GB1355709A - Deodourizing aqueous dispersions of polymers of alkyl esters of alpha,beta-olefinically unsaturated carboxylic acids - Google Patents
Deodourizing aqueous dispersions of polymers of alkyl esters of alpha,beta-olefinically unsaturated carboxylic acidsInfo
- Publication number
- GB1355709A GB1355709A GB4006471A GB4006471A GB1355709A GB 1355709 A GB1355709 A GB 1355709A GB 4006471 A GB4006471 A GB 4006471A GB 4006471 A GB4006471 A GB 4006471A GB 1355709 A GB1355709 A GB 1355709A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- styrene
- butyl acrylate
- ester
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title abstract 6
- 229920000642 polymer Polymers 0.000 title abstract 4
- 125000005907 alkyl ester group Chemical group 0.000 title abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 abstract 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 abstract 2
- 238000011282 treatment Methods 0.000 abstract 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 abstract 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 1
- JCVLRGLQOHKUMK-UHFFFAOYSA-N 3-(3-ethylhexoxy)propan-1-amine Chemical compound CCCC(CC)CCOCCCN JCVLRGLQOHKUMK-UHFFFAOYSA-N 0.000 abstract 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000004103 aminoalkyl group Chemical group 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 230000001877 deodorizing effect Effects 0.000 abstract 1
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 abstract 1
- 125000005678 ethenylene group Chemical group [H]C([*:1])=C([H])[*:2] 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical group O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1355709 Deodorizing polymer dispersions BASF AG 26 Aug 1971 [27 Aug 1970] 40064/71 Heading C3P The deodorization of an aqueous dispersion of a polymer of an alkyl ester of an alpha, beta ethylenically unsaturated carboxylic acid optionally containing units derived from one or more other ethylenic monomers, which dispersion has an odour due to the presence of unpolymerized ester, is effected by treating the dispersion with a compound containing one or more basic non-tertiary nitrogen atoms (except ammonia and ethylene imine), which reacts with the ester to form a monodiferous product. The term "alkyl" includes substituted alkyl. Preferred compounds are those of the formula (I) wherein R is H, alkyl, alkenyl, alkoxyalkyl, hydroxyalkyl, or aralkyl and X is an aliphatic or cycloaliphatic saturated or unsaturated hydrocarbon radical containing one or more aryl groups and/or hetero atoms selected from amino and amido nitrogen atoms, and amide, ether and hydroxy oxygen atoms or a compound of general formula in which Y is -CH 2 -, -O-, -S-, or =NR<SP>11</SP>, where R<SP>11</SP> is H, hydroxy alkyl, aminoalkyl, mono- or dialkyl amino alkyl, alkyl, alkenyl, alkoxyalkyl, aralkyl or acyl, m is zero or 1 or (only when Y is -S- or = NR<SP>11</SP>) 2, and n and o are zero or integers from 1-4 provided that m = 1 or 2 when n and o are both 1, and provided that m+o equals at least 2, and provided that any methylene group may be replaced by a substituted methylene group or any pair of adjacent methylene groups may be replaced by a vinylene group. A long list of examples is given. The treatment is preferably carried out at 40-80‹ C. and pH 5 to 12. In the examples the following treatments are effected on aqueous dispersion of the polymers specified; (1) styrene/n-butyl acrylate with piperazine, dimethylamine and morpholine; (2) styrene/2-ethyl hexyl acrylate with oleyl amine; (3) styrene/n-butyl acrylate/methacrylamide/methacrylic acid with 3-(2-ethyl)-hexoxypropylamine; and (4) styrene/n-butyl acrylate/ methacrylamide with ethylamine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702042499 DE2042499A1 (en) | 1970-08-27 | 1970-08-27 | Process for deodorising wassri ger dispersions of polymers of alkyl esters alpha, beta olefinically unsaturated carboxylic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1355709A true GB1355709A (en) | 1974-06-05 |
Family
ID=5780865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4006471A Expired GB1355709A (en) | 1970-08-27 | 1971-08-26 | Deodourizing aqueous dispersions of polymers of alkyl esters of alpha,beta-olefinically unsaturated carboxylic acids |
Country Status (7)
| Country | Link |
|---|---|
| AU (1) | AU3268971A (en) |
| BE (1) | BE771637A (en) |
| BR (1) | BR7105644D0 (en) |
| DE (1) | DE2042499A1 (en) |
| ES (1) | ES394532A1 (en) |
| FR (1) | FR2101925A5 (en) |
| GB (1) | GB1355709A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9512241B2 (en) | 2011-10-24 | 2016-12-06 | Dow Global Technologies Llc | Method for reducing odoriferous and/or toxic residual monomer in a latex |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4381375A (en) * | 1981-12-28 | 1983-04-26 | E. I. Du Pont De Nemours And Company | Method for vulcanizing ethylene/acrylic or vinyl ester/glycidyl(meth) acrylate copolymer with piperazinium diphenoxide salt of chloro-substituted phenol |
| US4381378A (en) * | 1981-12-28 | 1983-04-26 | E. I. Du Pont De Nemours And Company | Method for vulcanizing ethylene/acrylic or vinyl ester/glycidyl(meth)acrylate copolymer with piperazinium dicarboxylate salt and composition for same |
| DE3517098A1 (en) * | 1985-05-11 | 1986-11-13 | Chemische Fabrik Pfersee Gmbh, 8900 Augsburg | LIQUID FOAMING COMPPOUNDS FOR USE IN AQUEOUS SYSTEMS, METHOD FOR THE PRODUCTION AND USE THEREOF |
-
1970
- 1970-08-27 DE DE19702042499 patent/DE2042499A1/en active Pending
-
1971
- 1971-07-27 FR FR7127460A patent/FR2101925A5/fr not_active Expired
- 1971-08-23 BE BE771637A patent/BE771637A/en unknown
- 1971-08-25 AU AU32689/71A patent/AU3268971A/en not_active Expired
- 1971-08-26 ES ES394532A patent/ES394532A1/en not_active Expired
- 1971-08-26 GB GB4006471A patent/GB1355709A/en not_active Expired
- 1971-08-27 BR BR564471A patent/BR7105644D0/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9512241B2 (en) | 2011-10-24 | 2016-12-06 | Dow Global Technologies Llc | Method for reducing odoriferous and/or toxic residual monomer in a latex |
| US10023662B2 (en) | 2011-10-24 | 2018-07-17 | Dow Global Technologies Llc | Method for reducing odoriferous and/or toxic residual monomer in a latex |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2101925A5 (en) | 1972-03-31 |
| BE771637A (en) | 1972-02-23 |
| ES394532A1 (en) | 1974-09-01 |
| AU3268971A (en) | 1973-03-01 |
| BR7105644D0 (en) | 1973-03-13 |
| DE2042499A1 (en) | 1972-03-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |