorination of hydrocarbons |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7014569A (en) | 1971-04-15 |
| ES384402A1 (en) | 1973-03-01 |
| SU488381A3 (en) | 1975-10-15 |
| CA989422A (en) | 1976-05-18 |
| DE2050061B2 (en) | 1977-12-29 |
| NL169831B (en) | 1982-04-01 |
| DE2050061C3 (en) | 1978-12-07 |
| NL169831C (en) | 1982-09-01 |
| DE2050061A1 (en) | 1971-04-15 |
| FR2063365A5 (en) | 1971-07-09 |
| BE757380A (en) | 1971-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PE20 | Patent expired after termination of 20 years |