GB1304556A - - Google Patents
Info
- Publication number
- GB1304556A GB1304556A GB5613170A GB5613170A GB1304556A GB 1304556 A GB1304556 A GB 1304556A GB 5613170 A GB5613170 A GB 5613170A GB 5613170 A GB5613170 A GB 5613170A GB 1304556 A GB1304556 A GB 1304556A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ticl
- oxide
- ethylene
- alcl
- nov
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 2
- OALYTRUKMRCXNH-UHFFFAOYSA-N 5-pentyloxolan-2-one Chemical compound CCCCCC1CCC(=O)O1 OALYTRUKMRCXNH-UHFFFAOYSA-N 0.000 abstract 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- -1 titanium trichloride olefin Chemical class 0.000 abstract 2
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 abstract 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 abstract 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 abstract 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 1
- 229940093475 2-ethoxyethanol Drugs 0.000 abstract 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- LWBWGOJHWAARSS-UHFFFAOYSA-N diethylalumanyloxy(diethyl)alumane Chemical compound CC[Al](CC)O[Al](CC)CC LWBWGOJHWAARSS-UHFFFAOYSA-N 0.000 abstract 1
- OALYTRUKMRCXNH-QMMMGPOBSA-N gamma-Nonalactone Natural products CCCCC[C@H]1CCC(=O)O1 OALYTRUKMRCXNH-QMMMGPOBSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000002596 lactones Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 1
- 229960000380 propiolactone Drugs 0.000 abstract 1
- 239000006104 solid solution Substances 0.000 abstract 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1304556 Pulverized titanium trichloride olefin catalyst component SHOWA DENKO KK 25 Nov 1970 [26 Nov 1969 3 March 1970] 56131/70 Heading C3P [Also in Division C1] α-Olefins are polymerized in the presence of a catalyst comprising an organoaluminium compound and a TiCl 3 which has been ground during or after contact with an organic compound which is an alkylene oxide or a lactone or has at least one alcoholic or phenolic OH group. The following materials are exemplified: organo Al compounds tetraethyl dialuminoxane, Et 2 AlCl, EtAlCl 2 , Et 3 Al, diethyl Al #-caprolactam; treating agents ethylene oxide, propylene oxide, epichlorohydrin, allyl glycidyl ether, 2-butene oxide, γ-butyrolactone, #-caprolactone, #-propiolactone, γ-nonalactone, γ-valerolactone, coumarin, methanol, ethanol, t-butanol, phenol, cyclohexanol, 2-chloroethanol, 2-ethoxyethanol, ethylene glycol; monomers propylene, ethylene, butene-1; other compounds hexamethyl phosphortriamide, tri-n-butylamine, ZnCl 2 -pyridine complex, Et 2 Zn, H 2 . TiCl 3 alone, or a solid solution of TiCl 3 and AlCl 3 , may be used.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9425669 | 1969-11-26 | ||
| JP1766370 | 1970-03-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1304556A true GB1304556A (en) | 1973-01-24 |
Family
ID=26354220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5613170A Expired GB1304556A (en) | 1969-11-26 | 1970-11-25 |
Country Status (5)
| Country | Link |
|---|---|
| CA (1) | CA974700A (en) |
| DE (1) | DE2056749A1 (en) |
| FR (1) | FR2068665B1 (en) |
| GB (1) | GB1304556A (en) |
| PL (1) | PL74638B1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503188A (en) * | 1973-05-14 | 1975-01-14 | ||
| US4329440A (en) | 1974-01-10 | 1982-05-11 | Sumitomo Chemical Company, Limited | Process for producing highly crystalline α-olefinic polymer |
| US4444967A (en) * | 1975-12-22 | 1984-04-24 | Stauffer Chemical Company | Substantially agglomeration-free catalyst component |
| US4463102A (en) * | 1981-11-19 | 1984-07-31 | Northern Petrochemical Company | Polyolefin polymerization catalyst containing sterically unhindered phenolic compounds (II) |
| EP1138701A1 (en) * | 2000-03-30 | 2001-10-04 | Sumitomo Chemical Company, Limited | Process for producing catalyst for ethylene polymerization and process for producing ethylene polymer |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2742586A1 (en) * | 1976-09-28 | 1978-03-30 | Asahi Chemical Ind | NEW POLYMERIZATION CATALYSTS AND THEIR USE (II) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL260539A (en) * | 1960-10-31 |
-
1970
- 1970-11-18 DE DE19702056749 patent/DE2056749A1/en active Pending
- 1970-11-25 PL PL14463170A patent/PL74638B1/xx unknown
- 1970-11-25 GB GB5613170A patent/GB1304556A/en not_active Expired
- 1970-11-26 CA CA099,229A patent/CA974700A/en not_active Expired
- 1970-11-26 FR FR7042478A patent/FR2068665B1/fr not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503188A (en) * | 1973-05-14 | 1975-01-14 | ||
| US4329440A (en) | 1974-01-10 | 1982-05-11 | Sumitomo Chemical Company, Limited | Process for producing highly crystalline α-olefinic polymer |
| US4444967A (en) * | 1975-12-22 | 1984-04-24 | Stauffer Chemical Company | Substantially agglomeration-free catalyst component |
| US4463102A (en) * | 1981-11-19 | 1984-07-31 | Northern Petrochemical Company | Polyolefin polymerization catalyst containing sterically unhindered phenolic compounds (II) |
| EP1138701A1 (en) * | 2000-03-30 | 2001-10-04 | Sumitomo Chemical Company, Limited | Process for producing catalyst for ethylene polymerization and process for producing ethylene polymer |
| US6538079B2 (en) * | 2000-03-30 | 2003-03-25 | Sumitomo Chemical Company, Limited | Process for producing catalyst for ethylene polymerization and process for producing ethylene polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2068665B1 (en) | 1974-07-12 |
| DE2056749A1 (en) | 1971-07-01 |
| FR2068665A1 (en) | 1971-08-27 |
| PL74638B1 (en) | 1974-12-31 |
| CA974700A (en) | 1975-09-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |