GB1323931A - Desulphurization of flue gas - Google Patents
Desulphurization of flue gasInfo
- Publication number
- GB1323931A GB1323931A GB3693170A GB3693170A GB1323931A GB 1323931 A GB1323931 A GB 1323931A GB 3693170 A GB3693170 A GB 3693170A GB 3693170 A GB3693170 A GB 3693170A GB 1323931 A GB1323931 A GB 1323931A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formate
- flue gas
- thiosulphate
- converted
- sulphur dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title abstract 5
- 239000003546 flue gas Substances 0.000 title abstract 5
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract 7
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 3
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 3
- 239000004291 sulphur dioxide Substances 0.000 abstract 3
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 abstract 3
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 abstract 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 abstract 2
- -1 85%) Chemical compound 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 238000007596 consolidation process Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
1323931 Desulphurizing flue gas; thiosulphates CONSOLIDATION COAL CO 30 July 1970 [24 Nov 1969] 36931/70 Addition to 1191427 Heading C1A Hot flue gas containing sulphur dioxide is contacted with ammonium, sodium or potassium formate in solution or in the molten form at a temperature above 140‹ F. and below the decomposition temperature of the formate producing the corresponding thiosulphates and reducing the sulphur dioxide content of the hot flue gas. The temperature may be below 475 degrees. The formate may be in aqueous solution and the corresponding carbonate may also be present. The product thiosulphate may be isolated as such, or used to regenerate formate for recycle to treat further flue gas. In an embodiment of the latter process gas containing sulphur dioxide is contacted with excess potassium formate (e.g. 85%), whereby less than 25% by wt. of formate is converted to thiosulphate, in a scrubber 10. The resulting thiosulphate is then converted to the corresponding carbonate with the excess formate in redactor vessel 20; the products from which are then stripped of H 2 S by means of CO 2 and steam in 26, and carbonate present is converted to formate in 34, the regenerated formate being returned to the scrubber 10.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US87922369A | 1969-11-24 | 1969-11-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1323931A true GB1323931A (en) | 1973-07-18 |
Family
ID=25373679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3693170A Expired GB1323931A (en) | 1969-11-24 | 1970-07-30 | Desulphurization of flue gas |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE2055848A1 (en) |
| GB (1) | GB1323931A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE31236E (en) | 1973-02-10 | 1983-05-10 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method of removing sulfur dioxide from combustion exhaust gas |
-
1970
- 1970-07-30 GB GB3693170A patent/GB1323931A/en not_active Expired
- 1970-11-13 DE DE19702055848 patent/DE2055848A1/de active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE31236E (en) | 1973-02-10 | 1983-05-10 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method of removing sulfur dioxide from combustion exhaust gas |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2055848A1 (en) | 1971-06-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |