GB1306863A - Production of acetic acid - Google Patents
Production of acetic acidInfo
- Publication number
- GB1306863A GB1306863A GB3722770A GB3722770A GB1306863A GB 1306863 A GB1306863 A GB 1306863A GB 3722770 A GB3722770 A GB 3722770A GB 3722770 A GB3722770 A GB 3722770A GB 1306863 A GB1306863 A GB 1306863A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetic acid
- methanol
- carbon monoxide
- catalyst
- gaseous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 15
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000008246 gaseous mixture Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000003610 charcoal Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000003345 natural gas Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000003209 petroleum derivative Substances 0.000 abstract 1
- 238000002407 reforming Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1306863 Acetic acid AJINOMOTO CO Inc 31 July 1970 [14 Aug 1969] 37227/70 Heading C2C A process for the production of acetic acid comprises the following steps (a) reacting a gaseous mixture of carbon monoxide and hydrogen in a molar ratio of 1 to not less than 0À5, with methanol in the gas phase in the presence of a transition metal catalyst and a halogencontaining compound co-catalyst until no more than half of the carbon monoxide is consumed; (b) cooling the reacted gas obtained in step (a), separating the cooled gas into a liquid component containing acetic acid and a gaseous component containing unreacted carbon monoxide and hydrogen and withdrawing the acetic acid from the reaction system, (c) washing the gaseous component from step (b) with cold methanol and (d) reacting the washed gaseous component from step (c) in the presence of a coppercontaining catalyst to yield methanol and passing this methanol to step (a). Preferred processes are described referring to Figs. 1-3 (not shown). In an example the catalysts employed are metallic rhodium supported on active charcoal and metallic copper, zinc and chromium in admixture supported on graphite. The starting material gaseous mixture may be produced by the partial oxidation of coke, petroleum or natural gas or by reforming hydrocarbons in the presence of carbon dioxide and steam.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP44063861A JPS4837244B1 (en) | 1969-08-14 | 1969-08-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1306863A true GB1306863A (en) | 1973-02-14 |
Family
ID=13241519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3722770A Expired GB1306863A (en) | 1969-08-14 | 1970-07-31 | Production of acetic acid |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS4837244B1 (en) |
| FR (1) | FR2058060A5 (en) |
| GB (1) | GB1306863A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0133331A1 (en) * | 1983-07-26 | 1985-02-20 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of acetic acid and/or methyl acetate |
| RU2193551C2 (en) * | 1996-04-10 | 2002-11-27 | Хальдор Топсеэ А/С | Method of synthesis of acetic acid |
| RU2196128C2 (en) * | 1996-11-29 | 2003-01-10 | Хальдор Топсеэ А/С | Method of synthesis of acetic acid |
| WO2014096254A1 (en) * | 2012-12-21 | 2014-06-26 | Bp Chemicals Limited | Integrated process for making acetic acid |
| WO2014096237A1 (en) * | 2012-12-21 | 2014-06-26 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| WO2014096249A1 (en) * | 2012-12-21 | 2014-06-26 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| US20150329465A1 (en) * | 2012-12-21 | 2015-11-19 | Bp Chemicals Limited | Integrated process for the production of methyl acetate and methanol from synthesis gas and dimethylether |
| CN114192085A (en) * | 2021-12-15 | 2022-03-18 | 珠海谦信新材料有限公司 | Heat recycling system and method for acetic acid process production device |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51141657U (en) * | 1975-05-08 | 1976-11-15 | ||
| JPS5388311U (en) * | 1976-12-17 | 1978-07-20 | ||
| CN1295551A (en) | 1998-03-31 | 2001-05-16 | 哈尔多·托普森公司 | Process for production of acetic acid |
| US6160163A (en) * | 1999-02-16 | 2000-12-12 | Eastman Chemical Company | Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter |
| FR3076831B1 (en) * | 2018-01-17 | 2020-12-25 | Commissariat Energie Atomique | CARBON MONOXIDE PRODUCTION PROCESS |
-
1969
- 1969-08-14 JP JP44063861A patent/JPS4837244B1/ja active Pending
-
1970
- 1970-07-31 GB GB3722770A patent/GB1306863A/en not_active Expired
- 1970-08-13 FR FR7029900A patent/FR2058060A5/fr not_active Expired
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0133331A1 (en) * | 1983-07-26 | 1985-02-20 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of acetic acid and/or methyl acetate |
| RU2193551C2 (en) * | 1996-04-10 | 2002-11-27 | Хальдор Топсеэ А/С | Method of synthesis of acetic acid |
| RU2196128C2 (en) * | 1996-11-29 | 2003-01-10 | Хальдор Топсеэ А/С | Method of synthesis of acetic acid |
| EP0845452B2 (en) † | 1996-11-29 | 2011-09-14 | Haldor Topsoe A/S | HOAC process III |
| WO2014096254A1 (en) * | 2012-12-21 | 2014-06-26 | Bp Chemicals Limited | Integrated process for making acetic acid |
| WO2014096237A1 (en) * | 2012-12-21 | 2014-06-26 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| WO2014096249A1 (en) * | 2012-12-21 | 2014-06-26 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| CN104995160A (en) * | 2012-12-21 | 2015-10-21 | 英国石油化学品有限公司 | Integrated process for the production of methanol and methyl acetate |
| US20150329450A1 (en) * | 2012-12-21 | 2015-11-19 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| US20150329465A1 (en) * | 2012-12-21 | 2015-11-19 | Bp Chemicals Limited | Integrated process for the production of methyl acetate and methanol from synthesis gas and dimethylether |
| US20150329466A1 (en) * | 2012-12-21 | 2015-11-19 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| JP2016500378A (en) * | 2012-12-21 | 2016-01-12 | ビーピー ケミカルズ リミテッドＢｐ Ｃｈｅｍｉｃａｌｓ Ｌｉｍｉｔｅｄ | An integrated method for producing methyl acetate and methanol from synthesis gas and dimethyl ether |
| US9242920B2 (en) | 2012-12-21 | 2016-01-26 | Bp Chemicals Limited | Integrated process for making acetic acid |
| US9469591B2 (en) | 2012-12-21 | 2016-10-18 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| US9505702B2 (en) * | 2012-12-21 | 2016-11-29 | Bp Chemicals Limited | Integrated process for the production of methyl acetate and methanol from synthesis gas and dimethylether |
| US9546120B2 (en) | 2012-12-21 | 2017-01-17 | Bp Chemicals Limited | Integrated process for the production of methanol and methyl acetate |
| CN104995167B (en) * | 2012-12-21 | 2017-05-17 | 英国石油化学品有限公司 | Integrated process for the production of methyl acetate and methanol from synthesis gas and dimethylether |
| CN104995159B (en) * | 2012-12-21 | 2017-12-05 | 英国石油化学品有限公司 | Integrated process for the production of methanol and methyl acetate |
| RU2638922C2 (en) * | 2012-12-21 | 2017-12-19 | Бп Кемикэлз Лимитед | Joint method of producing acetic acid |
| RU2686701C2 (en) * | 2012-12-21 | 2019-04-30 | Бп Кемикэлз Лимитед | Combined method of producing methanol and methyl lanette |
| RU2686734C2 (en) * | 2012-12-21 | 2019-04-30 | Бп Кемикэлз Лимитед | Combined method of producing methyl acetate and methanol from syntheses gas and dimethyl ether |
| RU2687234C2 (en) * | 2012-12-21 | 2019-05-08 | Бп Кемикэлз Лимитед | Combined method of producing methyl acetate and methanol from syntheses gas and dimethyl ether |
| CN104995160B (en) * | 2012-12-21 | 2020-03-20 | 英国石油化学品有限公司 | Integrated process for the production of methanol and methyl acetate |
| CN114192085A (en) * | 2021-12-15 | 2022-03-18 | 珠海谦信新材料有限公司 | Heat recycling system and method for acetic acid process production device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4837244B1 (en) | 1973-11-09 |
| FR2058060A5 (en) | 1971-05-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |