GB1221610A - Transitory inks - Google Patents
Transitory inksInfo
- Publication number
- GB1221610A GB1221610A GB5424869A GB5424869A GB1221610A GB 1221610 A GB1221610 A GB 1221610A GB 5424869 A GB5424869 A GB 5424869A GB 5424869 A GB5424869 A GB 5424869A GB 1221610 A GB1221610 A GB 1221610A
- Authority
- GB
- United Kingdom
- Prior art keywords
- indicator
- ink
- transitory
- naoh
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000976 ink Substances 0.000 title abstract 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 4
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- CPBJMKMKNCRKQB-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-2-benzofuran-1-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 CPBJMKMKNCRKQB-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 abstract 2
- 235000011187 glycerol Nutrition 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 abstract 1
- UFBJCMHMOXMLKC-UHFFFAOYSA-N 2,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O UFBJCMHMOXMLKC-UHFFFAOYSA-N 0.000 abstract 1
- HBRCDTRQDHMTDA-UHFFFAOYSA-N 2-[[4-(diethylamino)phenyl]diazenyl]benzoic acid Chemical compound C1=CC(N(CC)CC)=CC=C1N=NC1=CC=CC=C1C(O)=O HBRCDTRQDHMTDA-UHFFFAOYSA-N 0.000 abstract 1
- RTZZCYNQPHTPPL-UHFFFAOYSA-N 3-nitrophenol Chemical compound OC1=CC=CC([N+]([O-])=O)=C1 RTZZCYNQPHTPPL-UHFFFAOYSA-N 0.000 abstract 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 abstract 1
- COWHVSLHGUONGN-UHFFFAOYSA-N 6,8-dinitro-1h-quinazoline-2,4-dione Chemical compound N1C(=O)NC(=O)C2=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C21 COWHVSLHGUONGN-UHFFFAOYSA-N 0.000 abstract 1
- UATJOMSPNYCXIX-UHFFFAOYSA-N Trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 UATJOMSPNYCXIX-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- CBMCZKMIOZYAHS-NSCUHMNNSA-N [(e)-prop-1-enyl]boronic acid Chemical compound C\C=C\B(O)O CBMCZKMIOZYAHS-NSCUHMNNSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- QDNJDKQITNEWOI-UHFFFAOYSA-N ethyl 2,2-bis(2,4-dimethylphenyl)acetate Chemical compound C=1C=C(C)C=C(C)C=1C(C(=O)OCC)C1=CC=C(C)C=C1C QDNJDKQITNEWOI-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09B—EDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
- G09B3/00—Manually or mechanically operated teaching appliances working with questions and answers
- G09B3/02—Manually or mechanically operated teaching appliances working with questions and answers of the type wherein the student is expected to construct an answer to the question which is presented or wherein the machine gives an answer to the question presented by a student
- G09B3/04—Manually or mechanically operated teaching appliances working with questions and answers of the type wherein the student is expected to construct an answer to the question which is presented or wherein the machine gives an answer to the question presented by a student of chart form
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Theoretical Computer Science (AREA)
- Educational Administration (AREA)
- Educational Technology (AREA)
- General Physics & Mathematics (AREA)
- Business, Economics & Management (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
1,221,610. Transitory inks. S. I. FRIEDMAN, A. F. LESHER and C. H. BEADLES. 5 Nov., 1969 [8 Nov., 1968], No. 54248/69. Heading C4A. A writing ink giving a transitory mark which then remains invisible until developed, comprises an ink vehicle and a solution of a pH- responsive chemical indicator which reversibly changes with pH from colourless to coloured, the pH of the ink being within the range in which the indicator is coloured. The indicator may be quinaldine red; ethyl red; p-nitrophenol; m - nitrophenol; 2,4 - dinitrophenol; 2,4,6 - trinitrotoluene; 1,3,5 - trinitrobenzene; 6,8 - dinitro - 2,4 - (lH)quinazolinedione - (mdinitrobenzoylene urea); phenolphthalein; o - cresolphthalein; thymolphthalein; ethylbis - (2,4 - dimethylphenyl) - acetate. The ink vehicle may include glycerine and ethanol or methanol, and/or acetone or carbon tetrachloride. The indicator is dissolved in water or an alcohol-water mixture adjusted to the required pH by means of alkali metal hydroxide, e.g. NaOH. Writing is subsequently exposed by a " revealing solution " which may be water, a base or a weak acid. Examples 1-3 disclose inks consisting of NaOH, glycerine, absolute alcohol, and (1) thymolphthalein, (2) phenolphthalein, (3) o-cresolphthalein, for which a revealing solution may be sodium carbonate or weak aqueous NaOH.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77449168A | 1968-11-08 | 1968-11-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1221610A true GB1221610A (en) | 1971-02-03 |
Family
ID=25101415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5424869A Expired GB1221610A (en) | 1968-11-08 | 1969-11-05 | Transitory inks |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1956143A1 (en) |
| GB (1) | GB1221610A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007080361A2 (en) | 2006-01-07 | 2007-07-19 | Polyseam Limited | Composition and method |
| FR2938266A1 (en) * | 2008-11-12 | 2010-05-14 | Ermanno Bo | SELF-DEACTING INK BY AUTO EVAPORATION, USEABLE ON PAPER SUPPORT, BY MEANS OF A SPECIFIC PEN, BUT NOT EXCLUSIVELY. |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54131428A (en) * | 1978-04-03 | 1979-10-12 | Adger Kogyo Co Ltd | Ink |
| US4907903A (en) * | 1987-08-07 | 1990-03-13 | Kiyoharu Kawashima | Representing utensil |
| JPH0323984A (en) * | 1989-06-20 | 1991-01-31 | Seiji Kawashima | Printed matter |
| US5213025A (en) * | 1990-01-26 | 1993-05-25 | Thomas Industries Inc. | Conical rod piston |
| US4976591A (en) * | 1990-03-02 | 1990-12-11 | Intevep, S.A. | Self lubricating, two stage variable compressor |
| ES2034800T3 (en) * | 1990-06-08 | 1993-04-01 | Kiyoharu Kawashima | COLOR CHANGE PRINT. |
| US5498282A (en) * | 1992-07-31 | 1996-03-12 | Binney & Smith Inc. | Color changing pan paint compositions |
-
1969
- 1969-11-05 GB GB5424869A patent/GB1221610A/en not_active Expired
- 1969-11-07 DE DE19691956143 patent/DE1956143A1/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007080361A2 (en) | 2006-01-07 | 2007-07-19 | Polyseam Limited | Composition and method |
| WO2007080361A3 (en) * | 2006-01-07 | 2007-09-07 | Polyseam Ltd | Composition and method |
| FR2938266A1 (en) * | 2008-11-12 | 2010-05-14 | Ermanno Bo | SELF-DEACTING INK BY AUTO EVAPORATION, USEABLE ON PAPER SUPPORT, BY MEANS OF A SPECIFIC PEN, BUT NOT EXCLUSIVELY. |
| WO2010055226A1 (en) * | 2008-11-12 | 2010-05-20 | Ermanno Bo | Ink that erases itself by self-evaporation and can be used on a paper medium by means of a specific writing implement |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1956143A1 (en) | 1970-07-02 |
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