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GB1318781A - Polymeric quaternary ammonium compounds - Google Patents

Polymeric quaternary ammonium compounds

Info

Publication number
GB1318781A
GB1318781A GB1318781DA GB1318781A GB 1318781 A GB1318781 A GB 1318781A GB 1318781D A GB1318781D A GB 1318781DA GB 1318781 A GB1318781 A GB 1318781A
Authority
GB
United Kingdom
Prior art keywords
quaternised
per cent
antistatic
hal
quaternary ammonium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of GB1318781A publication Critical patent/GB1318781A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

1318781 Rendering textiles antistatic IMPERIAL CHEMICAL INDUSTRIES Ltd 19 April 1971 [17 March 1970] 12699/70 Heading DIP [Also in Division C3] Textile materials such as fibres, filaments and woven fabrics made of synthetic polymeric materials are rendered antistatic by treating with polymeric quaternary ammonium compounds comprising a polymer, or copolymer with up to 80 mole per cent of a non-nitrogenous unsaturated compound, of a t. aminoalkyl acrylate or methacrylate, at least 90 per cent of the t. amino groups of which are quaternised and at least 1 per cent of the quaternised groups having the formula: -N<SP>+</SP>R 1 R 2 R 3 X<SP>-</SP> any remainder having the formula -N<SP>+</SP>R 2 R 3 R 4 X<SP>-</SP> where R 1 is -CH 2 CH(OH)CH 2 hal or HOCH 2 CHCH 2 hal and R 2 , R 3 and R 4 are C 1-3 alkyl or R 2 and R 3 form with the nitrogen atom a heterocyclic system containing not more than 6 carbon atoms, and X is an inorganic anion. The synthetic polymeric material may be polyhexamethylene adipamide, polycaprolactam, polyethylene terephthalate or an acrylonitrile polymer, and the articles may be impregnated, dipped, brushed or sprayed with an aqueous solution of the compound and heated to at least 120‹C, or to at least 60‹C in the presence of an acidfixing substance, e.g. sodium carbonate, bicarbonate, hydroxide or borate. Examples describe making polyamide woven fabrics antistatic by impregnating with aqueous solutions of dimethylaminoethyl methacrylate/styrene copolymers quaternised with methyl chloride and epichlorohydrin in the presence of hydrogen chloride, the solution optionally containing (3) sodium bicarbonate, and heating.
GB1318781D 1970-03-17 1970-03-17 Polymeric quaternary ammonium compounds Expired GB1318781A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1269970 1970-03-17

Publications (1)

Publication Number Publication Date
GB1318781A true GB1318781A (en) 1973-05-31

Family

ID=10009482

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1318781D Expired GB1318781A (en) 1970-03-17 1970-03-17 Polymeric quaternary ammonium compounds

Country Status (1)

Country Link
GB (1) GB1318781A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0041651A1 (en) * 1980-05-30 1981-12-16 Hercules Incorporated Process for producing wet strength agents for paper
FR2827314A1 (en) * 2001-07-13 2003-01-17 Protex Formaldehyde-free additive for textile treatment compositions, especially for improving crease resistance, comprises an emulsion polymer based on cationic monomer and alkyl (meth)acrylate comonomer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0041651A1 (en) * 1980-05-30 1981-12-16 Hercules Incorporated Process for producing wet strength agents for paper
FR2827314A1 (en) * 2001-07-13 2003-01-17 Protex Formaldehyde-free additive for textile treatment compositions, especially for improving crease resistance, comprises an emulsion polymer based on cationic monomer and alkyl (meth)acrylate comonomer

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees