GB1365479A - Plasticisers for polymers of vinyl acetate - Google Patents
Plasticisers for polymers of vinyl acetateInfo
- Publication number
- GB1365479A GB1365479A GB5090670A GB5090670A GB1365479A GB 1365479 A GB1365479 A GB 1365479A GB 5090670 A GB5090670 A GB 5090670A GB 5090670 A GB5090670 A GB 5090670A GB 1365479 A GB1365479 A GB 1365479A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glycol
- vinyl acetate
- polyester
- mixtures
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 4
- 239000004014 plasticizer Substances 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 229920000728 polyester Polymers 0.000 abstract 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N Butanol Natural products CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 3
- 239000002202 Polyethylene glycol Substances 0.000 abstract 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 abstract 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001279 adipic acids Chemical class 0.000 abstract 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 2
- 150000002311 glutaric acids Chemical class 0.000 abstract 2
- 150000003444 succinic acids Chemical class 0.000 abstract 2
- 229940058015 1,3-butylene glycol Drugs 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 235000011037 adipic acid Nutrition 0.000 abstract 1
- -1 aliphatic alcohols Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 235000019437 butane-1,3-diol Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 229940035429 isobutyl alcohol Drugs 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 235000011044 succinic acid Nutrition 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1365479 Plasticized vinyl acetate polymers CIBA-GEIGY AG 27 Oct 1971 [27 Oct 1970] 50906/70 Headings C3P and C3R Compositions comprise (1) a vinyl acetate polymer or copolymer containing a major proportion of vinyl acetate units and (2) 10 to 100% by weight of (1) of a polyester of average molecular weight 250 to 3000 derived from a C 4-10 dibasic acid or anhydride, a mono-, di- or polyalkylene glycol of molecular weight up to 1000 and a C 2-11 aliphatic monohydric alcohol. The polyester may be derived from succinic, glutaric and adipic acids and mixtures thereof, or phthalic anhydride; ethylene glycol or a polyethylene glycol; and n-butyl or isobutyl alcohol. The vinyl acetate may be copolymerized with ethylene or a maleate or acrylate. The polyester may be added to a stirred emulsion of the polymer. In examples polyvinyl acetate is plasticized with polyesters derived from phthalic anhydride, n-butanol and polyethylene glycol (200), ethylene glycol, diethylene glycol or triethylene glycol; and from mixtures of adipic, glutaric and succinic acids, ethylene glycol, polyethylene glycol (200), 1,2-propylene glycol or 1,3-butylene glycol, and isobutanol; and from mixtures of such acids, ethylene glycol or 1,2-propylene glycol, and C 7-9 aliphatic alcohols.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5090670A GB1365479A (en) | 1970-10-27 | 1970-10-27 | Plasticisers for polymers of vinyl acetate |
| AU34867/71A AU3486771A (en) | 1970-10-27 | 1971-10-21 | Plasticisers for polymers of vinyl acetate |
| CA126,076A CA980935A (en) | 1970-10-27 | 1971-10-26 | Plasticisers for polymers of vinyl acetate |
| ES396373A ES396373A1 (en) | 1970-10-27 | 1971-10-26 | Plasticisers for polymers of vinyl acetate |
| DE19712153282 DE2153282A1 (en) | 1970-10-27 | 1971-10-26 | Plasticizer for vinyl acetate polymers |
| BE774482A BE774482A (en) | 1970-10-27 | 1971-10-26 | PLASTICIZERS FOR USE IN VINYL ACETATE POLYMERS |
| FR7138415A FR2113253A5 (en) | 1970-10-27 | 1971-10-26 | |
| NL7114735A NL7114735A (en) | 1970-10-27 | 1971-10-26 | |
| US05/602,890 US4076678A (en) | 1970-10-27 | 1975-08-07 | Plasticized polymers of vinyl acetate |
| US05/602,888 US4111888A (en) | 1970-10-27 | 1975-08-07 | Plasticized polymers of vinyl acetate |
| US05/602,887 US4085083A (en) | 1970-10-27 | 1975-08-07 | Plasticized polymers of vinyl acetate |
| US05/602,889 US4085082A (en) | 1970-10-27 | 1975-08-07 | Polymers of vinyl acetate plasticized with low molecular weight polyesters |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5090670A GB1365479A (en) | 1970-10-27 | 1970-10-27 | Plasticisers for polymers of vinyl acetate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1365479A true GB1365479A (en) | 1974-09-04 |
Family
ID=10457855
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5090670A Expired GB1365479A (en) | 1970-10-27 | 1970-10-27 | Plasticisers for polymers of vinyl acetate |
Country Status (8)
| Country | Link |
|---|---|
| AU (1) | AU3486771A (en) |
| BE (1) | BE774482A (en) |
| CA (1) | CA980935A (en) |
| DE (1) | DE2153282A1 (en) |
| ES (1) | ES396373A1 (en) |
| FR (1) | FR2113253A5 (en) |
| GB (1) | GB1365479A (en) |
| NL (1) | NL7114735A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023111736A1 (en) * | 2021-12-16 | 2023-06-22 | 3M Innovative Properties Company | Melt processible compositions comprising a nonfluorinated polymer processing additive and methods of use |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3938894A1 (en) * | 1989-11-24 | 1991-05-29 | Fraunhofer Ges Forschung | BINDER FOR METAL OR CERAMIC POWDER |
-
1970
- 1970-10-27 GB GB5090670A patent/GB1365479A/en not_active Expired
-
1971
- 1971-10-21 AU AU34867/71A patent/AU3486771A/en not_active Expired
- 1971-10-26 DE DE19712153282 patent/DE2153282A1/en active Pending
- 1971-10-26 CA CA126,076A patent/CA980935A/en not_active Expired
- 1971-10-26 FR FR7138415A patent/FR2113253A5/fr not_active Expired
- 1971-10-26 NL NL7114735A patent/NL7114735A/xx unknown
- 1971-10-26 BE BE774482A patent/BE774482A/en unknown
- 1971-10-26 ES ES396373A patent/ES396373A1/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023111736A1 (en) * | 2021-12-16 | 2023-06-22 | 3M Innovative Properties Company | Melt processible compositions comprising a nonfluorinated polymer processing additive and methods of use |
Also Published As
| Publication number | Publication date |
|---|---|
| CA980935A (en) | 1975-12-30 |
| FR2113253A5 (en) | 1972-06-23 |
| DE2153282A1 (en) | 1972-05-04 |
| NL7114735A (en) | 1972-05-02 |
| AU3486771A (en) | 1973-05-03 |
| AU465439B2 (en) | 1975-09-25 |
| ES396373A1 (en) | 1974-12-16 |
| BE774482A (en) | 1972-04-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |