GB1324806A - Salts of 1/2 metal complex dyes containing sulphonic acid groups - Google Patents
Salts of 1/2 metal complex dyes containing sulphonic acid groupsInfo
- Publication number
- GB1324806A GB1324806A GB5604370A GB5604370A GB1324806A GB 1324806 A GB1324806 A GB 1324806A GB 5604370 A GB5604370 A GB 5604370A GB 5604370 A GB5604370 A GB 5604370A GB 1324806 A GB1324806 A GB 1324806A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dyes
- salts
- metal complex
- azo
- azomethine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003839 salts Chemical class 0.000 title abstract 5
- 239000000434 metal complex dye Substances 0.000 title abstract 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000975 dye Substances 0.000 abstract 5
- 239000000981 basic dye Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 2
- 239000000976 ink Substances 0.000 abstract 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 abstract 1
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000004982 aromatic amines Chemical class 0.000 abstract 1
- 239000000987 azo dye Substances 0.000 abstract 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000001003 triarylmethane dye Substances 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
- 239000001018 xanthene dye Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B55/00—Azomethine dyes
- C09B55/001—Azomethine dyes forming a 1,2 complex metal compound, e.g. with Co or Cr, with an other dye, e.g. with an azo or azomethine dye
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/48—Preparation from other complex metal compounds of azo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
- C09B69/04—Dyestuff salts, e.g. salts of acid dyes with basic dyes of anionic dyes with nitrogen containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
Abstract
1324806 Salts of 1 : 2 metal complex dyes BADISCHE ANILIN- & SODA-FABRIK AG 25 Nov 1970 [26 Nov 1969] 56043/70 Heading C4P The invention comprises salts of 1 : 2 metal complex dyes of azo or azomethine dyes containing at least one sulphonic acid group with at least a molar amount in each case of a basic dye and an aliphatic amine. Suitable metallizable azo dyes are o-o<SP>1</SP>-dihydroxy-, o-carboxy o<SP>1</SP>- hydroxy and o-hydroxy-o<SP>1</SP>-amino monoazo dyes and compounds bearing a hydroxy group ortho to the azomethine bond are suitable as azomethine dyes from aromatic amines and aldehydes. Iron, cobalt and particularly chromium complexes are preferred. Basic dyes which may be used are azo, oxazine, azine, thiazine, methine and preferably triarylmethane or xanthene dyes. The aliphatic amine used may be primary, secondary or tertiary and have 4-18 carbon atoms and may be linear, cyclic or a branched chain. Mixtures of amines can also be used. The dye salts may be prepared by reacting the metal complex dyes with the basic dyes and amine in an alcoholic or glycolic solvent. The dye salts are suitable for colouring transparent plastics and for the production of transparent varnishes, printing inks and ball point pen inks.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691959306 DE1959306C3 (en) | 1969-11-26 | Salts of 1 to 2 metal complex dyes containing sulfonic acid groups and their use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1324806A true GB1324806A (en) | 1973-07-25 |
Family
ID=5752109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5604370A Expired GB1324806A (en) | 1969-11-26 | 1970-11-25 | Salts of 1/2 metal complex dyes containing sulphonic acid groups |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5126930B1 (en) |
| BE (1) | BE759421A (en) |
| CH (1) | CH553245A (en) |
| FR (1) | FR2068657B1 (en) |
| GB (1) | GB1324806A (en) |
| NL (1) | NL7017247A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4204879A (en) * | 1976-12-09 | 1980-05-27 | Williams (Hounslow) Limited | Amino acid salts of anionic dyestuffs which have high solubility in organic solvents |
| EP0019128A1 (en) * | 1979-05-09 | 1980-11-26 | Bayer Ag | Cobalt complex dyestuffs, processes for their preparation and their use in dyeing and printing |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE890251C (en) * | 1939-10-10 | 1953-09-17 | Basf Ag | Process for the preparation of metal-containing azomethine dyes |
| CH234943A (en) * | 1941-01-22 | 1944-10-31 | Ag J R Geigy | Process for the preparation of a fuel-soluble dye. |
| FR1227024A (en) * | 1958-06-12 | 1960-08-18 | Geigy Ag J R | Process for the preparation of acetone-soluble transformation products derived from azo dyes containing a complexed heavy metal |
| FR1297014A (en) * | 1960-08-09 | 1962-06-22 | Basf Ag | Ammonium salts of metal complex dyes |
| NL129233C (en) * | 1965-01-15 |
-
0
- BE BE759421D patent/BE759421A/en unknown
-
1970
- 1970-11-20 CH CH1724670A patent/CH553245A/en not_active IP Right Cessation
- 1970-11-25 GB GB5604370A patent/GB1324806A/en not_active Expired
- 1970-11-25 FR FR7042331A patent/FR2068657B1/fr not_active Expired
- 1970-11-25 NL NL7017247A patent/NL7017247A/xx unknown
- 1970-11-26 JP JP45103743A patent/JPS5126930B1/ja active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4204879A (en) * | 1976-12-09 | 1980-05-27 | Williams (Hounslow) Limited | Amino acid salts of anionic dyestuffs which have high solubility in organic solvents |
| EP0019128A1 (en) * | 1979-05-09 | 1980-11-26 | Bayer Ag | Cobalt complex dyestuffs, processes for their preparation and their use in dyeing and printing |
Also Published As
| Publication number | Publication date |
|---|---|
| CH553245A (en) | 1974-08-30 |
| BE759421A (en) | 1971-05-25 |
| DE1959306B2 (en) | 1977-03-10 |
| DE1959306A1 (en) | 1971-06-03 |
| JPS5126930B1 (en) | 1976-08-10 |
| NL7017247A (en) | 1971-05-28 |
| FR2068657A1 (en) | 1971-08-27 |
| FR2068657B1 (en) | 1975-06-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |