GB1223015A - Polymers of 2-methyl-4-(vinyloxymethyl)-1,3-dioxolane - Google Patents
Polymers of 2-methyl-4-(vinyloxymethyl)-1,3-dioxolaneInfo
- Publication number
- GB1223015A GB1223015A GB1976768A GB1976768A GB1223015A GB 1223015 A GB1223015 A GB 1223015A GB 1976768 A GB1976768 A GB 1976768A GB 1976768 A GB1976768 A GB 1976768A GB 1223015 A GB1223015 A GB 1223015A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyloxymethyl
- methyl
- polymers
- products
- dioxolane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YQWRDYZTGKCPQE-UHFFFAOYSA-N 4-(ethenoxymethyl)-2-methyl-1,3-dioxolane Chemical compound CC1OCC(COC=C)O1 YQWRDYZTGKCPQE-UHFFFAOYSA-N 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 229960003328 benzoyl peroxide Drugs 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 239000011951 cationic catalyst Substances 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- 229960000834 vinyl ether Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F24/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6212—Polymers of alkenylalcohols; Acetals thereof; Oxyalkylation products thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
1,223,015. 2-Methyl-4-vinyloxymethyl-1,3- dioxolan polymers. BRITISH OXYGEN CO. Ltd. 25 April, 1969 [25 April, 1968], No. 19767/68. Heading C3P. 2 - methyl - 4 - (vinyloxymethyl) - 1,3 - dioxolan is homo- or copolymerized using a cationic catalyst and in an inert solvent. The polymer may be cross-linked by inclusion of a divinyl monomer such as divinyl ether in the polymerization. The polymers may be hydrolysed to form products of the formula The above products may be reacted with a dicarboxylic acid or diisocyanate to form threedimensional polyesters or polyurethanes or with a polyunsaturated acid to form diester groupings on each unit. In examples, 2-methyl- 4 - vinyloxymethyl - 1,3 - dioxolane is homo- or copolymerued with maleic anhydride in the presence of BF 3 .(C 2 H 5 ) 2 O or benzoylperoxide and the products hydrolysed with aqueous ammonia and reacted with a tall oil unsaturated acid mixture containing oleic, linoleic and cis - 5,9,12 - octadecatrionoic acids.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1976768A GB1223015A (en) | 1968-04-25 | 1968-04-25 | Polymers of 2-methyl-4-(vinyloxymethyl)-1,3-dioxolane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1976768A GB1223015A (en) | 1968-04-25 | 1968-04-25 | Polymers of 2-methyl-4-(vinyloxymethyl)-1,3-dioxolane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1223015A true GB1223015A (en) | 1971-02-17 |
Family
ID=10134880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1976768A Expired GB1223015A (en) | 1968-04-25 | 1968-04-25 | Polymers of 2-methyl-4-(vinyloxymethyl)-1,3-dioxolane |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1223015A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5019635A (en) * | 1990-03-23 | 1991-05-28 | Eastman Kodak Company | Copolymers of dioxolanes and maleic anhydride |
| US5077365A (en) * | 1990-03-23 | 1991-12-31 | Eastman Kodak Company | Preparation of copolymers of dioxolanes and maleic anhydride |
| US5304611A (en) * | 1992-12-30 | 1994-04-19 | Eastman Kodak Company | Copolymers of vinyl dioxolanes and imidized derivatives of maleic anhydride |
-
1968
- 1968-04-25 GB GB1976768A patent/GB1223015A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5019635A (en) * | 1990-03-23 | 1991-05-28 | Eastman Kodak Company | Copolymers of dioxolanes and maleic anhydride |
| US5077365A (en) * | 1990-03-23 | 1991-12-31 | Eastman Kodak Company | Preparation of copolymers of dioxolanes and maleic anhydride |
| US5304611A (en) * | 1992-12-30 | 1994-04-19 | Eastman Kodak Company | Copolymers of vinyl dioxolanes and imidized derivatives of maleic anhydride |
| US5418294A (en) * | 1992-12-30 | 1995-05-23 | Eastman Chemical Company | Copolymers of vinyl dioxolanes and imidized derivatives of maleic anhydride |
| US5446106A (en) * | 1992-12-30 | 1995-08-29 | Eastman Chemical Company | Copolymers of vinyl dioxolanes and imidized derivatives of maleic anhydride |
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