GB1365087A - Method for preparing acrolein and acetic anhydride - Google Patents
Method for preparing acrolein and acetic anhydrideInfo
- Publication number
- GB1365087A GB1365087A GB5774371A GB5774371A GB1365087A GB 1365087 A GB1365087 A GB 1365087A GB 5774371 A GB5774371 A GB 5774371A GB 5774371 A GB5774371 A GB 5774371A GB 1365087 A GB1365087 A GB 1365087A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetic anhydride
- acrolein
- noble metal
- metal catalyst
- acetic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 title abstract 9
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title abstract 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 9
- TXECTBGVEUDNSL-UHFFFAOYSA-N 1-acetyloxyprop-2-enyl acetate Chemical compound CC(=O)OC(C=C)OC(C)=O TXECTBGVEUDNSL-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910000510 noble metal Inorganic materials 0.000 abstract 3
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052714 tellurium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1365087 Acrolein; acetic anhydride BAYER AG 13 Dec 1971 [12 Dec 1970 3 May 1971] 57743/71 Heading C2C Acrolein and acetic anhydride are prepared by heating a diacetoxypropene to 50-300‹ C. in the presence of at least one acid and/or at least one halide of a metal of one of Groups II to VIII or of B, Si, As, Sb or Te. Liquid or gas phase may be used. The diacetoxypropene may be obtained by reacting propylene, O 2 and acetic acid in the presence of a noble metal catalyst to give allyl acetate which is then reacted in a second stage with O 2 and acetic acid in the presence of a noble metal catalyst. Alternatively propylene may be reacted with O 2 and acetic acid in the presence of a noble metal catalyst to give diacetoxy-propene and allylacetate, the latter being separated and recycled.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702061240 DE2061240A1 (en) | 1970-12-12 | 1970-12-12 | Acrolein and acetic anhydride prodn - by catalytic cleavage of diacetoxypropene |
| DE19712121672 DE2121672A1 (en) | 1971-05-03 | 1971-05-03 | Acrolein and acetic anhydride prodn - by catalytic cleavage of diacetoxypropene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1365087A true GB1365087A (en) | 1974-08-29 |
Family
ID=25760177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5774371A Expired GB1365087A (en) | 1970-12-12 | 1971-12-13 | Method for preparing acrolein and acetic anhydride |
Country Status (8)
| Country | Link |
|---|---|
| AT (1) | AT320605B (en) |
| BE (1) | BE776512A (en) |
| CA (1) | CA949073A (en) |
| ES (1) | ES397879A1 (en) |
| FR (1) | FR2117663A5 (en) |
| GB (1) | GB1365087A (en) |
| IT (1) | IT945372B (en) |
| NL (1) | NL7116925A (en) |
-
1971
- 1971-12-09 NL NL7116925A patent/NL7116925A/xx unknown
- 1971-12-10 IT IT5465771A patent/IT945372B/en active
- 1971-12-10 FR FR7144507A patent/FR2117663A5/fr not_active Expired
- 1971-12-10 CA CA129,838A patent/CA949073A/en not_active Expired
- 1971-12-10 AT AT1064571A patent/AT320605B/en not_active IP Right Cessation
- 1971-12-10 BE BE776512A patent/BE776512A/en unknown
- 1971-12-11 ES ES397879A patent/ES397879A1/en not_active Expired
- 1971-12-13 GB GB5774371A patent/GB1365087A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES397879A1 (en) | 1975-03-01 |
| IT945372B (en) | 1973-05-10 |
| NL7116925A (en) | 1972-06-14 |
| FR2117663A5 (en) | 1972-07-21 |
| AT320605B (en) | 1975-02-25 |
| BE776512A (en) | 1972-06-12 |
| CA949073A (en) | 1974-06-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |