GB1237785A - Tooth-filling and dental fixing material - Google Patents
Tooth-filling and dental fixing materialInfo
- Publication number
- GB1237785A GB1237785A GB37428/68A GB3742868A GB1237785A GB 1237785 A GB1237785 A GB 1237785A GB 37428/68 A GB37428/68 A GB 37428/68A GB 3742868 A GB3742868 A GB 3742868A GB 1237785 A GB1237785 A GB 1237785A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroperoxide
- monomer
- compositions
- compound
- perester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 3
- -1 alkyl hydroperoxide Chemical compound 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000004327 boric acid Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 238000011065 in-situ storage Methods 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 150000002976 peresters Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 150000001639 boron compounds Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- CXZRAHSKAVEDKO-UHFFFAOYSA-N ditert-butyl (2-methylpropan-2-yl)oxy borate Chemical group CC(C)(C)OOB(OC(C)(C)C)OC(C)(C)C CXZRAHSKAVEDKO-UHFFFAOYSA-N 0.000 abstract 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000834 fixative Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- LGQXXHMEBUOXRP-UHFFFAOYSA-N tributyl borate Chemical compound CCCCOB(OCCCC)OCCCC LGQXXHMEBUOXRP-UHFFFAOYSA-N 0.000 abstract 1
- DTBRTYHFHGNZFX-UHFFFAOYSA-N trioctyl borate Chemical compound CCCCCCCCOB(OCCCCCCCC)OCCCCCCCC DTBRTYHFHGNZFX-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
- A61K6/61—Cationic, anionic or redox initiators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/70—Preparations for dentistry comprising inorganic additives
- A61K6/71—Fillers
- A61K6/76—Fillers comprising silicon-containing compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/70—Preparations for dentistry comprising inorganic additives
- A61K6/71—Fillers
- A61K6/77—Glass
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dental Preparations (AREA)
Abstract
1,237,785. Polymerizable compositions for dental use. KULZER & CO. G.m.b.H. 6 Aug., 1968 [19 Aug., 1967], No. 37428/68. Heading C3P. Dental fillers or fixatives comprise (1) a liquid addition polymerizable monomer, (2) a powdered polymer, (3) 0À1-5% by weight (based on the liquid monomer) of at least one hydroperoxide of the formula ROOH in which R is C 3 -C 12 alkyl, or a compound from which such a hydroperoxide is formed in situ (e.g. a perester), and (4) a Redox type catalyst which is effective to polymerize the monomer and which does not comprise an alkyl hydroperoxide as specified in (3). Exemplified as components (1) and (2), respectively, are methyl methacrylate monomer and polymer. The hydroperoxide (3) preferably contains up to 7 carbon atoms; a suitable perester precursor is tri-t-butyl peroxyborate. Redox catalyst (4) is suitably a combination of a peroxide, e.g. benzoyl peroxide, and either a tertiary amine or a reducing sulphur compound, e.g. dimethyl-p-toluidine or a sulphinic acid. The compositions may optionally contain additional components, e.g. a regulator such as dodecyl mercaptan; fillers such as glass or quartz beads, optionally surface-treated with silanes, and also fibres; and, as an agent for protecting tooth pulp against toxic effects of various components of the compositions, boric acid or a boron compound which releases boric acid in situ, e.g. tributyl borate or trioctyl borate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK0063146 | 1967-08-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1237785A true GB1237785A (en) | 1971-06-30 |
Family
ID=7230944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB37428/68A Expired GB1237785A (en) | 1967-08-19 | 1968-08-06 | Tooth-filling and dental fixing material |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE719434A (en) |
| CH (1) | CH540692A (en) |
| DE (1) | DE1617583B1 (en) |
| DK (1) | DK122259B (en) |
| FR (1) | FR1581213A (en) |
| GB (1) | GB1237785A (en) |
| NL (1) | NL6811791A (en) |
| SE (1) | SE345068B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2427357A1 (en) * | 1978-06-01 | 1979-12-28 | Simon Gerald | Thermosetting PMMA compsn. - contg. MMA and reinforcing filler for preparing dental prosthesis |
| DK155079C (en) * | 1983-10-25 | 1989-06-19 | Erik Chr Munksgaard | ADHESIVE PROCEDURES FOR CURRENT ACRYLATE OR METHACRYLATE MATERIALS FOR USE OF COLLAGENIC MATERIALS, ISSENT DENTIN, AND USE OF THE AGENT |
| DE3414165A1 (en) * | 1984-04-14 | 1985-10-17 | Kulzer & Co GmbH, 6393 Wehrheim | Photopolymerisable dental adhesive |
| DE3414163A1 (en) * | 1984-04-14 | 1985-10-17 | Kulzer & Co GmbH, 6393 Wehrheim | PHOTOPOLYMERIZABLE PHOSPHATE-CONTAINING DENTAL ADHESIVE LACQUER |
| DE3414164A1 (en) * | 1984-04-14 | 1985-10-17 | Kulzer & Co GmbH, 6393 Wehrheim | PHOTOPOLYMERIZABLE DENTAL ADHESIVE LACQUER |
| DE3903407A1 (en) * | 1989-02-06 | 1990-08-09 | Blendax Werke Schneider Co | DENTAL FUELING MATERIAL |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE973590C (en) * | 1941-07-29 | 1960-04-07 | Degussa | Use of self-setting plastics in the dental field |
-
1967
- 1967-08-19 DE DE19671617583 patent/DE1617583B1/en active Pending
-
1968
- 1968-07-16 CH CH1063368A patent/CH540692A/en not_active IP Right Cessation
- 1968-07-17 DK DK346068AA patent/DK122259B/en unknown
- 1968-08-06 GB GB37428/68A patent/GB1237785A/en not_active Expired
- 1968-08-12 FR FR1581213D patent/FR1581213A/fr not_active Expired
- 1968-08-13 BE BE719434D patent/BE719434A/xx unknown
- 1968-08-16 SE SE11073/68A patent/SE345068B/xx unknown
- 1968-08-19 NL NL6811791A patent/NL6811791A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE719434A (en) | 1969-02-13 |
| DE1617583B1 (en) | 1970-07-02 |
| DK122259B (en) | 1972-02-14 |
| CH540692A (en) | 1973-08-31 |
| NL6811791A (en) | 1969-02-21 |
| FR1581213A (en) | 1969-09-12 |
| SE345068B (en) | 1972-05-15 |
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