GB1361518A - Photocurable compositions - Google Patents
Photocurable compositionsInfo
- Publication number
- GB1361518A GB1361518A GB3153572A GB3153572A GB1361518A GB 1361518 A GB1361518 A GB 1361518A GB 3153572 A GB3153572 A GB 3153572A GB 3153572 A GB3153572 A GB 3153572A GB 1361518 A GB1361518 A GB 1361518A
- Authority
- GB
- United Kingdom
- Prior art keywords
- meth
- acrylic
- acrylates
- benzoin
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- -1 Acrylic ester Chemical class 0.000 abstract 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 2
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 abstract 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 abstract 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 abstract 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 abstract 1
- YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 abstract 1
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 abstract 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 235000012730 carminic acid Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- MIJRFWVFNKQQDK-UHFFFAOYSA-N furoin Chemical compound C=1C=COC=1C(O)C(=O)C1=CC=CO1 MIJRFWVFNKQQDK-UHFFFAOYSA-N 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 abstract 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229960000907 methylthioninium chloride Drugs 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical group OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
- JEVGKYBUANQAKG-UHFFFAOYSA-N victoria blue R Chemical compound [Cl-].C12=CC=CC=C2C(=[NH+]CC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 JEVGKYBUANQAKG-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
- C08G59/1461—Unsaturated monoacids
- C08G59/1466—Acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
- C08F299/028—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight photopolymerisable compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Epoxy Resins (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1361518 Acrylic ester coatings NIPPON OIL SEAL INDUSTRY CO Ltd 5 July 1972 [5 July 1971] 31535/72 Heading B2E [Also in Division C3] Photocurable inks, paints or varnishes comprise (a) an esterification product of an epoxy resin and acrylic or methacrylic acid, (b) an ester of acrylic or methacrylic acid with a monohydric or polyhydric alcohol and (c) a photopolymerisation initiator. Component (a) is suitably derived from 1.33 to 2.0 gram equivalents of epoxy resin per gram equivalent of (meth) acrylic acid. Esters (b) specified are the (meth) acrylates of methyl, ethyl, nbutyl, n-octyl or 2-ethylhexyl alcohol, the di(meth)acrylates of ethylene, diethylene, triethylene or tetraethylene glycol, and the tri(meth)acrylates of trimethylolpropane or triethylolpropane. The initiator (c) may be, for example, benzophenone, acetophenone, triphenylphosphine, 2-ethylanthraquinone. 2-tertbutylanthraquinone, furoin, benzoin, benzoin methyl ether or benzoin ethyl ether. The compositions may optionally include a colouring agent, e.g. copper phthalocyanine, Victoria blue, methylene blue, hansa yellow, carmine lake or carbon black. In Examples the compositions are coated and photo-cured on sheets of copper or paper.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4970171A JPS564565B1 (en) | 1971-07-05 | 1971-07-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1361518A true GB1361518A (en) | 1974-07-24 |
Family
ID=12838472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3153572A Expired GB1361518A (en) | 1971-07-05 | 1972-07-05 | Photocurable compositions |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS564565B1 (en) |
| DE (1) | DE2232822C2 (en) |
| FR (1) | FR2144802B1 (en) |
| GB (1) | GB1361518A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4557813A (en) * | 1983-09-09 | 1985-12-10 | Basf Aktiengesellschaft | Magnetic recording media |
| US4559118A (en) * | 1983-09-09 | 1985-12-17 | Basf Aktiengesellschaft | Magnetic recording media |
| US4560456A (en) * | 1983-09-09 | 1985-12-24 | Basf Aktiengesellschaft | Magnetic recording media |
| US4666783A (en) * | 1984-05-18 | 1987-05-19 | Basf Aktiengesellschaft | Magnetic recording media |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5430431B2 (en) * | 1973-03-22 | 1979-10-01 | ||
| US4169732A (en) * | 1978-01-09 | 1979-10-02 | International Business Machines Corporation | Photosensitive coating composition and use thereof |
| US4239077A (en) * | 1978-12-01 | 1980-12-16 | Westinghouse Electric Corp. | Method of making heat curable adhesive coated insulation for transformers |
| US4434278A (en) * | 1982-09-27 | 1984-02-28 | Celanese Corporation | Phosphate esters of acrylated epoxides |
| JPS6069167A (en) * | 1983-09-27 | 1985-04-19 | Matsushita Electric Ind Co Ltd | Photo-setting light screening coating composition |
| DE3508399C2 (en) * | 1984-04-04 | 1995-08-10 | Hoechst Ag | 2-component paints and their use |
| DE3723196A1 (en) * | 1987-07-14 | 1989-01-26 | Bayer Ag | METHOD FOR PRODUCING PHENACRYLATE RESINS IN VINYL MONOMER SOLUTION |
| JP6930895B2 (en) | 2017-10-30 | 2021-09-01 | ニッタ株式会社 | Automatic tool changer coupler and automatic tool changer |
-
1971
- 1971-07-05 JP JP4970171A patent/JPS564565B1/ja active Pending
-
1972
- 1972-07-04 DE DE19722232822 patent/DE2232822C2/en not_active Expired
- 1972-07-05 FR FR7224323A patent/FR2144802B1/fr not_active Expired
- 1972-07-05 GB GB3153572A patent/GB1361518A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4557813A (en) * | 1983-09-09 | 1985-12-10 | Basf Aktiengesellschaft | Magnetic recording media |
| US4559118A (en) * | 1983-09-09 | 1985-12-17 | Basf Aktiengesellschaft | Magnetic recording media |
| US4560456A (en) * | 1983-09-09 | 1985-12-24 | Basf Aktiengesellschaft | Magnetic recording media |
| US4666783A (en) * | 1984-05-18 | 1987-05-19 | Basf Aktiengesellschaft | Magnetic recording media |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2232822C2 (en) | 1982-07-29 |
| DE2232822A1 (en) | 1973-02-01 |
| FR2144802B1 (en) | 1977-08-26 |
| JPS564565B1 (en) | 1981-01-30 |
| FR2144802A1 (en) | 1973-02-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 433D | Application made for revocation (sect. 33/1949) | ||
| 433B | Case decided by the comptroller ** patent revoked (sect. 33/1949) |