GB1363278A - Latex compositions - Google Patents
Latex compositionsInfo
- Publication number
- GB1363278A GB1363278A GB3914171A GB3914171A GB1363278A GB 1363278 A GB1363278 A GB 1363278A GB 3914171 A GB3914171 A GB 3914171A GB 3914171 A GB3914171 A GB 3914171A GB 1363278 A GB1363278 A GB 1363278A
- Authority
- GB
- United Kingdom
- Prior art keywords
- latex
- amino alcohol
- ionic surfactant
- ester
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004816 latex Substances 0.000 title abstract 5
- 229920000126 latex Polymers 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 239000002736 nonionic surfactant Substances 0.000 abstract 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Chemical group 0.000 abstract 2
- -1 amino alcohol ester Chemical group 0.000 abstract 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- XSHISXQEKIKSGC-UHFFFAOYSA-N 2-aminoethyl 2-methylprop-2-enoate;hydron;chloride Chemical compound Cl.CC(=C)C(=O)OCCN XSHISXQEKIKSGC-UHFFFAOYSA-N 0.000 abstract 1
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 125000002843 carboxylic acid group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003093 cationic surfactant Substances 0.000 abstract 1
- JCRDPEHHTDKTGB-UHFFFAOYSA-N dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound Cl.CN(C)CCOC(=O)C(C)=C JCRDPEHHTDKTGB-UHFFFAOYSA-N 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003839 salts Chemical group 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/10—Esters
- C08F22/12—Esters of phenols or saturated alcohols
- C08F22/22—Esters containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
1363278 Polymer latex DOW CHEMICAL CO 20 Aug 1971 39141/71 Heading C3P A polymer latex is formed by polymerizing in an aqueous medium at a pH below 7 in the presence of a non-ionic surfactant a monomer mixture comprising (a) monomer or monomers providing carboxylic acid groups in an amount of 0À26-5À2% and ester groups derived from an amino alcohol having at least one covalently bonded hydrogen on the nitrogen in an amount to provide 0À0085-0À85% of nitrogen based on the weight of total monomers and (b) at least one water insoluble comonomer, and increasing the pH of the latex to above 8. The amino alcohol ester and acid groups may be provided in the same monomer as a maleate or similar half ester but in the examples are used mixtures of an acid, e.g. methacrylic, acrylic, fumaric, itaconic or maleic acid, and an amino alcohol ester, e.g. 2-aminoethyl methacrylate hydrochloride which may be used in combination with dimethylaminoethyl methacrylate hydrochloride. Comonomers used are combinations of nbutyl acrylate, methyl methacrylate, ethyl acrylate, styrene and butadiene. Polymerization is effected with redox catalysts using a non- ionic surfactant and optionally a cationic surfactant. The latex may be made alkaline and into the salt form by adding ammonium hydroxide and further non-ionic surfactant and formed into a paint by adding pigment.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3914171A GB1363278A (en) | 1971-08-20 | 1971-08-20 | Latex compositions |
| NL7111502.A NL160846B (en) | 1971-08-20 | 1971-08-20 | PROCESS FOR THE PREPARATION OF A STABLE LATEX |
| JP7165596A JPS5416996B2 (en) | 1971-08-20 | 1971-08-28 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3914171A GB1363278A (en) | 1971-08-20 | 1971-08-20 | Latex compositions |
| NL7111502.A NL160846B (en) | 1971-08-20 | 1971-08-20 | PROCESS FOR THE PREPARATION OF A STABLE LATEX |
| JP7165596A JPS5416996B2 (en) | 1971-08-20 | 1971-08-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1363278A true GB1363278A (en) | 1974-08-14 |
Family
ID=27259548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3914171A Expired GB1363278A (en) | 1971-08-20 | 1971-08-20 | Latex compositions |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS5416996B2 (en) |
| GB (1) | GB1363278A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4528322A (en) * | 1983-01-28 | 1985-07-09 | Rhone-Poulenc Specialites Chimiques | Aqueous cationic dispersions of synthetic polymers |
| EP4455227A1 (en) * | 2023-04-28 | 2024-10-30 | Basf Se | Emulsion system containing anionic latex composition for improved coating |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5458789A (en) * | 1977-10-19 | 1979-05-11 | Nippon Zeon Co Ltd | Novel conjugated diolefin copolymer latex |
| EP0290777A3 (en) * | 1987-04-06 | 1990-05-02 | Ppg Industries, Inc. | Anionic latex containing acid and amine groups and a process for preparing the same |
-
1971
- 1971-08-20 GB GB3914171A patent/GB1363278A/en not_active Expired
- 1971-08-28 JP JP7165596A patent/JPS5416996B2/ja not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4528322A (en) * | 1983-01-28 | 1985-07-09 | Rhone-Poulenc Specialites Chimiques | Aqueous cationic dispersions of synthetic polymers |
| EP4455227A1 (en) * | 2023-04-28 | 2024-10-30 | Basf Se | Emulsion system containing anionic latex composition for improved coating |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5416996B2 (en) | 1979-06-26 |
| JPS4832188A (en) | 1973-04-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |