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GB1393011A - Polyamide fibres - Google Patents

Polyamide fibres

Info

Publication number
GB1393011A
GB1393011A GB1957472A GB1957472A GB1393011A GB 1393011 A GB1393011 A GB 1393011A GB 1957472 A GB1957472 A GB 1957472A GB 1957472 A GB1957472 A GB 1957472A GB 1393011 A GB1393011 A GB 1393011A
Authority
GB
United Kingdom
Prior art keywords
trans
fibres
groups
iii
phenylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1957472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27495312&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=GB1393011(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1393011A publication Critical patent/GB1393011A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/32—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

1393011 Polyamide fibres E I DU PONT DE NEMOURS & CO 27 April 1972 [28 April 1972 (2) 17 Aug 1971 (2)] 19574/72 Heading B5B [Also in Division C3] Fibres and films are made from a polyamide having an inherent viscosity of at least 2À5 and consisting essentially of recurring units I and II, or III, or I and II and III wherein I is II is and III is When I and II are present in the polymer they are present in substantially equimolar amounts. R, R<SP>1</SP> and R<SP>11</SP> groups, which may be the same or different, are such that at least 95 mol per cent of the total R, R<SP>1</SP> and R<SP>11</SP> consist of single rigid radicals with extended bonds (as herein defined), or a series of such rigid radicals linked by extended bonds, rigid ring radicals may also be linked by azo or azoxy groups. n is 0 or 1. The fibres and films have a filament or film tenacity of 18 to 14 g.p.d., a filament or film breaking elongation of 3À5 to 8À0% and crystalline regions with a primary appararent crystallite size of 0 to 52Š. R, R<SP>1</SP> and R<SP>11</SP> groups mentioned are 1,4- phenylene; 4,4<SP>1</SP>-biphenylene; 1,5-naphthylene; 2,6-naphthylene; trans- 1 ,4-cyclohexylene; 2,5- pyridylene; trans-trans-4,4<SP>1</SP>-bicyclohexylene and 1,4-phenylene groups linked by transvinylene, ethynylene, azo or azoxy ; R may also be selected from trans-vinylene, ethynylene, trans-, trans-1,4-butadienylene or 2,4<SP>1</SP>-trans-vinylenephenylene and R<SP>11</SP> may be 2,4<SP>1</SP>-transvinylene-phenylene. All may be substituted or unsubstituted. Fibres are prepared by wet-spinning; a dope of the polymer being extruded through a layer of an inert non-coagulating fluid into a coagulating bath. The solvent may consist of either sulphuric acid of at least 98% concentration, chlorosulphuric acid or fluorosulphuric acid and the polymer concentration is at least 30 grams per 100 ml. of solvent.
GB1957472A 1971-04-28 1972-04-27 Polyamide fibres Expired GB1393011A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13821071A 1971-04-28 1971-04-28
US13818071A 1971-04-28 1971-04-28
US17251571A 1971-08-17 1971-08-17
US17257271A 1971-08-17 1971-08-17

Publications (1)

Publication Number Publication Date
GB1393011A true GB1393011A (en) 1975-05-07

Family

ID=27495312

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1957472A Expired GB1393011A (en) 1971-04-28 1972-04-27 Polyamide fibres

Country Status (19)

Country Link
JP (3) JPS5514170B1 (en)
AR (1) AR193389A1 (en)
AU (1) AU474823B2 (en)
BE (1) BE782795A (en)
CA (1) CA996716A (en)
CH (1) CH531057A (en)
DD (1) DD98540A5 (en)
DE (3) DE2265806C3 (en)
DK (1) DK153800C (en)
FR (1) FR2134582B1 (en)
GB (1) GB1393011A (en)
IE (1) IE36332B1 (en)
IL (1) IL39187A (en)
IT (1) IT968191B (en)
LU (1) LU65248A1 (en)
NL (1) NL172569B (en)
NO (1) NO136415B (en)
PL (1) PL82355B1 (en)
SE (1) SE381684B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3838053A1 (en) * 1987-11-09 1989-05-24 Asahi Chemical Ind Spinning-tube wet-spinning process
US5393478A (en) * 1993-08-20 1995-02-28 The Dow Chemical Company Process for coagulation and washing of polybenzazole fibers
US6592987B1 (en) 1997-09-09 2003-07-15 E. I. Du Pont De Namours And Company Wholly aromatic synthetic fiber produced by liquid-crystal spinning, process for producing the same, and use thereof

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1810426B2 (en) * 1968-06-12 1980-08-28 E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) Optically anisotropic mass containing aromatic polyamides
IL39188A (en) * 1971-04-28 1976-02-29 Du Pont Poly(p-phenylene terephthalamide)fibers and their preparation
SE416814B (en) * 1974-05-10 1981-02-09 Du Pont NEW SYNTHETIC POLYESTERS AND SETS FOR THEIR PREPARATION
NL174730C (en) * 1974-05-24 Rhone Poulenc Textile PROCESS FOR PREPARING AN OPTICAL ANISOTROPIC PREPARATION OF A STATISTICAL OR ORDINARY COPOLYAMIDE, AND PRODUCTS FORMED THEREOF, AND PROCEDURE FOR PREPARING THE COPOLYAMIDS.
NL157327C (en) * 1975-02-21 1984-05-16 Akzo Nv PROCESS FOR PREPARING POLY-P-PHENYLENE DEPHALAMIDE.
JPS551324A (en) * 1978-06-15 1980-01-08 Asahi Chem Ind Co Ltd Production of aromatic polyamide fiber
JPS55122012A (en) * 1979-03-13 1980-09-19 Asahi Chem Ind Co Ltd Poly-p-phenylene terephthalamide fiber having improved fatigue resistance and its production
JPS55122011A (en) * 1979-03-13 1980-09-19 Asahi Chem Ind Co Ltd Poly-p-phenylene terephthalamide fiber having high young's modulus and its preparation
NL172680C (en) 1979-06-08 1983-10-03 Akzo Nv PROCESS FOR MANUFACTURING FIBERS FROM POLY-P-PHENYLENE DEPTHALAMIDE AND THE PRODUCTS PRODUCED SO.
NL7904496A (en) * 1979-06-08 1980-12-10 Akzo Nv FIBER, WIRE BUNDLE AND ROPE OF POLY-P-PHENYLENE GRADE-LANGUAGE AMIDE.
DE3366159D1 (en) * 1982-01-29 1986-10-23 Ciba Geigy Ag Transparent, cross-linkable polyamides
JPS5943114A (en) * 1982-09-06 1984-03-10 Asahi Chem Ind Co Ltd Poly(p-phenylene terephthalamide) fiber
US4869860A (en) * 1984-08-09 1989-09-26 E. I. Du Pont De Nemours And Company Spinning process for aromatic polyamide filaments
DE3835441A1 (en) * 1988-10-18 1990-04-26 Hoechst Ag FULL-AROMATIC POLYAMIDES, METHOD FOR THE PRODUCTION THEREOF AND THEREFORE MOLDED PICTURES
DE3835419A1 (en) * 1988-10-18 1990-04-19 Hoechst Ag FULLY FLAVORED POLYAMIDES, METHOD FOR THE PRODUCTION THEREOF AND MOLDS MADE THEREOF
DE3835405A1 (en) * 1988-10-18 1990-05-03 Hoechst Ag FULLY FLAVORED POLYAMIDES, METHOD FOR THE PRODUCTION THEREOF AND MOLDS MADE THEREOF
DE4010941A1 (en) * 1990-04-05 1991-10-10 Hoechst Ag METHOD FOR PRODUCING AROMATIC POPYAMIDES WITH HIGH HYDROLYSIS RESISTANCE
KR100749962B1 (en) * 2005-07-06 2007-08-16 주식회사 코오롱 Aromatic polyamide filament and method of manufacturing the same
JP2013177716A (en) * 2012-01-30 2013-09-09 Teijin Ltd Wholly aromatic polyamide regenerated fiber and method for producing the same

