GB1358209A - Radiation cure of synthetic rubbers - Google Patents
Radiation cure of synthetic rubbersInfo
- Publication number
- GB1358209A GB1358209A GB2305972A GB2305972A GB1358209A GB 1358209 A GB1358209 A GB 1358209A GB 2305972 A GB2305972 A GB 2305972A GB 2305972 A GB2305972 A GB 2305972A GB 1358209 A GB1358209 A GB 1358209A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cross
- radiation
- rubber
- link
- average
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000005855 radiation Effects 0.000 title abstract 5
- 229920003051 synthetic elastomer Polymers 0.000 title abstract 3
- 239000005061 synthetic rubber Substances 0.000 title abstract 3
- 229920001971 elastomer Polymers 0.000 abstract 4
- 239000005060 rubber Substances 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- 238000004132 cross linking Methods 0.000 abstract 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 abstract 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 abstract 1
- VSZSIEBALNXIFG-UHFFFAOYSA-N 2-hydroxyethyl 2,2-bis(sulfanyl)acetate Chemical compound OCCOC(=O)C(S)S VSZSIEBALNXIFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 239000002174 Styrene-butadiene Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 1
- 230000005865 ionizing radiation Effects 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1358209 Radiation cure of synthetic rubbers FIRESTONE TIRE & RUBBER CO 17 May 1972 [1 June 1971] 23059/72 Heading C3P Synthetic rubber compositions curable by high energy ionizing radiation at an average radiation dose (when the composition is in the pure state) of 0À5-7 megarads, comprise a least one diolefin polymer or copolymer having a weight average molecular weight of at least 50,000 and a molecular weight distribution (defined) or 1À01-30, the distribution of monomer units affecting the total cross-linking rate being such that when the value of the fraction G(cross-link)x i /G(cross-link) (defined) is greater than 1À5, from 50-100% of the monomer whose cross-linking rate contribution is represented by G(cross-link)x i is in molecules having a M.W. less than the weight average M.W. of the rubber; and when the said value is below 0À5, up to 50% of the said monomer is in molecular having a M.W. less than the weight average M.W. of the rubber. The compositions may be blended with conventional additives and cured at average radiation doses of up to 15 megarads, optionally with the aid of radiation promoters, e.g. p-dichlorobenzene, ethylene glycol dimercaptoacetate or a polyhydrosulphide. Suitable rubbers include polybutadiene, SBR and ethylene/propylene/ethylidene norbornene terpolymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14869671A | 1971-06-01 | 1971-06-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1358209A true GB1358209A (en) | 1974-07-03 |
Family
ID=22526933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2305972A Expired GB1358209A (en) | 1971-06-01 | 1972-05-17 | Radiation cure of synthetic rubbers |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5614691B1 (en) |
| CA (1) | CA997100A (en) |
| DE (1) | DE2226106C2 (en) |
| FR (1) | FR2141156A5 (en) |
| GB (1) | GB1358209A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2362015A1 (en) * | 1976-08-20 | 1978-03-17 | Firestone Tire & Rubber Co | LAMINATE WITH A CLOSING ACTION, ITS OBTAINING AND ITS APPLICATION TO A TIRE |
| US4140167A (en) * | 1976-08-20 | 1979-02-20 | The Firestone Tire & Rubber Company | Sealant laminates |
| US4352765A (en) | 1979-08-04 | 1982-10-05 | Metzeler Kautschuk Gmbh | Method for producing rubber articles by subjecting powdered caoutchou composition to intensive mixing and high-speed electrons |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4220512A (en) * | 1977-01-24 | 1980-09-02 | The Firestone Tire & Rubber Company | Morphology stabilization of heterogeneous polymer blends |
| US4559117A (en) * | 1982-11-12 | 1985-12-17 | The Firestone Tire & Rubber Company | Block copolymers made by radiation crosslinking of miscible mixture of homopolymers |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB901737A (en) * | 1958-03-04 | 1962-07-25 | Dunlop Rubber Co | Improvements in or relating to oil-extended polymers |
| GB922531A (en) * | 1958-12-30 | 1963-04-03 | Dunlop Rubber Co | Improvements in or relating to the curing of rubber |
| FR1291135A (en) * | 1960-05-05 | 1962-04-20 | Dunlop Rubber Co | Vulcanization of polymeric materials, in particular of rubber-type elastomers |
-
1972
- 1972-05-17 GB GB2305972A patent/GB1358209A/en not_active Expired
- 1972-05-23 CA CA142,778A patent/CA997100A/en not_active Expired
- 1972-05-29 DE DE19722226106 patent/DE2226106C2/en not_active Expired
- 1972-06-01 FR FR7219771A patent/FR2141156A5/fr not_active Expired
- 1972-06-01 JP JP5386072A patent/JPS5614691B1/ja active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2362015A1 (en) * | 1976-08-20 | 1978-03-17 | Firestone Tire & Rubber Co | LAMINATE WITH A CLOSING ACTION, ITS OBTAINING AND ITS APPLICATION TO A TIRE |
| US4140167A (en) * | 1976-08-20 | 1979-02-20 | The Firestone Tire & Rubber Company | Sealant laminates |
| US4352765A (en) | 1979-08-04 | 1982-10-05 | Metzeler Kautschuk Gmbh | Method for producing rubber articles by subjecting powdered caoutchou composition to intensive mixing and high-speed electrons |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2141156A5 (en) | 1973-01-19 |
| DE2226106C2 (en) | 1982-12-23 |
| JPS5614691B1 (en) | 1981-04-06 |
| CA997100A (en) | 1976-09-14 |
| DE2226106A1 (en) | 1972-12-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |