GB1349041A - Hydro metallurgical preparation of the oxides of antimony and antimonic acid - Google Patents
Hydro metallurgical preparation of the oxides of antimony and antimonic acidInfo
- Publication number
- GB1349041A GB1349041A GB343272A GB1349041DA GB1349041A GB 1349041 A GB1349041 A GB 1349041A GB 343272 A GB343272 A GB 343272A GB 1349041D A GB1349041D A GB 1349041DA GB 1349041 A GB1349041 A GB 1349041A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphur
- antimony
- weight
- solution
- oxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- AQTIRDJOWSATJB-UHFFFAOYSA-K antimonic acid Chemical compound O[Sb](O)(O)=O AQTIRDJOWSATJB-UHFFFAOYSA-K 0.000 title abstract 3
- 229910052787 antimony Inorganic materials 0.000 title 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 6
- 239000005864 Sulphur Substances 0.000 abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 3
- 238000002386 leaching Methods 0.000 abstract 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- 239000012452 mother liquor Substances 0.000 abstract 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 2
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 abstract 2
- -1 C1A Antimony oxides Chemical class 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 1
- ZGSDJMADBJCNPN-UHFFFAOYSA-N [S-][NH3+] Chemical compound [S-][NH3+] ZGSDJMADBJCNPN-UHFFFAOYSA-N 0.000 abstract 1
- MKUXAQIIEYXACX-UHFFFAOYSA-N aciclovir Chemical compound N1C(N)=NC(=O)C2=C1N(COCCO)C=N2 MKUXAQIIEYXACX-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 abstract 1
- 150000001463 antimony compounds Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052959 stibnite Inorganic materials 0.000 abstract 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical group S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 abstract 1
- 229950011008 tetrachloroethylene Drugs 0.000 abstract 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/02—Obtaining antimony
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G30/00—Compounds of antimony
- C01G30/004—Oxides; Hydroxides; Oxyacids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G30/00—Compounds of antimony
- C01G30/004—Oxides; Hydroxides; Oxyacids
- C01G30/005—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
1349041 Antimony oxides and acid OCCIDENTAL PETROLEUM CORP 25 Jan 1972 [30 Dec 1971] 3432/72 Heading C1A Antimony oxides and or antimonic acid are produced from stibnite bearing ores or concentrates by; (a) leaching with an aqueous ammonium sulphide and sulphur containing solution to form a mother liquor containing antimony sulphide; (b) eliminating ammonia from the mother liquor and then precipitating antimony sulphide and sulphur; (c) oxidizing the precipitate with an aqueous nitric acic solution to form a slurry of antimony oxides and antimonic acid together with sulphur; and (d) separating the antimony compounds from the solution and from the sulphur. The leaching solution preferably comprises 5 to 30% by weight of (NH 4 ) 2 S and 0.1 to 10% by weight of sulphur. It may also contain up to 18% by weight of NH 4 OH. The ammonia may be eliminated by neutralization or distillation. The aqueous nitric acid solution preferably contains 1 to 70% by weight of HNO 3 and oxygen may be present at a pressure of 0 to 300 psig. The sulphur may be separated from the product with a solvent, preferably one of carbon disulphide, trichloroethylene and tetrachloroethylene. The leaching may be carried out at temperatures from ambient to 90‹ C. and the oxidation at between ambient and 150‹ C.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21392971A | 1971-12-30 | 1971-12-30 | |
| DE2207181A DE2207181A1 (en) | 1971-12-30 | 1972-02-16 | PROCESS FOR PRODUCING ANTIMONOXYDE AND / OR ANTIMONIC ACIDS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1349041A true GB1349041A (en) | 1974-03-27 |
Family
ID=25762725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB343272A Expired GB1349041A (en) | 1971-12-30 | 1972-01-25 | Hydro metallurgical preparation of the oxides of antimony and antimonic acid |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS4873326A (en) |
| AU (1) | AU461214B2 (en) |
| BE (1) | BE778804A (en) |
| DE (1) | DE2207181A1 (en) |
| FR (1) | FR2165821B1 (en) |
| GB (1) | GB1349041A (en) |
| ZA (1) | ZA72576B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101265520B (en) * | 2008-05-06 | 2010-06-09 | 锡矿山闪星锑业有限责任公司 | Treatment method for refining lead slag-removed by antimony fire refining process |
| CN109250756A (en) * | 2018-12-06 | 2019-01-22 | 辽宁工程技术大学 | A kind of system of the pipeline reactor wet production without arsenic stibium trioxide |
| CN110697772A (en) * | 2019-10-11 | 2020-01-17 | 衡阳师范学院 | Method for removing trace antimony oxide in crude bismuth oxide |
| CN112708760A (en) * | 2020-12-29 | 2021-04-27 | 金川集团股份有限公司 | Method for removing antimony in nickel refining system |
| CN114875244A (en) * | 2022-05-11 | 2022-08-09 | 中南大学 | A method for recycling high arsenic and antimony smelting soot |
| CN115722347A (en) * | 2022-10-25 | 2023-03-03 | 昆明理工大学 | Method for separating lead and antimony from paragenetic ore |
| CN117210706A (en) * | 2023-08-07 | 2023-12-12 | 昆明理工大学 | Method for reducing antimony oxide by hydrogen |
| CN119406587A (en) * | 2024-10-24 | 2025-02-11 | 长沙矿山研究院有限责任公司 | Fine-grained antimony oxide ore dressing method |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19811763A1 (en) * | 1998-03-18 | 1999-09-23 | Stadtwerke Karlsruhe Gmbh | Removing arsenic and optionally antimony from suspensions obtained in drinking water production |
| CN111809046A (en) * | 2020-07-15 | 2020-10-23 | 锡矿山闪星锑业有限责任公司 | Process for removing lead, copper and bismuth in antimony oxide by wet method |
| CN112678869B (en) * | 2020-12-25 | 2023-04-07 | 广东宇星阻燃新材股份有限公司 | Preparation method of spherical antimony trioxide |
-
1972
- 1972-01-25 GB GB343272A patent/GB1349041A/en not_active Expired
- 1972-01-27 AU AU38439/72A patent/AU461214B2/en not_active Expired
- 1972-01-28 ZA ZA720576A patent/ZA72576B/en unknown
- 1972-02-01 BE BE778804A patent/BE778804A/en unknown
- 1972-02-09 FR FR7204315A patent/FR2165821B1/fr not_active Expired
- 1972-02-16 DE DE2207181A patent/DE2207181A1/en active Pending
- 1972-02-22 JP JP47017774A patent/JPS4873326A/ja active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101265520B (en) * | 2008-05-06 | 2010-06-09 | 锡矿山闪星锑业有限责任公司 | Treatment method for refining lead slag-removed by antimony fire refining process |
| CN109250756A (en) * | 2018-12-06 | 2019-01-22 | 辽宁工程技术大学 | A kind of system of the pipeline reactor wet production without arsenic stibium trioxide |
| CN110697772A (en) * | 2019-10-11 | 2020-01-17 | 衡阳师范学院 | Method for removing trace antimony oxide in crude bismuth oxide |
| CN110697772B (en) * | 2019-10-11 | 2022-04-12 | 衡阳师范学院 | A kind of method for removing trace antimony oxide in crude bismuth oxide |
| CN112708760A (en) * | 2020-12-29 | 2021-04-27 | 金川集团股份有限公司 | Method for removing antimony in nickel refining system |
| CN114875244A (en) * | 2022-05-11 | 2022-08-09 | 中南大学 | A method for recycling high arsenic and antimony smelting soot |
| CN115722347A (en) * | 2022-10-25 | 2023-03-03 | 昆明理工大学 | Method for separating lead and antimony from paragenetic ore |
| CN117210706A (en) * | 2023-08-07 | 2023-12-12 | 昆明理工大学 | Method for reducing antimony oxide by hydrogen |
| CN119406587A (en) * | 2024-10-24 | 2025-02-11 | 长沙矿山研究院有限责任公司 | Fine-grained antimony oxide ore dressing method |
Also Published As
| Publication number | Publication date |
|---|---|
| BE778804A (en) | 1972-05-30 |
| JPS4873326A (en) | 1973-10-03 |
| ZA72576B (en) | 1972-10-25 |
| FR2165821B1 (en) | 1975-03-21 |
| AU461214B2 (en) | 1975-05-01 |
| FR2165821A1 (en) | 1973-08-10 |
| AU3843972A (en) | 1973-08-02 |
| DE2207181A1 (en) | 1973-08-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |