GB1343842A - Polymides containing alkali-modified disulphimide groups - Google Patents
Polymides containing alkali-modified disulphimide groupsInfo
- Publication number
- GB1343842A GB1343842A GB2509071*A GB2509071A GB1343842A GB 1343842 A GB1343842 A GB 1343842A GB 2509071 A GB2509071 A GB 2509071A GB 1343842 A GB1343842 A GB 1343842A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- disulphimide
- aliphatic
- copolymerized
- hexamethylene diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 2
- -1 decamethylene diamines Chemical class 0.000 abstract 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 abstract 2
- 229920002647 polyamide Polymers 0.000 abstract 2
- 239000004953 Aliphatic polyamide Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 229920003231 aliphatic polyamide Polymers 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229960002684 aminocaproic acid Drugs 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 229910003002 lithium salt Inorganic materials 0.000 abstract 1
- 159000000002 lithium salts Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003330 sebacic acids Chemical class 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 150000003442 suberic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/42—Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
1343842 Polyamides BAYER AG 19 April 1971 [15 April 1970] 25090/71 Heading C3R An otherwise aliphatic linear polyamide of relative viscosity 1À2 to 4À5 (1 g./100 ml m-cresol at 25‹ C.) contains at least 50 mequiv./Kg. of units where Z is H or alkali metal, R is a monovalent aliphatic, cycloaliphatic or aromatic radical and each A is -CO-NH- or -NH-CO-. They may be obtained by copolymerizing appropriate quantities of compounds of the above formula wherein -A- is an amide-forming group such as amino or carboxylic acid, ester or chloride with aliphatic polyamide monomers by melt, interfacial or solution techniques. Specified aliphatic monomers are capro- and dodecalactams, amino-caproic and -undecanoic acids, hexa-, octa- and decamethylene diamines and adipic, suberic and sebacic acids. Polymers containing 50 to 250 mequiv. disulphimide units may be used to form basic-dyeable fibres, films or mouldings; those with higher contents may be used as master batches for this purpose or cross-linked with formaldehyde to form ionexchange resins. In Examples (1) 26À1 parts ofthe sodium salt of 3,5-dicarbomethoxy diphenyl disulphimide is copolymerized with 7 parts hexamethylene diamine, 4000 parts caprolactam and 67 parts aminocaproic acid; (2) 100À6 parts of the the lithium salt thereof is copolymerized with 27À8 parts, 50 parts and 30 parts respectively of the same monomers; (3) the potassium salt thereof is homopolymerized with hexamethylene diamine; and (4) 385 parts 3,5- dicarboxyphenyl methyl disulphimide is copolymerized with 116 parts hexamethylene diamine and 500 parts caprolactam.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702017968 DE2017968A1 (en) | 1970-04-15 | 1970-04-15 | Acid modified high molecular weight polyamides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1343842A true GB1343842A (en) | 1974-01-16 |
Family
ID=5768110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2509071*A Expired GB1343842A (en) | 1970-04-15 | 1971-04-19 | Polymides containing alkali-modified disulphimide groups |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3755263A (en) |
| BE (1) | BE765800A (en) |
| CA (1) | CA962799A (en) |
| DE (1) | DE2017968A1 (en) |
| FR (1) | FR2086092B1 (en) |
| GB (1) | GB1343842A (en) |
| NL (1) | NL7104699A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2311982C3 (en) * | 1973-03-10 | 1981-12-17 | Bayer Ag, 5090 Leverkusen | Process for the production of homogeneous modified polycaprolactams and their use for threads and fibers |
| DE2339865C2 (en) * | 1973-08-07 | 1983-04-28 | Bayer Ag, 5090 Leverkusen | Polycaprolactams containing sulfonate groups, processes for their production, and threads and fibers made from polycaprolactams which contain these polycaprolactams containing sulfonate groups in admixture |
| ES462585A1 (en) * | 1976-09-24 | 1978-07-16 | Bauer Ag | Semipermeable membranes of aromatic disulfimide containing polyamides |
| GB202101153D0 (en) * | 2021-01-28 | 2021-03-17 | Fujifilm Mfg Europe Bv | Polymer films |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3184436A (en) * | 1959-09-04 | 1965-05-18 | Du Pont | Polycarbonamides of improved dye affinity having the benzene sulfonic acid salt moiety as an integral part of the polymer chain |
| US3296204A (en) * | 1962-02-20 | 1967-01-03 | Eastman Kodak Co | Sulfonated polyamides |
-
1970
- 1970-04-15 DE DE19702017968 patent/DE2017968A1/en active Pending
-
1971
- 1971-04-07 NL NL7104699A patent/NL7104699A/xx unknown
- 1971-04-09 US US00132871A patent/US3755263A/en not_active Expired - Lifetime
- 1971-04-13 CA CA110,129A patent/CA962799A/en not_active Expired
- 1971-04-15 FR FR7113362A patent/FR2086092B1/fr not_active Expired
- 1971-04-15 BE BE765800A patent/BE765800A/en unknown
- 1971-04-19 GB GB2509071*A patent/GB1343842A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2086092A1 (en) | 1971-12-31 |
| CA962799A (en) | 1975-02-11 |
| NL7104699A (en) | 1971-10-19 |
| DE2017968A1 (en) | 1971-10-28 |
| FR2086092B1 (en) | 1974-10-11 |
| US3755263A (en) | 1973-08-28 |
| BE765800A (en) | 1971-08-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] |