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR738777A (en) * 1931-07-06 1932-12-29 Bemberg Ag Process for manufacturing cellulose products
US2318704A (en) * 1940-04-02 1943-05-11 Celanese Corp Production of artificial filaments, foils, and like shaped articles
NL108288C (en) * 1957-02-28
BE600587A (en) * 1960-02-25
FR1327017A (en) * 1960-09-05 1963-05-17 Process for wet spinning of polymers dissolved in aqueous solutions containing electrolytes and device for its implementation
US3154610A (en) * 1961-05-31 1964-10-27 Celanese Corp Process of wet spinning polyamides and prevention of gel formation
FR1323414A (en) * 1961-05-31 1963-04-05 Celanese Corp Improvements in the production of extruded products
US3080210A (en) * 1961-12-01 1963-03-05 Monsanto Chemicals Spinning of acrylonitrile polymers
US3414645A (en) * 1964-06-19 1968-12-03 Monsanto Co Process for spinning wholly aromatic polyamide fibers
GB1175042A (en) * 1966-03-11 1969-12-23 Compoflex Co Ltd Improvements in or relating to Flexible Hose or Tubing
US3411645A (en) * 1966-06-09 1968-11-19 Hercules Galion Prod Inc Refuse collecting vehicle forward tilt body
DE1745254A1 (en) * 1966-06-13 1970-12-23 Du Pont Polyamide threads, fibers, films and fibrids
CA928440A (en) * 1967-12-27 1973-06-12 I. Bair Thomas Fibres of aromatic para-oriented polyterephthalamides
DE1810426B2 (en) * 1968-06-12 1980-08-28 E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) Optically anisotropic mass containing aromatic polyamides
GB1272316A (en) * 1968-07-02 1972-04-26 Toray Industries Method for production of thermally stable polyimide fibres
US3532778A (en) * 1968-10-23 1970-10-06 Celanese Corp Art of producing shaped,modified,condensation polymers
US3574811A (en) * 1969-10-08 1971-04-13 Celanese Corp Polyamide wet-spinning and stretching process
US3642706A (en) * 1970-03-03 1972-02-15 Monsanto Co Process for spinning wholly aromatic polyamide filaments
IL39188A (en) * 1971-04-28 1976-02-29 Du Pont Poly(p-phenylene terephthalamide)fibers and their preparation
JPH0833594B2 (en) 1988-09-06 1996-03-29 富士写真フイルム株式会社 Irradiation field recognition method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3838053A1 (en) * 1987-11-09 1989-05-24 Asahi Chemical Ind Spinning-tube wet-spinning process
US5393478A (en) * 1993-08-20 1995-02-28 The Dow Chemical Company Process for coagulation and washing of polybenzazole fibers
US6592987B1 (en) 1997-09-09 2003-07-15 E. I. Du Pont De Namours And Company Wholly aromatic synthetic fiber produced by liquid-crystal spinning, process for producing the same, and use thereof

Also Published As

Publication number Publication date
AR193389A1 (en) 1973-04-23
LU65248A1 (en) 1972-07-13
IT968191B (en) 1974-03-20
DE2265806C3 (en) 1991-03-07
DD98540A5 (en) 1973-06-20
PL82355B1 (en) 1975-10-31
JPS5914567B2 (en) 1984-04-05
BE782795A (en) 1972-10-30
DE2219703B2 (en) 1975-01-16
DK153800B (en) 1988-09-05
AU474823B2 (en) 1976-08-05
AU4153572A (en) 1973-11-01
JPS5123566A (en) 1976-02-25
NO136415B (en) 1977-05-23
JPS5130257A (en) 1976-03-15
DK153800C (en) 1989-01-16
CA996716A (en) 1976-09-14
JPS5914568B2 (en) 1984-04-05
NL172569B (en) 1983-04-18
IE36332L (en) 1972-10-28
FR2134582B1 (en) 1979-06-08
DE2219703A1 (en) 1972-11-09
NL7205836A (en) 1972-10-31
IL39187A0 (en) 1972-06-28
DE2219703C3 (en) 1984-06-07
IL39187A (en) 1976-02-29
IE36332B1 (en) 1976-10-13
DE2265807C3 (en) 1990-05-10
CH531057A (en) 1972-11-30
SE381684B (en) 1975-12-15
JPS5514170B1 (en) 1980-04-14
FR2134582A1 (en) 1972-12-08

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
430B Application (made) for amendment of specification (sect. 30/1949)
746B Proceeding under section 46(3) patents act 1977
746B Proceeding under section 46(3) patents act 1977
430A Specification amended (sect. 30/1949)
SPA Amended specification published
PE20 Patent expired after termination of 20 years