GB1310054A - Method for the manufacture of soluble organic copolymers and their use in reaction lacquers - Google Patents
Method for the manufacture of soluble organic copolymers and their use in reaction lacquersInfo
- Publication number
- GB1310054A GB1310054A GB2346770A GB2346770A GB1310054A GB 1310054 A GB1310054 A GB 1310054A GB 2346770 A GB2346770 A GB 2346770A GB 2346770 A GB2346770 A GB 2346770A GB 1310054 A GB1310054 A GB 1310054A
- Authority
- GB
- United Kingdom
- Prior art keywords
- styrene
- groups
- esterified
- component
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004922 lacquer Substances 0.000 title abstract 3
- 229920001577 copolymer Polymers 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- 229920000642 polymer Polymers 0.000 abstract 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- -1 alkyl styrenes Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 150000007974 melamines Chemical class 0.000 abstract 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
- C08G18/6258—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids the acid groups being esterified with polyhydroxy compounds or epoxy compounds during or after polymerization
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1310054 Esterified polymers containing hydroxyl groups REICHHOLD-ALBERTCHEMIE AG 14 May 1970 [27 May 1969] 23467/70 Heading C3P Hydroxyl group-containing polymers are produced by heating in an inert organic solvent with or without initiatiors or chain terminating agents, the following components: (a) 38-70% by wt. of styrene or one or more C 1-3 alkyl styrenes, (b) 3-15% by wt. of one or more α,#- ethylenically unsaturated mono- or di-carboxylic acids and (c) 10-40% by wt. of the glycidyl ester of an α-alkyl alkane monocarboxylic acid and/or α,α-dialkylalkane monocarboxylic acid of the empirical formula the carboxyl groups of (b) having been esterified by (c) under equivalency conditions, and wherein (a), (b) and (c) total 100% by wt. Component (a) is preferably styrene or vinyl toluene, and component (b) is preferably acrylic or methacrylic acid. The polymer preferably has a molecular weight of 5000 to 20,000 and an OH group content of 0À7-3À0% by weight. The polymer may be made into a lacquer by dissolving in a solvent without active hydrogen atoms and mixing with an organic polyisocyanate. The lacquers may be coated on to substrates which are then heated to produce crosslinking of OH groups by -NCO groups. A melamine derivative may also be present. In the examples the monomers used are styrene and acrylic acid. Solvents used are xylene and ethylene glycol monoacetate monoethyl ether.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH798569A CH525255A (en) | 1969-05-27 | 1969-05-27 | Process for the production of soluble organic copolymers and their use as a binder component |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1310054A true GB1310054A (en) | 1973-03-14 |
Family
ID=4333384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2346770A Expired GB1310054A (en) | 1969-05-27 | 1970-05-14 | Method for the manufacture of soluble organic copolymers and their use in reaction lacquers |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS4920948B1 (en) |
| AT (1) | AT298808B (en) |
| AU (1) | AU1511970A (en) |
| BE (1) | BE749949A (en) |
| BR (1) | BR7018870D0 (en) |
| CH (1) | CH525255A (en) |
| DE (1) | DE2021141A1 (en) |
| ES (1) | ES379360A1 (en) |
| FR (1) | FR2047349A5 (en) |
| GB (1) | GB1310054A (en) |
| NL (1) | NL162092C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS523268U (en) * | 1975-06-24 | 1977-01-11 | ||
| JPS56172614U (en) * | 1980-05-22 | 1981-12-19 | ||
| DE59105478D1 (en) * | 1990-01-20 | 1995-06-22 | Synthopol Chemie Dr Koch | Copolymer solutions based on addition products of alpha, beta-unsaturated carboxylic acid with glycidyl esters and thus copolymerizable alpha, beta-unsaturated monomers. |
-
1969
- 1969-05-27 CH CH798569A patent/CH525255A/en not_active IP Right Cessation
-
1970
- 1970-04-30 DE DE19702021141 patent/DE2021141A1/en active Pending
- 1970-05-01 JP JP45036903A patent/JPS4920948B1/ja active Pending
- 1970-05-05 BE BE749949D patent/BE749949A/en unknown
- 1970-05-06 ES ES379360A patent/ES379360A1/en not_active Expired
- 1970-05-06 AT AT413870A patent/AT298808B/en not_active IP Right Cessation
- 1970-05-06 FR FR7016460A patent/FR2047349A5/fr not_active Expired
- 1970-05-07 BR BR21887070A patent/BR7018870D0/en unknown
- 1970-05-08 NL NL7006734A patent/NL162092C/en not_active IP Right Cessation
- 1970-05-14 GB GB2346770A patent/GB1310054A/en not_active Expired
- 1970-05-15 AU AU15119/70A patent/AU1511970A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2021141A1 (en) | 1970-12-03 |
| NL7006734A (en) | 1970-12-01 |
| AT298808B (en) | 1972-05-25 |
| NL162092C (en) | 1980-04-15 |
| CH525255A (en) | 1972-07-15 |
| BE749949A (en) | 1970-10-16 |
| ES379360A1 (en) | 1973-04-16 |
| FR2047349A5 (en) | 1971-03-12 |
| NL162092B (en) | 1979-11-15 |
| BR7018870D0 (en) | 1973-04-17 |
| JPS4920948B1 (en) | 1974-05-28 |
| AU1511970A (en) | 1971-11-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |