GB1387303A - Polymers - Google Patents
PolymersInfo
- Publication number
- GB1387303A GB1387303A GB694672A GB694672A GB1387303A GB 1387303 A GB1387303 A GB 1387303A GB 694672 A GB694672 A GB 694672A GB 694672 A GB694672 A GB 694672A GB 1387303 A GB1387303 A GB 1387303A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymer
- polymers
- polyketones
- feb
- phenoxybenzoyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 230000021736 acetylation Effects 0.000 abstract 2
- 238000006640 acetylation reaction Methods 0.000 abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 abstract 2
- 229920001470 polyketone Polymers 0.000 abstract 2
- AOOZVQGGMFGGEE-UHFFFAOYSA-N 4-phenoxybenzoyl chloride Chemical compound C1=CC(C(=O)Cl)=CC=C1OC1=CC=CC=C1 AOOZVQGGMFGGEE-UHFFFAOYSA-N 0.000 abstract 1
- 229910015900 BF3 Inorganic materials 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000004020 conductor Substances 0.000 abstract 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- -1 p-phenoxybenzoyl halides Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/307—Other macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/15—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/127—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from carbon dioxide, carbonyl halide, carboxylic acids or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/05—Filamentary, e.g. strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/06—Rod-shaped
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polyethers (AREA)
- Organic Insulating Materials (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
1387303 Polyketones RAYCHEM CORP 15 Feb 1972 [16 Feb 1971 17 Jan 1972] 6946/72 Heading C3R Melt processable polyketones have repeating units of formula and have inherent viscosities between 0À8 and 1À65 (measured as a solution of 0À1 gm. of polymer in 100 ml. of concentrated sulphuric acid at 25 C.) and an elongation to break at room temperature of at least 50%. The polymers are obtained by polyermizing p-phenoxybenzoyl halides under Friedel-Crafts acetylation conditions, the reaction mixture containing an aromatic compound having a rate of reaction to acetylation relative to benzene greater than 150, which controls the inherent viscosity by endcapping the polymer chains and so terminating the polymerization. The polymer may be recovered by spray drying and may be solvent extracted. In examples polymers are obtained from p-phenoxybenzoyl chloride and from pphenoxybenzoyl fluoride in hydrogen fluoride with boron trifluoride as catalyst, the capping agents being biphenyl and diphenyl ether. Uses.-Insulation for electrical conductors, especially wires, fibres, films and moulded articles.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11582471A | 1971-02-16 | 1971-02-16 | |
| US21846572A | 1972-01-17 | 1972-01-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1387303A true GB1387303A (en) | 1975-03-12 |
Family
ID=26813604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB694672A Expired GB1387303A (en) | 1971-02-16 | 1972-02-15 | Polymers |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS5633419B1 (en) |
| AT (1) | AT335183B (en) |
| AU (1) | AU470466B2 (en) |
| BE (1) | BE779457A (en) |
| CA (1) | CA1011895A (en) |
| CH (1) | CH587872A5 (en) |
| DE (2) | DE2266022C2 (en) |
| ES (1) | ES399816A1 (en) |
| FR (1) | FR2125511B1 (en) |
| GB (1) | GB1387303A (en) |
| IL (1) | IL38768A (en) |
| IT (1) | IT960658B (en) |
| SE (2) | SE407070B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4359501A (en) | 1981-10-28 | 1982-11-16 | Albany International Corp. | Hydrolysis resistant polyaryletherketone fabric |
| US4360630A (en) * | 1979-12-14 | 1982-11-23 | Imperial Chemical Industries Limited | Compositions of aromatic polyetherketones and glass and/or carbon fibres |
| GB2138433A (en) * | 1983-03-31 | 1984-10-24 | Raychem Corp | Preparation of poly (arylene ether ketones) |
| US4533417A (en) * | 1983-07-19 | 1985-08-06 | Bicc Public Limited Company | Manufacture of oriented insulated wires and cables |
| GB2172294A (en) * | 1985-03-11 | 1986-09-17 | Union Carbide Corp | Process for preparing poly(aryl ether ketones) |
| US4650228A (en) * | 1983-09-14 | 1987-03-17 | Raychem Corporation | Heat-recoverable coupling assembly |
| EP0173408A3 (en) * | 1984-03-29 | 1987-09-30 | Raychem Corporation | Preparing poly(arylene ketones) |
| US4791708A (en) * | 1984-02-23 | 1988-12-20 | Asten Group, Inc. | Abrasion and hydrolysis resistant joining means for fabric seams |
| US4820571A (en) * | 1983-07-12 | 1989-04-11 | Asten Group, Inc. | High temperature industrial fabrics |
| EP0557950A3 (en) * | 1992-02-26 | 1993-12-08 | Hoechst Ag | Polyetherketones and polyethersulphones based on phenylindane and their use for optical systems |
| US5362836A (en) * | 1992-06-11 | 1994-11-08 | Hoechst Aktiengesellschaft | Polymer electrolytes and their preparation |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1470049A (en) * | 1973-03-21 | 1977-04-14 | Rachem Corp | Splicing method and heat-recoverable article |
| CA1112393A (en) * | 1975-11-07 | 1981-11-10 | Klaus J. Dahl | Ketone and sulfone polymers |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB971227A (en) * | 1962-05-21 | 1900-01-01 | ||
| NL6611019A (en) * | 1965-08-04 | 1967-02-06 | ||
| GB1153035A (en) * | 1965-09-24 | 1969-05-21 | Ici Ltd | Production of Aromatic Polymers and Intermediates therefor |
| GB1153527A (en) * | 1965-09-24 | 1969-05-29 | Ici Ltd | Aromatic Polymers and the production thereof |
| US3442857A (en) * | 1965-11-10 | 1969-05-06 | Du Pont | Boron trifluoride-hydrogen fluoride catalyzed synthesis of poly(aromatic sulfone) and poly(aromatic ketone) polymers |
| US3516966A (en) * | 1968-02-05 | 1970-06-23 | Du Pont | Polyketone copolymers |
-
1972
- 1972-02-14 DE DE2266022A patent/DE2266022C2/de not_active Expired
- 1972-02-14 DE DE19722206835 patent/DE2206835A1/en active Granted
- 1972-02-15 IL IL38768A patent/IL38768A/en unknown
- 1972-02-15 GB GB694672A patent/GB1387303A/en not_active Expired
- 1972-02-15 AU AU38999/72A patent/AU470466B2/en not_active Expired
- 1972-02-15 ES ES399816A patent/ES399816A1/en not_active Expired
- 1972-02-16 JP JP1631772A patent/JPS5633419B1/ja active Pending
- 1972-02-16 BE BE779457A patent/BE779457A/en not_active IP Right Cessation
- 1972-02-16 CH CH219872A patent/CH587872A5/xx not_active IP Right Cessation
- 1972-02-16 CA CA134,800A patent/CA1011895A/en not_active Expired
- 1972-02-16 IT IT20629/72A patent/IT960658B/en active
- 1972-02-16 SE SE7201871A patent/SE407070B/en unknown
- 1972-02-16 AT AT126872A patent/AT335183B/en not_active IP Right Cessation
- 1972-02-16 FR FR7205180A patent/FR2125511B1/fr not_active Expired
-
1975
- 1975-10-23 SE SE7511897A patent/SE411764B/en not_active IP Right Cessation
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4360630A (en) * | 1979-12-14 | 1982-11-23 | Imperial Chemical Industries Limited | Compositions of aromatic polyetherketones and glass and/or carbon fibres |
| US4359501A (en) | 1981-10-28 | 1982-11-16 | Albany International Corp. | Hydrolysis resistant polyaryletherketone fabric |
| GB2179951A (en) * | 1983-03-31 | 1987-03-18 | Raychem Corp | Preparation of poly (arylene ether ketones) |
| GB2138433A (en) * | 1983-03-31 | 1984-10-24 | Raychem Corp | Preparation of poly (arylene ether ketones) |
| US4820571A (en) * | 1983-07-12 | 1989-04-11 | Asten Group, Inc. | High temperature industrial fabrics |
| US4533417A (en) * | 1983-07-19 | 1985-08-06 | Bicc Public Limited Company | Manufacture of oriented insulated wires and cables |
| US4650228A (en) * | 1983-09-14 | 1987-03-17 | Raychem Corporation | Heat-recoverable coupling assembly |
| US4791708A (en) * | 1984-02-23 | 1988-12-20 | Asten Group, Inc. | Abrasion and hydrolysis resistant joining means for fabric seams |
| EP0173408A3 (en) * | 1984-03-29 | 1987-09-30 | Raychem Corporation | Preparing poly(arylene ketones) |
| GB2172294A (en) * | 1985-03-11 | 1986-09-17 | Union Carbide Corp | Process for preparing poly(aryl ether ketones) |
| EP0557950A3 (en) * | 1992-02-26 | 1993-12-08 | Hoechst Ag | Polyetherketones and polyethersulphones based on phenylindane and their use for optical systems |
| US5373081A (en) * | 1992-02-26 | 1994-12-13 | Hoechst Aktiengesellschaft | Polyether ketones and polyether sulfones based on phenylindane, and the use thereof for optical systems |
| US5362836A (en) * | 1992-06-11 | 1994-11-08 | Hoechst Aktiengesellschaft | Polymer electrolytes and their preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| AT335183B (en) | 1977-02-25 |
| CH587872A5 (en) | 1977-05-13 |
| DE2266022C2 (en) | 1987-11-19 |
| ES399816A1 (en) | 1975-06-16 |
| ATA126872A (en) | 1976-06-15 |
| IT960658B (en) | 1973-11-30 |
| BE779457A (en) | 1972-08-16 |
| FR2125511B1 (en) | 1978-06-02 |
| SE411764B (en) | 1980-02-04 |
| AU3899972A (en) | 1973-08-16 |
| SE407070B (en) | 1979-03-12 |
| SE7511897L (en) | 1975-10-23 |
| IL38768A (en) | 1975-04-25 |
| AU470466B2 (en) | 1976-03-18 |
| FR2125511A1 (en) | 1972-09-29 |
| IL38768A0 (en) | 1972-06-28 |
| JPS5633419B1 (en) | 1981-08-04 |
| CA1011895A (en) | 1977-06-07 |
| DE2206835C2 (en) | 1988-08-11 |
| DE2206835A1 (en) | 1972-10-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1387303A (en) | Polymers | |
| US3953400A (en) | Polyketones and methods therefor | |
| US3385825A (en) | Fiber-forming polyketones | |
| US3631010A (en) | Process for the production of transpolypentenamers | |
| US4239884A (en) | Process for isolation of solid polymers | |
| GB1250225A (en) | ||
| US3974094A (en) | Catalyst system for the production of polyalkenamers | |
| CA1126447A (en) | Liquid peroxide composition | |
| CA1044397A (en) | Aromatic polyketones | |
| US3098058A (en) | Process for reacting a diolefinic polymer with hexachlorocyclopentadiene production of new polymeric compositions and products thereof | |
| US3816382A (en) | Polyalkenamers and process for the preparation thereof | |
| US2932630A (en) | Polymers of bicyclo (2. 2. 1)-2-heptene | |
| US3816384A (en) | Polyalkenamers and process for the preparation thereof | |
| GB1414421A (en) | Aromatic polymers | |
| US3265640A (en) | Crosslinked polymers from alpha, alpha-dichloro-p-xylene and polysubstituted benzenes | |
| US3849509A (en) | Polyalkenamers and process for the preparation thereof | |
| US5221786A (en) | Process for the preparation of polythiophenes and electrically conducting devices containing them | |
| US3325530A (en) | Method for making organosilicon copolymers | |
| US5279768A (en) | Process for the preparation of electrically conductive polymers derived from 3-alkylthiophenes | |
| US5254648A (en) | Process for the preparation of polythiophenes and electrically conducting devices containing them | |
| GB1434672A (en) | Process for preparing cyclic polyethers | |
| US3565862A (en) | Hydroxybenzenesulfonyl halide polymerization | |
| US3236807A (en) | Process for preparing poly(unsymmetri-cally-2, 6-disubstituted phenylene) ether | |
| CA1042132A (en) | Production of polymeric compounds having functional end groups | |
| US3179649A (en) | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |