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GB1346402A - Polyisocyanates and their use in the production of polyurethane plastics - Google Patents

Polyisocyanates and their use in the production of polyurethane plastics

Info

Publication number
GB1346402A
GB1346402A GB2193472A GB2193472A GB1346402A GB 1346402 A GB1346402 A GB 1346402A GB 2193472 A GB2193472 A GB 2193472A GB 2193472 A GB2193472 A GB 2193472A GB 1346402 A GB1346402 A GB 1346402A
Authority
GB
United Kingdom
Prior art keywords
weight
content
polyisocyanate
diisocyanatotoluene
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2193472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1346402A publication Critical patent/GB1346402A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/487—Polyethers containing cyclic groups
    • C08G18/4879—Polyethers containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
    • C08G18/3889—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having nitrogen in addition to phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/727—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80 comprising distillation residues or non-distilled raw phosgenation products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1346402 Polyisocyanate mixtures BAYER AG 10 May 1972 [11 May 1971] 21934/72 Heading C2C [Also in Division C3] A polisocyanate mixture comprises (a) from 2 to 60% by weight of a distillation residue obtained from the large-scale distillation of a crude diisocyanatotoluene isomer mixture, which residue has (i) a carbodiimide group content of less than 1À4% by weight, (ii) a content of phosgenation products of 2,3- or 3,4-diaminotoluene or biuret derivatives thereof, corresponding to an O-diamine content of more than 2% by weight in the amine mixture used for phosgenation, (iii) an NCO-group content of from 15 to 32% by weight and (iv) a monomeric diisocyanatotoluene content of less than 15%; and (b) from 40 to 98% by weight of a polyphenyl polymethylene polyisocyanate mixture comprising from 50 to 100% by weight of trinuclear diisocyanato diphenylmethane isomers, obtained by phosgenating an aniline/formaldehyde condensate. This distillation residue (c) is obtained by working up of the crude diisocyanatotoluene at a temperature not above 200‹ C. Preferably the polyphenyl polymethylene polyisocyanate (b) has a binuclear diisocyanate content of 65 to 97% by weight. The polyisocyanate mixtures are advantageously produced by mixing the distillation residue heated to 80‹ to 200‹ C., with the polyphenyl polymethylene polyisocyanate, which preferably is also heated. Both cellular and non- cellular polyurethanes may be produced from the polyisocyanate mixtures (see Division C3).
GB2193472A 1971-05-11 1972-05-10 Polyisocyanates and their use in the production of polyurethane plastics Expired GB1346402A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19712123183 DE2123183A1 (en) 1971-05-11 1971-05-11

Publications (1)

Publication Number Publication Date
GB1346402A true GB1346402A (en) 1974-02-13

Family

ID=5807464

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2193472A Expired GB1346402A (en) 1971-05-11 1972-05-10 Polyisocyanates and their use in the production of polyurethane plastics

Country Status (11)

Country Link
AT (1) AT325858B (en)
AU (1) AU462594B2 (en)
BE (1) BE783257A (en)
BR (1) BR7202907D0 (en)
CH (1) CH571544A5 (en)
DE (1) DE2123183A1 (en)
ES (1) ES402619A1 (en)
FR (1) FR2137728A1 (en)
GB (1) GB1346402A (en)
IT (1) IT957771B (en)
NL (1) NL7206340A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4251401A (en) 1978-10-27 1981-02-17 Bayer Aktiengesellschaft Suspensions of isocyanate distillation residues in polyols
US4251638A (en) 1978-10-27 1981-02-17 Bayer Aktiengesellschaft Process for the production of polyurethane plastics
US5314588A (en) * 1991-08-20 1994-05-24 Bayer Aktiengesellschaft Process for recovering polysocyanates from the distillation residues obtained in the production of tolylene diisocyanate
SG122820A1 (en) * 2003-05-08 2006-06-29 Bayer Materialscience Ag Process for the distillation of a mixture of isomeric diisocyanatodiphenylmethanes
CN102816087A (en) * 2011-06-10 2012-12-12 上海朗亿功能材料有限公司 Method for preparing hydrolysis stabilizer for adhesive
WO2016162255A1 (en) * 2015-04-10 2016-10-13 Basf Se Insulative polyurethane rigid foam based on tdi liquid residue

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4118410A (en) 1971-02-04 1978-10-03 Gottfried Reuter Gmbh I.L. Polyphenyl-polymethylene-polyisocyanate mixtures
DE4200325A1 (en) * 1992-01-09 1993-07-15 Bayer Ag METHOD FOR PRODUCING HARD URETHANOUS GROUPS
CN106279623A (en) * 2015-06-01 2017-01-04 科思创聚合物（中国）有限公司 Isocyanate composition and hard polyurethane foam prepared therefrom

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4251401A (en) 1978-10-27 1981-02-17 Bayer Aktiengesellschaft Suspensions of isocyanate distillation residues in polyols
US4251638A (en) 1978-10-27 1981-02-17 Bayer Aktiengesellschaft Process for the production of polyurethane plastics
US5314588A (en) * 1991-08-20 1994-05-24 Bayer Aktiengesellschaft Process for recovering polysocyanates from the distillation residues obtained in the production of tolylene diisocyanate
SG122820A1 (en) * 2003-05-08 2006-06-29 Bayer Materialscience Ag Process for the distillation of a mixture of isomeric diisocyanatodiphenylmethanes
CN102816087A (en) * 2011-06-10 2012-12-12 上海朗亿功能材料有限公司 Method for preparing hydrolysis stabilizer for adhesive
WO2016162255A1 (en) * 2015-04-10 2016-10-13 Basf Se Insulative polyurethane rigid foam based on tdi liquid residue
CN107466304A (en) * 2015-04-10 2017-12-12 巴斯夫欧洲公司 Adiabatic hard polyurethane foam based on TDI liquid residues
JP2018512343A (en) * 2015-04-10 2018-05-17 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Insulating polyurethane rigid foam based on TDI liquid residue

Also Published As

Publication number Publication date
AU462594B2 (en) 1975-06-26
ATA403972A (en) 1975-01-15
AU4203172A (en) 1973-11-15
BE783257A (en) 1972-11-10
FR2137728A1 (en) 1972-12-29
CH571544A5 (en) 1976-01-15
ES402619A1 (en) 1975-04-01
IT957771B (en) 1973-10-20
AT325858B (en) 1975-11-10
DE2123183A1 (en) 1972-12-14
BR7202907D0 (en) 1973-05-10
NL7206340A (en) 1972-11-14

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee