GB1384318A - Phenolic resin foams - Google Patents
Phenolic resin foamsInfo
- Publication number
- GB1384318A GB1384318A GB1686472A GB1686472A GB1384318A GB 1384318 A GB1384318 A GB 1384318A GB 1686472 A GB1686472 A GB 1686472A GB 1686472 A GB1686472 A GB 1686472A GB 1384318 A GB1384318 A GB 1384318A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- formaldehyde
- resol
- catalyst
- april
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006260 foam Substances 0.000 title abstract 3
- 229920001568 phenolic resin Polymers 0.000 title abstract 2
- 239000005011 phenolic resin Substances 0.000 title abstract 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 15
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 3
- 229920003987 resole Polymers 0.000 abstract 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08J2361/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols with monohydric phenols
- C08J2361/10—Phenol-formaldehyde condensates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
1384318 Self-extinguishing phenolic foams SAINT-GOBAIN 12 April 1972 [15 April 1971] 16864/72 Heading C3C A process for obtaining phenol resin foams comprises mixing a resol, obtained by condensing a phenol formaldehyde mixture in the presence of an alkaline catalyst, with a blowing agent, an agent for controlling the formation of cells and an acid, wherein the formaldehyde and catalyst used for effecting the condensation of the phenol and formaldehyde are added to the phenol in at least two successive stages such that the proportion of free phenol remaining is less than 8% by weight of the total mass after concentration of the resol obtained by removal of water therefrom, while the total mole ratio of formaldehyde to phenol used is less than or equal to 1À7 : 1. In the examples phenol and formaldehyde are condensed using NaOH catalyst by adding the formaldehyde and NaOH in two stages to phenol. The resol thus obtained is foamed in the mould using pentane or monofluorotrichloromethane as foaming agent.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7113238A FR2147766B1 (en) | 1971-04-15 | 1971-04-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1384318A true GB1384318A (en) | 1975-02-19 |
Family
ID=9075292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1686472A Expired GB1384318A (en) | 1971-04-15 | 1972-04-12 | Phenolic resin foams |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS5148177B1 (en) |
| AT (1) | AT314840B (en) |
| AU (1) | AU473596B2 (en) |
| BE (1) | BE782147A (en) |
| BR (1) | BR7202187D0 (en) |
| CA (1) | CA1015500A (en) |
| CH (1) | CH535809A (en) |
| DE (1) | DE2218271A1 (en) |
| ES (1) | ES401758A1 (en) |
| FI (1) | FI57437C (en) |
| FR (1) | FR2147766B1 (en) |
| GB (1) | GB1384318A (en) |
| IL (1) | IL39222A (en) |
| IT (1) | IT951387B (en) |
| LU (1) | LU65165A1 (en) |
| NL (1) | NL7205031A (en) |
| NO (1) | NO137757C (en) |
| TR (1) | TR17307A (en) |
| ZA (1) | ZA722524B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1095970A4 (en) * | 1998-07-03 | 2003-02-05 | Asahi Chemical Ind | Phenolic foam |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2309574A1 (en) * | 1975-04-30 | 1976-11-26 | Saint Gobain | PROCESS FOR MANUFACTURING PHENOLIC RESINS |
| FR2350945A1 (en) | 1976-05-12 | 1977-12-09 | Saint Gobain | IMPROVEMENT OF PROCESS AND INSTALLATION FOR THE CONTINUOUS MANUFACTURING OF CELLULAR PRODUCTS IN THERMOSETTING RESIN |
| US4303758A (en) * | 1976-06-07 | 1981-12-01 | Gusmer Frederick E | Method of preparing closed cell phenol-aldehyde foam and the closed cell foam thus prepared |
| JPS5426880A (en) * | 1977-07-30 | 1979-02-28 | Kutsuwa Kk | Method of making cover board in container*bag*file*etc |
-
1971
- 1971-04-15 FR FR7113238A patent/FR2147766B1/fr not_active Expired
-
1972
- 1972-04-12 GB GB1686472A patent/GB1384318A/en not_active Expired
- 1972-04-12 FI FI1033/72A patent/FI57437C/en active
- 1972-04-12 AU AU41062/72A patent/AU473596B2/en not_active Expired
- 1972-04-13 TR TR17307A patent/TR17307A/en unknown
- 1972-04-13 IT IT23112/72A patent/IT951387B/en active
- 1972-04-13 BR BR722187A patent/BR7202187D0/en unknown
- 1972-04-14 NO NO1312/72A patent/NO137757C/en unknown
- 1972-04-14 ES ES401758A patent/ES401758A1/en not_active Expired
- 1972-04-14 CA CA139,727A patent/CA1015500A/en not_active Expired
- 1972-04-14 CH CH548672A patent/CH535809A/en not_active IP Right Cessation
- 1972-04-14 NL NL7205031A patent/NL7205031A/xx not_active Application Discontinuation
- 1972-04-14 LU LU65165D patent/LU65165A1/xx unknown
- 1972-04-14 BE BE782147A patent/BE782147A/en not_active IP Right Cessation
- 1972-04-14 ZA ZA722524A patent/ZA722524B/en unknown
- 1972-04-14 JP JP47037044A patent/JPS5148177B1/ja active Pending
- 1972-04-14 IL IL39222A patent/IL39222A/en unknown
- 1972-04-14 AT AT331172A patent/AT314840B/en not_active IP Right Cessation
- 1972-04-15 DE DE19722218271 patent/DE2218271A1/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1095970A4 (en) * | 1998-07-03 | 2003-02-05 | Asahi Chemical Ind | Phenolic foam |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2147766A1 (en) | 1973-03-11 |
| BR7202187D0 (en) | 1973-05-10 |
| ZA722524B (en) | 1973-01-31 |
| CH535809A (en) | 1973-04-15 |
| NL7205031A (en) | 1972-10-17 |
| BE782147A (en) | 1972-10-16 |
| NO137757C (en) | 1978-04-19 |
| FR2147766B1 (en) | 1974-03-08 |
| FI57437C (en) | 1980-08-11 |
| JPS5148177B1 (en) | 1976-12-18 |
| IL39222A0 (en) | 1972-06-28 |
| ES401758A1 (en) | 1975-03-01 |
| CA1015500A (en) | 1977-08-09 |
| AT314840B (en) | 1974-04-25 |
| TR17307A (en) | 1975-03-24 |
| NO137757B (en) | 1978-01-09 |
| LU65165A1 (en) | 1972-12-07 |
| DE2218271A1 (en) | 1972-11-02 |
| FI57437B (en) | 1980-04-30 |
| IT951387B (en) | 1973-06-30 |
| AU4106272A (en) | 1973-10-18 |
| IL39222A (en) | 1975-04-25 |
| AU473596B2 (en) | 1973-10-18 |
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| Publication | Publication Date | Title |
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| EP0170357B1 (en) | A process for producing phenolic foams | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |