GB1358062A - Photosensitive compositions - Google Patents
Photosensitive compositionsInfo
- Publication number
- GB1358062A GB1358062A GB3274471A GB3274471A GB1358062A GB 1358062 A GB1358062 A GB 1358062A GB 3274471 A GB3274471 A GB 3274471A GB 3274471 A GB3274471 A GB 3274471A GB 1358062 A GB1358062 A GB 1358062A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- acrylonitrile
- meth
- copolymerized
- nitrile rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- 229920000459 Nitrile rubber Polymers 0.000 abstract 2
- -1 alpha-substituted acrylonitrile Chemical class 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- OGQVROWWFUXRST-FNORWQNLSA-N (3e)-hepta-1,3-diene Chemical compound CCC\C=C\C=C OGQVROWWFUXRST-FNORWQNLSA-N 0.000 abstract 1
- CLNYHERYALISIR-FNORWQNLSA-N (3e)-nona-1,3-diene Chemical compound CCCCC\C=C\C=C CLNYHERYALISIR-FNORWQNLSA-N 0.000 abstract 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 abstract 1
- CKKQLOUBFINSIB-UHFFFAOYSA-N 2-hydroxy-1,2,2-triphenylethanone Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C(=O)C1=CC=CC=C1 CKKQLOUBFINSIB-UHFFFAOYSA-N 0.000 abstract 1
- DIVXVZXROTWKIH-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(O)(C)C(=O)C1=CC=CC=C1 DIVXVZXROTWKIH-UHFFFAOYSA-N 0.000 abstract 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical group C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 abstract 1
- YMRDPCUYKKPMFC-UHFFFAOYSA-N 4-hydroxy-2,2,5,5-tetramethylhexan-3-one Chemical compound CC(C)(C)C(O)C(=O)C(C)(C)C YMRDPCUYKKPMFC-UHFFFAOYSA-N 0.000 abstract 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract 1
- 238000012644 addition polymerization Methods 0.000 abstract 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 229920001198 elastomeric copolymer Polymers 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 abstract 1
- 229960004337 hydroquinone Drugs 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 229920000193 polymethacrylate Polymers 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
- G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1358062 Photopolymerizable compositions UNIROYAL Inc 13 July 1971 [3 Aug 1970] 32744/71 Heading C3P [Also in Division G2] Non - aqueous photopolymerizable compositions suitable for application to a substrate to form a photopolymerizable element (for use in forming printing plates) comprise (I) at least 40% by weight of a nitrile rubber (defined as an elastomeric copolymer containing at least 50% by weight of a copolymerized C 4 -C 10 conjugated diene and at least 2% by weight of copolymerized acrylonitrile or alpha-substituted acrylonitrile); (II) at least 5% by weight of a polyethylenically unsaturated ester of acrylic or methacrylic acid; and (III) 0À1 to 10% by weight of an addition polymerization initiator activatable by actinic light. The nitrile rubber may be derived from (a) butadiene, hexadiene, heptadiene, octadiene or nonadiene and (b) acrylonitrile, chloroacrylonitrile or methacrylonitrile. The (meth)acrylic ester is suitably a poly(meth)acrylate ester of a glycol, glycerol, trimethylolpropane, pentaerythritol, 1,4- cyclohexanediol or 1,4 - benzenediol. Useful initiators include diacetyl, benzil, benzoin, pivaloin, benzoin methyl or ethyl ether, α- methylbenzoin, α-phenylbenzoin and benzophenone.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6062470A | 1970-08-03 | 1970-08-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1358062A true GB1358062A (en) | 1974-06-26 |
Family
ID=22030706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3274471A Expired GB1358062A (en) | 1970-08-03 | 1971-07-13 | Photosensitive compositions |
Country Status (6)
| Country | Link |
|---|---|
| AU (1) | AU451514B2 (en) |
| CA (1) | CA977202A (en) |
| DE (1) | DE2138582A1 (en) |
| FR (1) | FR2103825A5 (en) |
| GB (1) | GB1358062A (en) |
| NL (1) | NL165763C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51106501A (en) * | 1975-03-15 | 1976-09-21 | Tokyo Ohka Kogyo Co Ltd | FUREKISOBANYOKANKOSEIJUSHISOSEIBUTSU |
| DE2902412A1 (en) * | 1978-01-25 | 1979-07-26 | Du Pont | PHOTOPOLYMERIZABLE ELASTOMER MIXTURE |
| US4547453A (en) * | 1981-02-02 | 1985-10-15 | Uniroyal, Inc. | Compressible photopolymer printing plate |
| US4684600A (en) * | 1981-02-02 | 1987-08-04 | Uniroyal Plastics Co., Inc. | Compressible photopolymer printing plate |
| US4686172A (en) * | 1985-07-18 | 1987-08-11 | Uniroyal Plastics Co., Inc. | Photosensitive elastomeric composition for flexographic printing plates having improved softness |
| GB2216136A (en) * | 1988-03-29 | 1989-10-04 | Kendall & Co | Novel processes for bonding polycarbonate substrates and adhesive compositions useful therein |
| US4940650A (en) * | 1986-09-06 | 1990-07-10 | Basf Aktiengesellschaft | Preparation of recording layers and their use for the production of flexographic printing plates |
| US5041360A (en) * | 1988-12-13 | 1991-08-20 | Hoechst Aktiengesellschaft | Process for producing an ozone-resistant flexographic printing form |
| US5135827A (en) * | 1990-02-14 | 1992-08-04 | Hoechst Aktiengesellschaft | Process for the manufacture of photopolymer plates |
| US5147757A (en) * | 1989-02-25 | 1992-09-15 | Basf Aktiengesellschaft | Optically transparent polymer alloy and its use in molding materials, moldings, films, coatings, adhesives and photosensitive recording elements |
| US5474875A (en) * | 1992-01-29 | 1995-12-12 | Basf Lacke+Farben | Photosensitive mixture for producing relief and printing plates |
| US5512419A (en) * | 1988-12-13 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Photopolymerizable elastomeric mixture and recording material containing this mixture, for producing ozone-resistant flexographic printing forms |
| US6103451A (en) * | 1997-10-01 | 2000-08-15 | Basf Drucksysteme Gmbh | Multilayer element for producing printing or relief plates |
| US6248502B1 (en) | 1998-01-09 | 2001-06-19 | Nupro Technologies, Inc. | Developer solvent for photopolymer printing plates and method |
| US6582886B1 (en) | 2001-11-27 | 2003-06-24 | Nupro Technologies, Inc. | Developing solvent for photopolymerizable printing plates |
| US7326353B2 (en) | 2001-11-27 | 2008-02-05 | Nupro Technologies | Methods for reclaiming developing solvents |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4234676A (en) | 1978-01-23 | 1980-11-18 | W. R. Grace & Co. | Polythiol effect curable polymeric composition |
| DE2942183A1 (en) | 1979-10-18 | 1981-05-07 | Basf Ag, 6700 Ludwigshafen | PHOTOPOLYMERIZABLE MIXTURES AND ELEMENTS THEREOF |
| DE3107741A1 (en) | 1981-02-28 | 1982-09-16 | Basf Ag, 6700 Ludwigshafen | MULTIPLE-LAYER ELEMENTS SUITABLE FOR PRODUCING PRINT AND RELIEF FORMS AND METHOD FOR THEIR PRODUCTION |
| JPS5894431A (en) * | 1981-11-28 | 1983-06-04 | バスフ アクチェン ゲゼルシャフト | Manufacture of reactive plane-shaped shape having high thickness accuracy and stability |
| DE3415044C2 (en) * | 1984-04-21 | 1986-12-04 | Du Pont de Nemours (Deutschland) GmbH, 4000 Düsseldorf | Process for the ozone protection of photopolymer flexographic printing plates using alcohol-soluble polyamides |
| DE3828551C3 (en) * | 1988-08-23 | 1995-02-23 | Du Pont Deutschland | Process for the production of flexographic printing forms |
| JP3510393B2 (en) | 1994-08-10 | 2004-03-29 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Flexographic printing plate obtained from a photocurable elastomer composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA614181A (en) * | 1961-02-07 | J. Mcgraw William | Photopolymerizable compositions, elements and processes | |
| US3261686A (en) * | 1963-04-23 | 1966-07-19 | Du Pont | Photopolymerizable compositions and elements |
| US3380831A (en) * | 1964-05-26 | 1968-04-30 | Du Pont | Photopolymerizable compositions and elements |
| DE1945456A1 (en) * | 1968-09-11 | 1970-04-02 | Asahi Chemical Ind | Photosensitizing solution and its use for the production of relief printing plates |
-
1971
- 1971-04-21 CA CA110,944A patent/CA977202A/en not_active Expired
- 1971-07-13 GB GB3274471A patent/GB1358062A/en not_active Expired
- 1971-07-19 AU AU31390/71A patent/AU451514B2/en not_active Expired
- 1971-07-30 NL NL7110524A patent/NL165763C/en not_active IP Right Cessation
- 1971-07-30 FR FR7128043A patent/FR2103825A5/fr not_active Expired
- 1971-08-02 DE DE19712138582 patent/DE2138582A1/en not_active Withdrawn
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51106501A (en) * | 1975-03-15 | 1976-09-21 | Tokyo Ohka Kogyo Co Ltd | FUREKISOBANYOKANKOSEIJUSHISOSEIBUTSU |
| DE2902412A1 (en) * | 1978-01-25 | 1979-07-26 | Du Pont | PHOTOPOLYMERIZABLE ELASTOMER MIXTURE |
| US4547453A (en) * | 1981-02-02 | 1985-10-15 | Uniroyal, Inc. | Compressible photopolymer printing plate |
| US4684600A (en) * | 1981-02-02 | 1987-08-04 | Uniroyal Plastics Co., Inc. | Compressible photopolymer printing plate |
| US4686172A (en) * | 1985-07-18 | 1987-08-11 | Uniroyal Plastics Co., Inc. | Photosensitive elastomeric composition for flexographic printing plates having improved softness |
| US5112725A (en) * | 1986-09-06 | 1992-05-12 | Basf Aktiengesellschaft | Preparation of recording layers and their use for the production of flexographic printing plates |
| US4940650A (en) * | 1986-09-06 | 1990-07-10 | Basf Aktiengesellschaft | Preparation of recording layers and their use for the production of flexographic printing plates |
| GB2216136A (en) * | 1988-03-29 | 1989-10-04 | Kendall & Co | Novel processes for bonding polycarbonate substrates and adhesive compositions useful therein |
| US5041360A (en) * | 1988-12-13 | 1991-08-20 | Hoechst Aktiengesellschaft | Process for producing an ozone-resistant flexographic printing form |
| US5512419A (en) * | 1988-12-13 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Photopolymerizable elastomeric mixture and recording material containing this mixture, for producing ozone-resistant flexographic printing forms |
| US5516624A (en) * | 1988-12-13 | 1996-05-14 | E. I. Du Pont De Nemours And Company | Photopolymerizable elastomeric mixture and recording material containing this mixture, for producing ozone-resistant flexographic printing forms |
| US5147757A (en) * | 1989-02-25 | 1992-09-15 | Basf Aktiengesellschaft | Optically transparent polymer alloy and its use in molding materials, moldings, films, coatings, adhesives and photosensitive recording elements |
| US5135827A (en) * | 1990-02-14 | 1992-08-04 | Hoechst Aktiengesellschaft | Process for the manufacture of photopolymer plates |
| US5474875A (en) * | 1992-01-29 | 1995-12-12 | Basf Lacke+Farben | Photosensitive mixture for producing relief and printing plates |
| US6103451A (en) * | 1997-10-01 | 2000-08-15 | Basf Drucksysteme Gmbh | Multilayer element for producing printing or relief plates |
| US6248502B1 (en) | 1998-01-09 | 2001-06-19 | Nupro Technologies, Inc. | Developer solvent for photopolymer printing plates and method |
| US6582886B1 (en) | 2001-11-27 | 2003-06-24 | Nupro Technologies, Inc. | Developing solvent for photopolymerizable printing plates |
| US7326353B2 (en) | 2001-11-27 | 2008-02-05 | Nupro Technologies | Methods for reclaiming developing solvents |
Also Published As
| Publication number | Publication date |
|---|---|
| NL165763B (en) | 1980-12-15 |
| NL165763C (en) | 1983-02-16 |
| AU451514B2 (en) | 1974-08-08 |
| NL7110524A (en) | 1972-02-07 |
| CA977202A (en) | 1975-11-04 |
| FR2103825A5 (en) | 1972-04-14 |
| AU3139071A (en) | 1973-01-25 |
| DE2138582A1 (en) | 1972-02-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PE20 | Patent expired after termination of 20 years |