GB1225210A - - Google Patents
Info
- Publication number
- GB1225210A GB1225210A GB3868769A GB1225210DA GB1225210A GB 1225210 A GB1225210 A GB 1225210A GB 3868769 A GB3868769 A GB 3868769A GB 1225210D A GB1225210D A GB 1225210DA GB 1225210 A GB1225210 A GB 1225210A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reactor
- initiator
- halogen
- oxygen
- vinyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003999 initiator Substances 0.000 abstract 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004157 Nitrosyl chloride Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007033 dehydrochlorination reaction Methods 0.000 abstract 1
- 239000003546 flue gas Substances 0.000 abstract 1
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 abstract 1
- VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 abstract 1
- 235000019392 nitrosyl chloride Nutrition 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,225,210. Vinyl chloride. E. V. SONIN, A. L. ENGLINE, I. F. PIMENOV, M.G. AVETIAN, O. V. POLOZOV, A. S. GOLEV, J. A. TREGER, and V. N. ANTIPOV. 1 Aug., 1969, No. 38687/69. Heading C2C. Vinyl chloride is prepared by dehydrochlorination of 1,2-dichloroethane in a reactor at at least 250‹ C. in the presence of an initiator comprising oxygen, a halogen or a compound which liberates a halogen or a free radical under the reaction conditions, the initiator being introduced through at least two inlets spaced along the reactor. Initiators specified are oxygen, chlorine, nitrosyl chloride and hexachloroethane. The use of two and three inlets is described. The reactor may be heated by flue gases. A pressure of 2-30 atmospheres is preferred, but atmospheric pressure may be used in combination with a compressor or gas blower at the reactor outlet. Three rectification columns may be used to purify the exit gas.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3868769 | 1969-08-01 | ||
| DE1953240A DE1953240C3 (en) | 1969-08-01 | 1969-10-22 | Process for the production of vinyl chloride |
| FR6943347A FR2082004A5 (en) | 1969-08-01 | 1969-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1225210A true GB1225210A (en) | 1971-03-17 |
Family
ID=27182201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3868769A Expired GB1225210A (en) | 1969-08-01 | 1969-08-01 |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1953240C3 (en) |
| FR (1) | FR2082004A5 (en) |
| GB (1) | GB1225210A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4584420A (en) * | 1984-06-25 | 1986-04-22 | Ppg Industries, Inc. | Method for producing vinyl chloride |
| US4590318A (en) * | 1984-11-23 | 1986-05-20 | Ppg Industries, Inc. | Method for producing vinyl chloride |
| US7309471B2 (en) | 2002-05-02 | 2007-12-18 | Uhde Gmbh | Method for producing unsaturated halogenic hydrocarbons and device suitable for use with said method |
| US7435983B2 (en) | 2003-04-30 | 2008-10-14 | Uhde Gmbh | Device for injecting electromagnetic radiation into a reactor |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54135712A (en) * | 1978-04-13 | 1979-10-22 | Osaka Soda Co Ltd | Prepartion of 3-chloropropene |
| JPS54135713A (en) * | 1978-04-13 | 1979-10-22 | Osaka Soda Co Ltd | Preparation of 1,3-dichloropropene |
| DE4342906C2 (en) * | 1993-12-16 | 1995-10-26 | Ver Schmiedewerke Gmbh | Rubber body and rubber-sprung rail wheel |
| DE19536149A1 (en) * | 1995-09-28 | 1997-04-03 | Gutehoffnungshuette Radsatz | Current breaker for rubber sprung rail wheel |
| DE29702851U1 (en) * | 1997-02-19 | 1998-06-18 | Gutehoffnungshütte Radsatz GmbH, 46145 Oberhausen | Current bridge for a rubber-sprung rail wheel |
| DE102008049261B4 (en) * | 2008-09-26 | 2018-03-22 | Thyssenkrupp Industrial Solutions Ag | Process and apparatus for the preparation of ethylenically unsaturated halogenated hydrocarbons |
| DE102008049260B4 (en) | 2008-09-26 | 2016-03-10 | Thyssenkrupp Industrial Solutions Ag | Process and apparatus for the preparation of ethylenically unsaturated halogenated hydrocarbons |
| DE102008049262B4 (en) | 2008-09-26 | 2016-03-17 | Thyssenkrupp Industrial Solutions Ag | Process and apparatus for the preparation of ethylenically unsaturated halogenated hydrocarbons |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE473305A (en) * | 1941-08-08 | |||
| US3222407A (en) * | 1962-03-08 | 1965-12-07 | Monsanto Co | Production of vinyl chloride |
-
1969
- 1969-08-01 GB GB3868769A patent/GB1225210A/en not_active Expired
- 1969-10-22 DE DE1953240A patent/DE1953240C3/en not_active Expired
- 1969-12-15 FR FR6943347A patent/FR2082004A5/fr not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4584420A (en) * | 1984-06-25 | 1986-04-22 | Ppg Industries, Inc. | Method for producing vinyl chloride |
| US4590318A (en) * | 1984-11-23 | 1986-05-20 | Ppg Industries, Inc. | Method for producing vinyl chloride |
| US7309471B2 (en) | 2002-05-02 | 2007-12-18 | Uhde Gmbh | Method for producing unsaturated halogenic hydrocarbons and device suitable for use with said method |
| US7435983B2 (en) | 2003-04-30 | 2008-10-14 | Uhde Gmbh | Device for injecting electromagnetic radiation into a reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1953240A1 (en) | 1971-05-06 |
| FR2082004A5 (en) | 1971-12-10 |
| DE1953240C3 (en) | 1984-08-23 |
| DE1953240B2 (en) | 1973-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |